HONORS CHEMISTRY SPRING FINAL EXAM TOPICS SHEET (What a year it was!) Significant Figures Significant Figures and Operations Metric System (prefixes) Dimensional Analysis ----------------------------------------------------------------------------------------------------------------------------- --------------------------------Matter Pure Substances (elements and compounds) Mixtures (homogeneous and heterogeneous) Suspensions and Colloids Tyndall Effect Chemical and Physical Properties Chemical and Physical Changes ----------------------------------------------------------------------------------------------------------------------------- --------------------------------Atomic Structure Nuclear Symbols Atomic Number Mass Number Atomic Mass Isotopes Electron Configurations / Shorthand Configurations / Valence Configurations Isoelectronic Configurations Quantum Numbers Degenerate Orbitals Orbital Diagrams “Light” math (3 equations) Frequency, Wavelength, and Energy – How are they related to each other? Important People The amu Ion Formation ----------------------------------------------------------------------------------------------------------------------------- --------------------------------Periodic Trends (Shielding, Effective Nuclear Charge, Atomic Radius, Ionic Radius, Ionization Energy, Electron Affinity, Electronegativity, Reactivity, Metallic Character) ----------------------------------------------------------------------------------------------------------------------------- --------------------------------Ionic Bonding and Covalent Bonding Lattice Energy Lewis Structures, Electron Domains, and Molecular Geometry Sigma and Pi bonding Bond Polarity and Molecular Polarity IMFs (DD, HB, LDF) Which molecules have the highest boiling point and slowest rate of evporation? ---------------------------------------------------------------------------------------------------------------------------------------- ---------------------Writing names and formulas for organic compounds Isomers Writing names and formulas for ionic compounds, molecular compounds and acids ----------------------------------------------------------------------------------------------------------------------------- --------------------------------5 Types of Reactions Predicting products of chemical reactions Know basic solubility rules (all nitrates and all alkali metal ion compounds are soluble!) Activity Series / Oxidation / Reduction Oxidation Numbers Net Ionic Equations Redox Reactions in Acidic Solution (½ reactions) -------------------------------------------------------------------------------------------------------------------------------------------------------------The mole and Avogadro’s Number (moles to representative particles conversions and vice versa) Molar Mass (moles to mass conversions and vice versa) The Mole Map Percent Composition Empirical Formulas and Molecular Formulas Hydrated Ionic Compounds – Percent Composition and “X” (for example MgSO47H2O) Combustion Analysis -------------------------------------------------------------------------------------------------------------------------------------------------------------Stoichiometry and Balanced Equations The Stoichiometry Map (with gases and solutions [Molarity] added as well) Percent Yield Limiting and Excess Reactants ----------------------------------------------------------------------------------------------------------------------------- --------------------------------States of Matter and the Kinetic Molecular Theory Properties of the sates of matter Gases and P, V, T, and n Rleationship between P, V, T, and n Gas Laws – Boyle, Charles, Gay-Lussac, Combined, & Dalton Ideal Gas Law, Ideal Gas Law solved for molar mass Effusion, Diffusion and Graham’s Law Changes of State -------------------------------------------------------------------------------------------------------------------------------------------------------------Heat Heat Gained = Heat Lost Q=Cm∆T Q=Hfusm Q=Hvapm Specific Heat Capacity, Molar Heat Capacity, Heat Capacity Chemical Energy (also known as Enthalpy) vs Physical Energy (also known as heat) Enthalpy Diagrams for exothermic and endothermic reactions Enthalpy Diagrams with Activation Energy Hess’ Law Summation Equation: ∆Hrxn = n∆Hf(products) - n∆Hf(reactants) Phase Diagrams, Triple Point, Critical Point ----------------------------------------------------------------------------------------------------------------------------- --------------------------------Thermodynamics, Entropy and Free Energy ∆G = ∆H-T∆S Spontaneity and the Thermodynamic Tug of War ----------------------------------------------------------------------------------------------------------------------------- --------------------------------Kinetics – How to increase the rate of a reaction Initial rates of appearance and disappearance Rate Laws Determining “m” and “n” (order of reaction = m+n) Determining the rate constant (k) with units ------------------------------------------------------------------------------------------------------------------------- ------------------------------------Equilibrium definition: when the rate of the ________________rxn = the rate of the ________________rxn. Equilibrium expressions and Keq (what about solids and liquids?) LeChatelier’s Principle (including volume changes for gaseous systems) The ICE Box and solving for equilibrium concentrations when initial concentrations are given The ICE Box and solving for Keq (no “x” in the ICE box) Q and K Solubility Equilibrium and Ksp ----------------------------------------------------------------------------------------------------------------------------- --------------------------------Strong, Weak, and Non Electrolytes Arrhenius Acids and Bases Bronsted Lowry Acids and Bases Strong and Weak Acids Strong and Weak Bases Kw and water Definition of Acids and Bases Ka and Kb Conjugate acids and bases Determining pH and pOH for various solutions (consult acid base help sheet) Titration Calculations and Titration Curves Buffers ----------------------------------------------------------------------------------------------------------------------------- --------------------------------Molality and the Colligative Properties of Freezing Point and Boiling Point