o o Exam 2 Topics Exam 2 may be moved until Monday (3/3). Topics include material covered on or before 2/24/03 (today) Atomic Theory Quantum Model: o Valence electrons (outer shell, ignore d electrons), atoms ionized to get to full valence/octet, noble gas configuration o Groups, Lewis Dot for atoms, halogen= ns2np5 Bonding Ionic Bonds, Covalent Bonds, Polar Covalent Bonds Lewis dot structure of elements & ions Don't worry about octet exceptions Electronegativity (EN) values will be given, know how to use them. Know EN cutoffs for bond type. Remember H is an exception 5 to know system {per-ate, -ate, -ite, hypo-ite, -ide} o system for acids Ionic compounds: balance charge to make them neutral Common chemicals: familiar ones from lecture examples 2 non-metal compounds (N2O dinitrogen monoxide) Multiple charges for Cu & Fe (cuprous, cupric, copper(I), copper(II) ions, same for Fe (II, III)). Procedure & bottom of pg. N.18 Complex Ions: o Cations: NH4+ = ammonium ion o anions: oxyanions, CN- cyanide ion, OH- hydroxide ion, CH3COO- acetate ion Unit C Measurement, dimensions, metric units Scientific Notation Significant Figures Temperature (C, F, K – use formulas (given on exam) to convert) Density = mass/volume, will something float? Skills Lewis Structures Official Lewis steps (1-5). Know the steps. Extra Lewis structure rules: 2+ carbons form chains, H never in center, H on O if possible Similarity between ClO4- and BrO4- Nomenclature Element names, symbols (remember HONClBrIF) Funny elements, e.g. Potassium (K) Prefixes (mono-, di-, tri- … up to 10) Naming non-metal diatomic compound: o Prefix-1st element <space> prefix-2nd element root-ide o Elements in alphabetical order Element ions o Metals: add “ion” to name o Group 5A – 7A (non-metals): add –ide to element root + space + ion Unit D Molecular Geometry: o 3-D repulsion idea, electron pairs or bonds are a “stick” o Linear, Trigonal planar, Tetrahedral Polarity o o o Bond dipoles -> molecular dipoles Draw H2O with bond dipoles, determine net dipole Bond & molecular dipoles for CH4, CH3Cl, CH2Cl2, CHCl3, CCl4 Unit N Oxyanions: Find # of valence electrons for an element. Draw Lewis dots for an atom or ion. Determine formula of an ionic compound (given Al & Cl, come up with AlCl3) Determine polarity of a bond based on electronegativity. Draw Lewis structure (follow the 5 steps) Name an element, determine the elemental formula (HONClBrIF) Name a diatomic compound. Name metal ions, non-metal ions. Calculations, etc.