Chapter 16/17 Unit Test Objectives o Understand the three definitions of acids and bases and be able to identify reaction species as Arrhenius acids or bases, Brønsted-Lowery acids and bases or Lewis acids or bases o Identify compounds as strong or weak acids or bases as well as the conjugates of each. Understand why some acids or bases are strong and other are not. o Convert between [H+], [OH-] and pH and pOH. o Understand the information presented in the pH scale. o Use ICE charts to determine the pH of various weak acids or bases and be able to determine when a Ka is appropriate and when a Kb is appropriate for these calculations. o Convert between Ka and Kb using Kw. o Apply Le Châtelier’s principle to weak acid-base equilibrium when a common ion is present. o Understand what a buffer is, how to identify when a buffer is present and how to calculate the pH of a buffer using both an ICE chart and the HendersonHasselbach equation. o Conceptually understand titration curves, the various “landmarks” that can be found on the curves, what they mean and how these curves differ bases on the identity of the titrant and the solution being titrated. (Recall, the “crib notes” handed out in class and the quiz) o Be able to perform calculations of strong acid-strong base titrations (see pg. 671673 for information and a worked out example. You may also want to try the practice exercise on page 673 immediately following the example for extra practice since the answers are given for you to check your work.) o Be able to calculate the pH, pOH, [H+] and [OH-] at any point in a titration. Pay particular attention to how to do this at the equilivance point…it gets a bit tricky since the major species present in the solution changes here. (Recall, we worked out a very challenging titration in class for your review. You should also review pg. 673-677 for information, more example problems and graphic “plans of attack.” It is also highly suggested that you try the practice exercise on pg. 676 immediately following the example and check your answers.) o Understand and apply principles of equilibrium as it applies to solubility and identify factors that affect solubility. o Know what a complex ion is, their amphoteric nature and how to determine its stability in aqueous solution using the equilibrium constant. (Note, we will not be covering complex ion formation in depth. If you are looking to maximize your AP test score, you may want to review Ch 24 of your text and the rules laid out in the predicting products hand-out.)