SALICYLATES & CHEMICALS PVT. LTD.,
A-25, Road No.18, I.D.A. Nacharam,
Hyderabad - 500 076 – India.
Tel # 91 40 27171550, 27174691
Fax # +91 40 27171249
Email : salipl@satyam.net.in
Visit us : www.preservativesindia.com
Safety Data Sheet
SALISOL CRY- Octocrylene
1.
IDENTIFICATION OF THE SUBSTANCE AND OF THE COMPANY
1.1
Identification of the substance


EC#
CAS#

NIOSH, Registry
of Toxic Effects
(RTECS)
Identification
Number


Substance
Name
Synonym:
228-250-8
6197-30-4
Not Available
Octocrylene
2-Ethylhexyl 2-cyano-3,3-diphenylacrylate
2-ethylhexyl 2-cyano-3,3-diphenyl-2-propenoate
2-Ethylhexyl D19202-cyano-3,3-diphenylacrylate
2-Propenoic acid, 2-cyano-3,3-diphenyl-, 2-ethylhexyl ester

Chemical
Formula

Structural
Formula

SMILES


It is used as ultraviolet absorber in plastics, paints and dyes.
It can penetrate into the skin where it acts as a photosensitizer.
1.2
C24H27NO2
CCCCC(CC)COC(=O)C(=C(c1ccccc1)c2ccccc2)C#N
Use of the substance/mixture
SALICYLATES & CHEMICALS PVT. LTD.,
A-25, Road No.18, I.D.A. Nacharam,
Hyderabad - 500 076 – India.
Tel # 91 40 27171550, 27174691
Fax # +91 40 27171249
Email : salipl@satyam.net.in
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
Used as an ingredient in sunscreens and cosmetics that is protecting the skin from direct DNA
damage
1.3
Company/undertaking identification

The person
responsible for
placing the
substance on
the market
within the
Community.

Full address

Telephone No.

Emergency
telephone
number of the
company and/or
relevant official
advisory body
1.4
Salicylates and chemical Pvt ltd
A-25 road no.18 I.D.A Nacharam
Hyderabad -500076
0091 40271715550, 27174691
Emergency telephone
2.
0091 40271715550, 27174691
HAZARDS IDENTIFICATION
Classification according to REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF
THE COUNCIL
Skin Irrit. 2
 Hazard Class
and Category
Eye Irrit. 2
Code(s)

Hazard statement H316
H320
Code(s)
Most important adverse physicochemical, human health and environmental effects and symptoms
relating to the uses and possible misuses of the mixture that can reasonably be forseen
None Found
3.
COMPOSITION/INFORMATION ON INGREDIENTS
SALICYLATES & CHEMICALS PVT. LTD.,
A-25, Road No.18, I.D.A. Nacharam,
Hyderabad - 500 076 – India.
Tel # 91 40 27171550, 27174691
Fax # +91 40 27171249
Email : salipl@satyam.net.in
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Substance
Name
CAS#
EC#
Percentage
by weight
6197-30-4
228-250-8
100%
Octocrilene
Risk
phrases
Hazard
Class and
Category
Code(s)
Hazard
statement
Code(s)
R38
R36
Eye Irrit. 2
Skin Irrit.2
H316
H320
Pictogram,
Signal
Word
Code(s)
Wng
4.
FIRST AID MEASURES
Subdivision of information according to route of exposure
 Eye contact
In case of contact, immediately flush eyes with copious amounts of water for at
least 15 minutes.

Skin Contact

Inhalation

Ingestion
5.
In case of contact, immediately wash skin with soap and copious amounts of
water.
If inhaled, remove to fresh air. If breathing is difficult,
give oxygen. If not breathing, give artificial respiration. Get medical
attention.
Do not ingest. If this material is swallowed, call a physician
Immediately. Drink plenty of water; induce vomiting if conscious
and as directed by a physician. Loosen tight clothing such as collar,
tie, belt or waistband. Never give anything by mouth to an unconscious
person.
FIRE-FIGHTING MEASURES
Suitable extinguishing media

Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or
appropriate foam.
Extinguishing media which shall not be used for safety reasons

Carbon oxides (CO, CO2), nitrogen oxides (NO, NO2, etc.)
SALICYLATES & CHEMICALS PVT. LTD.,
A-25, Road No.18, I.D.A. Nacharam,
Hyderabad - 500 076 – India.
Tel # 91 40 27171550, 27174691
Fax # +91 40 27171249
Email : salipl@satyam.net.in
Visit us : www.preservativesindia.com
Special exposure hazards arising from the substance or preparation itself, combustion products,
resulting gases
As in any fire, wear a self-contained breathing apparatus in pressure demand, MSHA/NIOSH (approved or
equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by
thermal decomposition or combustion.
Other information
 Flammability of
the Product






Auto-Ignition
Temperature
Flash Points
Flammable
Limits
Products of
Combustion
Fire Hazards in
Presence of
Various
Substances
Special
Remarks on Fire
Hazards
6.
This product may be combustible at high temperature. This product
is slightly flammable in the presence of open flames, sparks and
Static discharge.
Not Applicable
>1190C closed cup method
Not Available
Carbon oxides (CO, CO2), nitrogen oxides
(NO, NO2, etc.)
NA
NA
ACCIDENTAL RELEASE MEASURES
Personal Precautions:



Isolate spill area immediately.
Keep unauthorized personnel away.
Ventilate closed spaces before entering.
Methods for cleaning up:
Small Spill and Leak: Use a tool to scoop up solid or absorbed material and place into appropriate
labeled waste container. Finish cleaning by spreading water on the contaminated surface and dispose of
according to local and regional regulatory requirements.
Large Spill and Leak: Use appropriate tools to put the spilled material into a labeled waste disposal
container. Finish cleaning by spreading water on the contaminated surface and dispose of according to
local and regional regulatory requirements.
SALICYLATES & CHEMICALS PVT. LTD.,
A-25, Road No.18, I.D.A. Nacharam,
Hyderabad - 500 076 – India.
Tel # 91 40 27171550, 27174691
Fax # +91 40 27171249
Email : salipl@satyam.net.in
Visit us : www.preservativesindia.com
7.
HANDLING AND STORAGE
7.1
Handling





Avoid breathing vapors, spray or mists
Keep container closed.
Use with adequate ventilation
Wear suitable protective clothing.
Avoid contact with eyes. Wash thoroughly after handling.



Keep container tightly closed.
Keep container in a cool, well-ventilated area.
Do not store at high temperatures
7.2
Storage
8.
EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1.
Exposure controls
8.2.1.

(a)
Occupational Exposure controls
Use process enclosures, local exhaust ventilation, or other engineering
controls to keep airborne levels below recommended exposure limits. If user
operations generate dust, fume or mist, use ventilation to keep exposure to
airborne contaminants below the exposure limit.
Respiratory protection


Be sure to use NIOSH/ OSHA-approved respirator
government-approved respirator.

Hand protection
Be sure to use an approved/certified or equivalent Gloves
(b)
(c)
Eye protection

Safety glasses, goggles, or face shield recommended.

Splash goggles in case of large spill
(d)
Skin protection



9.
Engineering
Controls
Wear Lab coat
Full suit in case of large spill
Boots in case of large spills
PHYSICAL AND CHEMICAL PROPERTIES
SALICYLATES & CHEMICALS PVT. LTD.,
A-25, Road No.18, I.D.A. Nacharam,
Hyderabad - 500 076 – India.
Tel # 91 40 27171550, 27174691
Fax # +91 40 27171249
Email : salipl@satyam.net.in
Visit us : www.preservativesindia.com
9.1



Physical state
Color
Odor
9.2
General Information
liquid
Yellow
Mild, characteristic
Important health, safety and environmental information






pH(1%
soln/water)
Molecular Weight
Boiling
point/boiling
range
Melting point
Specific Gravity
Flash point

Flammability
(solid, gas)


Auto ignition
point
Vapour pressure
Dispersion
property
Solubility


Water solubility:
Refractive index


10.
NA
361.4767
2000 C
NA
Between 1.045 to 1.055
Non Flammable
Not Applicable
NA
NA
NA
Insoluble
1.561 to 1.571
STABILITY AND REACTIVITY
Stability: Stable under normal conditions of storage and Handling
10.1.

Conditions to avoid:
Strong heating.
10.2.

10.3.


Materials to avoid:
None hazardous decomposition products
Hazardous decomposition products:
Hazardous Decomposition Products: Nitrogen oxides, (NO, NO2)
Polymerisation will not occur.
SALICYLATES & CHEMICALS PVT. LTD.,
A-25, Road No.18, I.D.A. Nacharam,
Hyderabad - 500 076 – India.
Tel # 91 40 27171550, 27174691
Fax # +91 40 27171249
Email : salipl@satyam.net.in
Visit us : www.preservativesindia.com
11.
TOXICOLOGICAL INFORMATION
Acute effects (acute toxicity, irritation and corrosivity)

May cause mild eye irritation

May cause mild skin irritation
Sensitization

No sensitizing effects on human.
CMR effects (carcinogenicity, mutagenicity and toxicity for reproduction)
Not Mutagenic
Test System:: MOUSE LYMPHOMA
Strain Indicator: L5178Y (TK+/TK-)
 Mutagenic
Metabolic Activation: NONE
Effects
Method: SUSPENSION/PLATE
Dose: 0.028-0.38 UG/ML (TEST MATERIAL SOLVENT: DMSO)
Results: NEGATIVE
 Reproductive
No Repro-toxic
toxicity Effects
Component Name
Value
Dose Range 0.0067-0.089 UG/ML (TEST MATERIAL SOLVENT: DMSO)
Metabolic Activation RAT, LIVER, S-9, AROCLOR 1254
Method SUSPENSION/PLATE
Reference [ODIO,MR, AZRI-MEEHAN,S, ROBISON,SH AND KRAUS,AL; EVALUATION OF
SUBCHRONIC (13 WEEK), REPRODUCTIVE, AND IN VITRO GENETIC TOXICITY POTENTIAL
OF 2-ETHYLHEXYL-2-CYANO-3,3-DIPHENYL ACRYLATE (OCTOCRYLENE); FUNDAM. APPL.
TOXICOL. 22(3):355-368, 1994]
Results NEGATIVE
Strain/Indicator L5178Y (TK+/TK-)
Test System MOUSE LYMPHOMA
Other Toxic Effects on Humans:
 Eyes:
May cause irritation


NIOSH Immediately Dangerous To Life or Health Concentration (IDLH): 500 mg/m3
Acute Oral Toxicity, rat: LD50 = >67000mg/kg
SALICYLATES & CHEMICALS PVT. LTD.,
A-25, Road No.18, I.D.A. Nacharam,
Hyderabad - 500 076 – India.
Tel # 91 40 27171550, 27174691
Fax # +91 40 27171249
Email : salipl@satyam.net.in
Visit us : www.preservativesindia.com
12.
ECOLOGICAL INFORMATION
12.1







Ecotoxicity
Inherently Toxic to Aquatic Organisms No
Meets CEPA Categorization Criteria
No
Meets Environmental Criteria for Categorization No
Meets Human Health Criteria
No
Persistent
No
Fish toxicity: LC50 :>10000mg/1/0.5h
Bacterial toxicity: EC50: >100mg/1/48h
12.2
Persistence and degradability
Biodegradation:<20% MITI test Slightly biodegradable
12.3
Bioaccumulative potential

Bioaccumulative: Yes

Bioaccumulation potential is to be (log p(o/w)>3
13.
DISPOSAL CONSIDERATIONS
Waste Disposal
Appropriate method of disposal of substance or preparation dissolve or mix the material with a combustible
solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. Observe all federal,
state, and local environmental regulations
14.
TRANSPORT INFORMATION
Not Regulated
15.
REGULATORY INFORMATION
Classification and Labelling according to REGULATION (EC) No 1272/2008 OF THE EUROPEAN
PARLIAMENT AND OF THE COUNCIL
 U.S. Federal Regulations:
 TSCA 8(a) Pair octocrylene (2-ethylhexyl-2-cyano-3, 3-diphenyl-2-propenoate
 TSCA 8(b) inventory: Octocrylene (2-ethylhexyl-2-cyana-3, 3-diphenyl-2-propenoate
SALICYLATES & CHEMICALS PVT. LTD.,
A-25, Road No.18, I.D.A. Nacharam,
Hyderabad - 500 076 – India.
Tel # 91 40 27171550, 27174691
Fax # +91 40 27171249
Email : salipl@satyam.net.in
Visit us : www.preservativesindia.com
Label elements
GHS Pictogram
Signal Word
Acute
Precautionary Statement
Response
Warning
H316
H320
P262: Do not get in eyes, on skin, or
on clothing
P270: Do not eat, drink or smoke when
using this product
P350: Gently wash with soap and
water
Precautionary Statement
Storage
P403: Store in a well ventilated place
P404: Store in a closed container
Hazard Statement
Precautionary Statement
prevention
Chronic
Other regulatory information

HMIS (Hazardous Materials Identification System) Classification
1 = Temporary or minor injury may occur
0= Minimal Hazard = Materials that will not burn
0 = Minimal Hazard = Materials that are normally stable under fire conditions and will not react to water,
polymerise, decompose, condense or self react
SALICYLATES & CHEMICALS PVT. LTD.,
A-25, Road No.18, I.D.A. Nacharam,
Hyderabad - 500 076 – India.
Tel # 91 40 27171550, 27174691
Fax # +91 40 27171249
Email : salipl@satyam.net.in
Visit us : www.preservativesindia.com
E=

NFPA (National Fire Protection Association)
1 = Health Hazard = Exposure could cause irritation but only minor residual injury even if no treatment is
given.
0 = Flammability = Materials that will not burn.
0 = Instability = Normally stable, even under fire exposure conditions, and are not reactive with water.
16.
OTHER INFORMATION
Technical Advice
 Use data given in this Safety Data Sheet and make an inventory list of all chemicals used in the
factory
 Create a Register for Workplace Chemicals;
 Set priorities concerning the safety in the organization
 Create emergency plans for the assessed hazards;
 Organize occupational health care and regular surveys as necessary;
 Organize contacts with authorities/laboratories to create a monitoring system for chemical hazards,
and to reliably measure and/or estimate occupational exposures to chemicals when needed;
 Start collecting case studies of accidents and sickness records in the enterprise to create a basis
for priority measures in the control of hazards;
 Involve workers in safety organizations, such as the system of Safety Representatives and
Committees.
 Do regular inspection using checklists made for the particular chemicals and chemical processes in
use;
 Mark and label all chemicals;
 Keep at hand an inventory list of all chemicals handled in the place of work together with a
collection of Chemical Safety Data Sheets for these chemicals;
SALICYLATES & CHEMICALS PVT. LTD.,
A-25, Road No.18, I.D.A. Nacharam,
Hyderabad - 500 076 – India.
Tel # 91 40 27171550, 27174691
Fax # +91 40 27171249
Email : salipl@satyam.net.in
Visit us : www.preservativesindia.com






Train workers to read and understand the Chemical Safety Information, including the health
hazards and routes of exposure; train them to handle dangerous chemicals and processes with
respect;
Plan, develop and choose the safe working procedures;
Reduce the number of people coming into contact with dangerous chemicals;
Reduce the length of time and/or frequency of exposure of workers to dangerous chemicals;
Train workers to know and understand the emergency procedures;
Equip and train workers to use personal protective equipment properly after everything possible
has been done to eliminate hazards by means of other methods;
List of relevant R phrases
 R 38/36
Created by
ELC Group
Momaja s.r.o
Krakovska9, Prague1, 11000, CzechRepublic
Tel.+420224910000
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to us. However, we make no warranty of merchantability or any other warranty, express or implied, with
respect to such information, and we assume no liability resulting from its use. Users should make their
own investigations to determine the suitability of the information for their particular purposes. In no event
shall SALICYLATES & CHEMICALS PVT. LTD be liable for any claims, losses, or damages of any third
party or for lost profits or any special, indirect, incidental, consequential or exemplary damages.