Unit IX Study Guide: Acids and Bases Chapters 14, 15 and 18.3 To Review: 1. 2. 3. 4. 5. 6. 7. 8. 9. Nomenclature/formula writing (especially acids and ionic compounds) Polyatomic ions Strong/weak electrolytes Dissociation and ionization Double replacement reactions Molarity Logarithms Equilibrium constants Stoichiometry To Memorize: **Definitions of all words in bold 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. 14. 15. 16. Properties of acids (page 468) Properties of bases (page 471) 3 main types of acids and bases Strong acids and bases (table 2 on page 501) and NH3 is a weak base Relationship between an acid or a base and its conjugate Kw=[OH-][H3O+]= 1.0x10-14 at 25°C Table 4 on page 504 pH + pOH = 14 Purpose and function of an indicator Parts of a titration curve including explanations of the pH at various time points Steps 1-4 on page 520 Ka and Kb expressions Ka x Kb = Kw Components of a buffer Henderson-Hasselbalch equation Hydrolysis of anions and cations To Master: 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. 14. Classify an acid or base as one of the 3 types. Identify acids, bases, conjugate acids, and conjugate bases in a given acid/base equation. Predict the products of an acid/base reaction using a ‘strength of acids’ chart. Write neutralization reactions. Calculate the pH or pOH of a solution when given [H3O+], [H+] or [OH-] and identify the solution as acidic, basic or neutral. Calculate the pH of a strong acid or strong base solution when given the molarity. Determine the appropriate indicator for a titration or determine the pH range of a solution when given the chart on page 513 and color data (you do NOT need to memorize the chart). Determine the concentration of an unknown solution when given titration data. Write the Ka or Kb expression for a given acid, base or conjugate. Calculate the Ka or Kb for a weak acid or base when given its concentration and the pH of the solution or calculate the pH when given its dissociation constant and initial concentration. Calculate the Kb for a weak base given Ka of its conjugate acid, or Ka from Kb. Describe how a buffer solution is usually prepared and be able to use the Henderson-Hasselbalch equation to calculate the pH. Write reactions for the addition of an acid or a base to a buffer. Draw titration curves for various types of titrations and label the equivalence point (greater than, less than or equal to pH =7) and buffer regions where appropriate.