Record Extrinsic Transconductance (2.45 mS/μm at VDS = 0.5 V) InAs/In0.53Ga0.47As Channel MOSFETs Using MOCVD Source-Drain Regrowth Sanghoon Lee1*, C.-Y. Huang1, A. D. Carter1, D. C. Elias1, J. J. M. Law1, V. Chobpattana2, S. Krӓmer2, B. J. Thibeault1, W. Mitchell1, S. Stemmer2, A. C. Gossard2, and M. J. W. Rodwell1 1ECE and 2Materials Departments University of California, Santa Barbara, CA 2013 Symposium on VLSI Technology Kyoto, Japan 06/13/2013 *sanghoon_lee@ece.ucsb.edu 1 VLSI 2013 Outline Motivation: Why III-V MOSFETs? Design Considerations Process Flow Key Process Developments - Damaged Surface removal - Interfacial trap Passivation Measurement Results - I-V Characteristics - Gate leakage & TLM measurement - Peak gm and Ron VS Lg (Benchmarking) Conclusion 2 VLSI 2013 Why III-V MOSFETs in VLSI ? more transconductance per gate width more current (at a fixed Vdd )→ IC speed or reduced Vdd (at a constant Ion)→ reduced power or reduced FET widths→ reduced IC size increased transconductance from: low mass→ high injection velocities lower density of states→ less scattering higher mobility in N+ regions → lower access resistance Other advantages heterojunctions→ strong carrier confinement wide range of available materials epitaxial growth→ atomic layer control 3 VLSI 2013 Key Design Considerations Device structure: Scalability (sub 20 nm-Lg ,<30 nm contact pitch) : self-aligned S/D, very low ρc Carrier supply: heavily doped N+ source region Shallow junction: regrown S/D or Trench-gate Channel Design: Thinner wavefunction depth: Thin channel More injection velocity: higher In-content channel Gate Dielectric: Thinner EOT : scaled high-k dielectric Low Dit : surface passivation, minimized process damage 4 VLSI 2013 Process Flow HSQ HSQ 3/5/3 nm In0.53GaAs/InAs/In0.53GaAs (Channel) 5 nm n+ InGaAs (Capping layer) (Regrown S/D) N+ InGaAs 5 nm n+ InGaAs (Capping layer) 3/5/3 nm Composite Channel 3/5/3 nm Composite channel InAlAs (Barrier) InAlAs (Barrier) InAlAs (Barrier) InP (Substrate) InP (Substrate) 5 nm n+ InGaAs (Capping layer) 3 nm 3.9e12/cm2 Pulse doping InP (Substrate) - Epitaxial layer growth using MBE - Dummy gate definition using e-beam lithography - N+ InGaAs S/D regrowth using MOCVD 3.6 nm HfO2 Ti/Pd/ Au Ni/Au N+ InGaAs (Regrown S/D) Capping layer N+ InGaAs (Regrown S/D) Capping layer S/D metal Ni/Au N+ InGaAs (Regrown S/D) Capping layer 5/3 nm InAs/InGaAs channel 5/3 nm InAs/InGaAs channel InAlAs (Barrier) InAlAs (Barrier) InAlAs (Barrier) InP (Substrate) InP (Substrate) InP (Substrate) 5/3 nm InAs/InGaAs channel - Dummy gate removal - Capping layer digital etching - High-k deposition - Post Deposition Annealing - Gate metal deposition 5 - S/D metal deposition VLSI 2013 Evidence of Surface Damage During Regrowth Long-channel FETs: consistently show >100 mV/dec. subthreshold swing Indicates high Dit despite good MOSCAP data. Suggests process damage. Experiment: SiO2 capping + high temp anneal + strip MOSCAP Process Finding: large degradation in MOSCAP dispersion. Confirms process damage hypothesis. o SiO Capped, 500 C anneal Control 2 1.2 1 KHz 10 KHz 100 KHz 1 MHz Capacitance (F/cm2) 1 Large dispersion Large Dit 0.8 0.6 0.4 0.2 0 -2 -1 0 1 2 -2 -1 Voltage (V) 6 0 1 Voltage (V) 2 VLSI 2013 2 ) Post-Regrowth Surface Digital Etching for Damage Removal Damaged surface HSQ N+ InGaAs (Regrown S/D) N+ InGaAs 5 nm n+ InGaAs (Capping layer) (Regrown S/D) Capping layer 3/5/3 nm Composite channel 5/3 nm InAs/InGaAs channel InAlAs (Barrier) InAlAs (Barrier) InP (Substrate) InP (Substrate) - Surface removed by digital etch process # cycles: 15’ UV ozone (surface oxidation) 1’ dilute HCl (native oxide removal) 13 - 15 Ȧ/cycle, ~0.16 nm RMS roughness Ti/Pd/ Au Ni/Au S/D metal (Regrown S/D)swing and transconductance N+ InGaAs - Etch significantly improves Capping layer 5/3 nm InAs/InGaAs channel - Using this technique, the upper cladding of the composite channel is removed InAlAs (Barrier) InP (Substrate) 7 VLSI 2013 Dit Passivation : In-situ N2 plasma and TMA pretreatment “False inversion” - Cyclic H2 plasma and TMA treatment Dit passivated (A. Carter et al., APEX 2012) H2+TMA+H2 N2+TMA+N2 - Lower Midgap Dit for N2 plasma pretreatment - Al2O3 interfacial layer is not needed (V. Chobpattana, et al. APL 2013) 8 VLSI 2013 Cross-sectional STEM image Ni 3.6 nm HfO2 60 nm 5 nm InAs 3 nm In0.53GaAs Lg ~40 nm In0.52AlAs 8 nm channel (5 nm/3 nm InAs/In0.53GaAs) ; The InAs channel is not relaxed ~ 3.5 nm HfO2 and ~0.5 nm interfacial layer formed by cyclic N2 and TMA treatment 9 VLSI 2013 I-V characteristics for short and long channel devices 1.6 1.4 2.4 2.0 1.2 1.0 1.6 0.8 1.2 0.6 0.8 0.4 0.2 0.0 VDS = 0.5 V -0.2 0.0 0.2 0.4 0.6 0.4 0.0 1 10 0 10 -1 10 -2 10 -3 10 -4 10 -5 VDS=0.5 V VDS=0.05 V 40 nm 70 nm 90 nm -0.2 2.0 VDS=0.5 V 2.0 1.6 1.6 1.2 1.2 0.8 0.8 0.4 0.4 0.0 -0.2 0.0 0.2 0.4 Gate Bias (V) 0.6 0.0 Current Density (mA/m) 2.4 Gm (mS/m) Current Density (mA/m) W = 10.1 μm , L = 510 nm VDS=0.05 V 0.2 0.4 0.6 Gate Bias (V) Gate Bias (V) 2.4 0.0 Current Density (mA/m) 40 nm 70 nm 90 nm 10 10 1 10 0 10 -1 10 -2 10 -3 10 -4 10 -5 10 -6 VDS=0.05 V VDS=0.5 V SS ~ 93 mV/dec at VDS=0.05 V -0.2 0.0 0.2 0.4 Gate Bias (V) 2.2 2.0 VGS = -0.4 V to 1.4 V 1.8 0.2 V increment 1.6 R = 214 Ohm-m on 1.4 1.2 1.0 0.8 0.6 0.4 0.2 0.0 0.0 0.1 0.2 0.3 0.4 0.6 0.8 0.7 0.6 0.5 VGS = -0.4 V to 1.4 V 0.2 V increment Ron = 495 Ohm-m 0.4 0.3 0.2 0.1 0.0 0.0 0.1 0.2 0.3 0.4 0.5 Drain Bias (V) ~2.45 mS/μm Peak Gm at VDS=0.5 V , 93 mV/dec long-channel SS 10 0.5 Drain Bias (V) Current Density (mA/m) 2.8 Current Density (mA/m) 1.8 Gm (mS/m) Current Density (mA/m) W = 10.1 μm , L = 40 nm / 70 nm / 90 nm VLSI 2013 Gate leakage (A/cm ) Gate leakage, access resistance, gm uniformity Resistance (Ohm-m) 2 800 700 Ti/Pd/Au Gap 60 nm n++ InGaAs (regrown contact layer) 600 5 nm n++ InGaAs (Capping layer) 500 Y = 21.8 + 25.1X 400 10 -1 10 -2 10 -3 10 -4 10 -5 10 -6 10 -7 VDS=0.5 V VDS=0.05 V -0.2 0.0 0.2 0.4 0.6 Gate Bias (V) VDS= ~1.2 μm 300 200 Ti/Pd/Au Gate metal 50 nm n++ InGaAs (regrown) 100 5 nm n++ InGaAs 0 0 5 10 3/4/3 nm In0.53GaAs/InAs/In0.53GaAs 15 20 Gap (400 m) nm In 0.52AlAs 25 (UID) 3 nm 3.9e12/cm2 Pulse doping Rsheet = 25 ohm/sq ρc= ~4.7 ohm-μm2 ;S.I. ~82 InPOhm-μm RSD : ~8% degradation gate leakage <10-4 A/cm2 at all bias conditions 11 VLSI 2013 Peak gm and Ron vs. Lg (Benchmarking) 2.8 800 Ron (Ohm-m) Gm_max (mS/m) 2.4 600 2.0 1.6 at Vds=0.5V D.-H. Kim 2011 IEDM (HEMT) D.-H. Kim 2012 IEDM J.J. Gu 2012 IEDM 1.2 T.-W. Kim 2012 VLSI Intel 2009 IEDM This work 400 M. Egard 2011 IEDM 200 Intel 2009 IEDM D.-H. Kim 2012 IEDM T.-W Kim 2012 IEDM Y. Yonai 2011 IEDM This work M. Egard 2011 IEDM 0.1 Y. Yonai 2011 IEDM D.-H. Kim 2012 IEDM (VDS=1V) 0.8 1 Gate length (m) 0.4 0.01 0.1 Gate length (m) 1 Record Gm over all the gate lengths Very Low Ron when considering not fully self-aligned S/D contact 12 VLSI 2013 Conclusion Using digital etching, damaged surface during S/D regrowth can be effectively removed and the channel thinned in a nanometer precision without etch-stop. Employing N2 plasma and TMA in-situ treatment, thin HfO2 (3.5 nm) gate dielectric can be incorporated with low Dit. Peak gm = 2.45 mS/μm at Vds=0.5 V for a 40 nm-Lg device Regrown S/D provides very low access resistance (~ 200 ohm-μm) even with non-self aligned S/D metal contact. 13 VLSI 2013 Acknowledgment Thanks for your attention! Questions? This research was supported by the SRC Non-classical CMOS Research Center (Task 1437.006). A portion of this work was done in the UCSB nanofabrication facility, part of NSF funded NNIN network and MRL Central Facilities supported by the MRSEC Program of the NSF under award No. MR05-20415. *sanghoon_lee@ece.ucsb.edu 14 VLSI 2013