1 EXCHANGE Gas-Forming Reactions REACTIONS 2 3 Gas Forming Reactions 4 REACTIONS EXCHANGE Acid-Base Reactions Aqueous Solutions Solutions that conduct electricity are called ELECTROLYTES Strong electrolytes dissociate completely (or nearly so) into ions. 5 Aqueous Solutions Acids that ionize only to a small extent are called weak electrolyte. CH3CO2H(aq) ---> CH3CO2-(aq) + H+(aq) 6 Aqueous Solutions Some compounds dissolve in water but do not conduct electricity. They are called nonelectrolytes. Examples include: sugar ethanol ethylene glycol 7 8 Know the strong acids & bases! 9 Strong Acids ANION 9 BASES Base g OH- in water NaOH(aq) NaOH is a strong base ---> Na+(aq) + OH-(aq) 10 BASES 11 CaO(s) + H2O(liq) g Ca(OH)2(aq) Metal oxides are bases CaO in water. Indicator shows solution is basic. ACIDS Nonmetal oxides can be acids CO2(aq) + H2O(l) g H2CO3(aq) SO3(aq) + H2O(l) g H2SO4(aq) and can come from burning coal and oil. 12 Acid-Base Reactions 13 The “driving force” = water. Net ionic equation OH-(aq) + H+(aq) g H2O(l) This applies to ALL reactions of STRONG acids and bases. 14 EXCHANGE: Precipitation Reactions REACTIONS IONIC COMPOUNDS Compounds in Aqueous Solution Most redox reactions are in water — aqueous solutions - and involve ionic compounds KMnO4 in water K+(aq) + MnO4-(aq) 15 Insoluble products: Precipitation formation 16 Precipitation Reactions 17 The “driving force”= solid. Pb(NO3)2(aq) + 2 KI(aq) g 2 KNO3(aq) + PbI2(s) Net ionic equation Pb2+(aq) + 2 I-(aq) g PbI2(s) Water Solubility of Ionic Compounds If one ion from the “Soluble Compound” list is present, the compound is water soluble. 18 19 Net Ionic Equations Mg(s) + 2 HCl(aq) g H2(g) + MgCl2(aq) We really should write Mg(s) + 2 H+(aq) + 2 Cl-(aq) g H2(g) + Mg2+(aq) + 2 Cl-(aq) The two Cl- ions are SPECTATOR IONS — they do not participate. Could have used NO3-. Net Ionic Equations Mg(s) + 2 HCl(aq) --> H2(g) + MgCl2(aq) Mg(s) + 2 H+(aq) + 2 Cl-(aq) ---> H2(g) + Mg2+(aq) + 2 Cl-(aq) We leave the spectator ions out — Mg(s) + 2 H+(aq) ---> H2(g) + Mg2+(aq) to give the NET IONIC EQUATION 20