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CHAPTER 10: Acids and Bases

1. From the following choices in the word bank, select the definition that best describes 1-

Word Bank:

Bronsted-Lowry Acid Bronsted-Lowry Base Arrhenius Acid Arrhenius Base

______________: Produces H + in solution

______________: Donates H+ or protons

______________: Produces OH in solution

______________: Accepts H + protons

2. In following reactions label the Acid, Base, Conjugate Acid, and Conjugate Base. It would help if you try and draw the structures: a.

𝑁𝐻

3

(π‘Žπ‘ž) + 𝐻 b. 𝐻𝐢𝑙 (π‘Žπ‘ž) + 𝐻

2 c. 𝐹 − (π‘Žπ‘ž) + 𝐻

2

2

𝑂 (𝑙)

𝑂 (𝑙)

𝑂 (𝑙)

οƒ 

οƒ 

οƒ 

𝑁𝐻

𝐻

3

𝑂

4

+

+

(π‘Žπ‘ž) + 𝑂𝐻

(π‘Žπ‘ž) + + 𝐢𝑙

𝐻𝐹 (π‘Žπ‘ž) + 𝑂𝐻 −

(π‘Žπ‘ž)

(π‘Žπ‘ž)

(π‘Žπ‘ž)

3. From the reactions above, can you now explain what amphoteric means?

4. Write formulas for the following:

(a) The conjugate acid of the cyanide ion, CN -

(b) The conjugate base of perchloric acid, HClO

4

CHAPTER 10: Acids and Bases

5. T/F: The stronger the acid the weaker the conjugate base. Moreover, stronger bases have weaker the conjugate acids.

6. T/F: Strong acids are acids that dissociate completely in the presence of water/soln.

7. T/F: The “Ka” or equilibrium constant is expressed as products/ reactants ... Therefore, for reaction HAc οƒ  H

3

O + + Ac ,

[𝐻

3

𝑂 + ][𝐴𝐢 −]

πΎπ‘Ž =

[𝐻𝐴𝑐]

8. T/F: As polyprotic acids loose H + ions, the value for Ka decreases significantly.

9. Benzoic acid has a Ka = 6.5x10

-5 , and citric acid has a Ka=7.2x10

-4 . Which of the two is the stronger acid?

10. What is the pH of a solution that contains 25 grams of hydrochloric acid (HCl) dissolved in 1.5 liters of water?

11. What is the pH of a solution that contains 1.32 grams of nitric acid (HNO

3

12. Milk has an H

3

O + concentration of 4.5x10

-7 M. What is the value of [OH -

) (M.W. = 63.02 ) dissolved in 750 mL of water?

]? Is mile acidic, neutral, or basic?

CHAPTER 10: Acids and Bases

13. Lemon juice has a pH of about 2. What [H

3

O + ] concentration is this?

14. A cleaning solution is found to have [OH ] = 1 x 10 -3 M. What is the pH?

15. What is the pH of a buffer solution that contains 0.100 HF and 0.120M NaF? The Ka of HF is 3.5x10

-4 , and so the pKa = 3.46.

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