Valence Bond Theory

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Valence Bond Theory & Hybridization p. 224-235

1.

The salt compound, potassium bromide, possesses anticonvulsant properties but is presently used by veterinarians for treating epilepsy in animals. a.

Identify the type of bonding in potassium bromide. Provide at least two reasons for the type of bonding involved in potassium bromide. b.

Which element has the larger atomic radius: potassium or bromine? Explain. c.

Use Lewis structures to show the formation of potassium bromide. d.

Use orbital diagrams to show the formation of potassium bromide. e.

Which orbitals are involved in the reaction between potassium and bromine? f.

Describe what happens to the size of potassium and bromine atoms when they become ions. g.

Provide three physical properties conferred by the type of bonding in potassium bromide.

2.

Hydrochloric acid, HCl

(aq)

, is a stong acid commonly used in high school laboratories. a.

Determine the difference in electronegativity between hydrogen and chlorine and identify the type of bonding involved.

Provide reasoning. b.

Use Lewis structures to show the formation of hydrochloric acid. c.

Use orbital diagrams to show the formation of hydrochloric acid.

3.

Water, H

2

O

(l)

is considered the universal solvent. Answer question 2 for water.

4.

Beryllium hydride, BeH

2(s)

, is a solid compound that does not exhibit the physical properties of ionic compounds, such as its low melting point. a.

Determine the difference in electronegativity between beryllium and hydrogen and identify the type of bonding involved.

b.

Draw the energy level diagrams for beryllium and hydrogen. What orbitals will form covalent bonds? c.

Explain how beryllium will form two equivalent covalent bonds to form beryllium hydride.

5.

Borane, BH

3(g)

, is only found in the gaseous state indicating that it is a molecular compound. The three

B-H bonds formed in borane are all equivalent covalent bonds, equal strengths and lengths. a.

Draw the Lewis structure of borane. Explain why this is an example of an “incomplete octet”. b.

In which orbitals does boron have valence electrons? c.

Describe how boron must arrange its valence electrons to form three equal bonds.

6.

Methane, CH

4(g)

, is the simplest hydrocarbon, a group of molecular compounds composed of carbon and hydrogen which form very strong covalent bonds. o Draw the Lewis structure of methane. o What is the electron configuration of the carbon atom? o Describe how carbon must arrange its valence electrons to form four equal bonds.

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