SALICYLATES & CHEMICALS PVT. LTD.,
A-25, Road No.18, I.D.A. Nacharam,
Hyderabad - 500 076 – India.
Tel # 91 40 27171550, 27174691
Fax # +91 40 27171249
Email : salipl@satyam.net.in
Visit us : www.preservativesindia.com
SAFETY DATA SHEET
SALIGIN MPS
(SODIUM METHYL PARABEN)
1.Product identifier
Product name: Sodium Methyl Paraben
Product code : SLM3823
EC#: 225-714-1
CAS#: 5026-62-0
EINECS#: 225-714-1
RTECS: DH2455000
Synonyms: Methylparaben, sodium salt; Benzoate, 4-oxide-, methyl, sodium salt;
Benzoic acid, 4-hydroxy-, methyl ester, sodium salt; Benzoic acid, p-hydroxy-, methyl ester,
sodium derivative; Methyl
p-hydroxybenzoate, sodium salt; Sodium 4-(methoxycarbonyl)phenolate.
Chemical Formula : C8 H7 Na O3
Structural Formula :
1.1.

Relevant uses and uses advised against
It is characterized by its high solubility in cold water and is extremely
effective preservatives regularly used in hair styling gels, hair care products
toothpaste and oral care products.
 It can be particularly useful when the heating of aqueous solution is undesirable.

1.2.
With high water solubility, it can be used in aqueous products that cannot be heated.
Details on the supplier of the SDS
SALICYLATES & CHEMICALS PVT. LTD.,
SALICYLATES & CHEMICALS PVT. LTD.,
A-25, Road No.18, I.D.A. Nacharam,
Hyderabad - 500 076 – India.
Tel # 91 40 27171550, 27174691
Fax # +91 40 27171249
Email : salipl@satyam.net.in
Visit us : www.preservativesindia.com
A-25, Road No.18, I.D.A. Nacharam,
Hyderabad - 500 076 – India.
Tel # 91 40 27171550, 27174691
Fax # +91 40 27171249
Email : salipl@satyam.net.in
Visit us : www.preservativesindia.com
1.3.
Emergency telephone number: (EM): give the number of the company (+ working
hours) and emergency number in the country of destination.
2. Hazard identification
2.1. Classification of Substance
2.1.1. Classification according to Regulation (EC) Nr 1272/2008 (CLP/GHS)
Acute Tox. 2: H332
Skin Irrit. 2 : H315
Eye Irrit. 2 : H319
2.1.2. Classification according to Directive 67/548/EEC (DSD):
 R22: Harmful if Swallowed
2.2. Labelling
2.2.1. Labeling according to Regulation (EC) No 1272/2008 (CLP/GHS)
Hazard pictogram:
GHS08: Health
SALICYLATES & CHEMICALS PVT. LTD.,
A-25, Road No.18, I.D.A. Nacharam,
Hyderabad - 500 076 – India.
Tel # 91 40 27171550, 27174691
Fax # +91 40 27171249
Email : salipl@satyam.net.in
Visit us : www.preservativesindia.com
Signal word:
Warning
Hazard statements:
H332
GHS07: Skin and Eye
Signal word:
Warning
Hazard statements:
H315,H319
Precautionary statements:

P262: Do not get in eyes, on skin, or on clothing
2.2.2. Labeling according to Directive 67/548/EEC (DSD):
Hazard statements:
R-phrases:


R22: Harmful if Swallowed
R36/38: Irritating to eyes and skin
Precautionary statements:
S-phrases:


S24 – Avoid contact with skin
S25 - Avoid contact with eyes
SALICYLATES & CHEMICALS PVT. LTD.,
A-25, Road No.18, I.D.A. Nacharam,
Hyderabad - 500 076 – India.
Tel # 91 40 27171550, 27174691
Fax # +91 40 27171249
Email : salipl@satyam.net.in
Visit us : www.preservativesindia.com
2.3. Other hazards
Substance meets the criteria for PBT according to Regulation (EC) 1907/2006, Annex XIII
 No
Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex
XIII:
 No
2.Composition/Information on ingredients
Constituents
Constituent
Sodium Methyl
Paraben
CAS#
5026-62-0
Concentration
100 % (w/w)
4. First Aid Measures
4.1. Description of first aid measures
Inhalation- Move the exposed person to fresh air at once. Keep the affected person warm
and at
rest. Get prompt medical attention.
Ingestion- Rinse mouth thoroughly with water and give large amounts of milk or water to
people
not unconscious. Get medical attention.
Skin- Wash off promptly and flush contaminated skin with water. Promptly remove clothing if
soaked through and flush skin with water.
Eyes- Promptly wash eyes with plenty of water while lifting the eye lids. Contact physician if
irritation persists.
4.2. Most important symptoms and effects, both acute and delayed
The substance is toxic to lungs. Repeated or prolonged exposure to the substance can
produce target organs damage.
4.3. indication of any immediate medical attention and special treatment needed
Not Available
5. Fire fighting measures
Flammability of the Product: May be combustible at high temperature.
SALICYLATES & CHEMICALS PVT. LTD.,
A-25, Road No.18, I.D.A. Nacharam,
Hyderabad - 500 076 – India.
Tel # 91 40 27171550, 27174691
Fax # +91 40 27171249
Email : salipl@satyam.net.in
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Products of Combustion: These products are carbon oxides (CO, CO2). Some metallic
oxides.
Fire Hazards in Presence of Various Substances: Extremely flammable in presence of
open flames and sparks.
Fire Fighting Media and Instructions:
SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray, fog or foam. Do
not use water jet.
6. Accidental release measures:
Small Spill:
Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish
cleaning by spreading water on
the contaminated surface and dispose of according to local and regional authority
requirements.
Large Spill:
Use a shovel to put the material into a convenient waste disposal container. Finish cleaning
by spreading water on the
contaminated surface and allow to evacuate through the sanitary system.
7. Handling and storage
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use
with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with
eyes, skin, and clothing. Avoid ingestion and inhalation. Keep from contact with moist air and
steam.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Store protected from moisture.
8: Exposure Controls/Personal Protection
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a
safety shower. Use adequate ventilation to keep airborne concentrations low.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA’s
eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
SALICYLATES & CHEMICALS PVT. LTD.,
A-25, Road No.18, I.D.A. Nacharam,
Hyderabad - 500 076 – India.
Tel # 91 40 27171550, 27174691
Fax # +91 40 27171249
Email : salipl@satyam.net.in
Visit us : www.preservativesindia.com
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA’s 29 CFR Ì1910.134 and ANSI Z88.2
requirements or European
Standard EN 149 must be followed whenever workplace conditions warrant a respirator’s
use.
8.2 Exposure controls:
Exposure Limits: Not available.
9. Physical and chemical properties
9.1. Information on basic physical and chemical properties
Property
Results
1) odour
Not Available
2) pH, concentration
9,5-10,5
solution
3) Melting / freezing point Not Available
4) Boiling point
Decomposes
5) Vapour density
Not applicable
6) Water solubility
Soluble in cold water.
7) Auto-ignition
The substance is not auto-flammable
temperature
8) Molecular Weight
174.13
9) Physical State
Solid. Crystals or crystalline. Plates.
10) Corrosivity
Non-corrosive in presence of glass, of steel, of stainless
steel(304), of stainless steel(316).
SALICYLATES & CHEMICALS PVT. LTD.,
A-25, Road No.18, I.D.A. Nacharam,
Hyderabad - 500 076 – India.
Tel # 91 40 27171550, 27174691
Fax # +91 40 27171249
Email : salipl@satyam.net.in
Visit us : www.preservativesindia.com
10. Stability and Reactivity
10.1. Reactivity
No details have been found
10.2. Chemical stability
Stable under normal temperatures and pressures.
10.3. Possibility of hazardous reactions
Strong oxidants.
10.4. Conditions to avoid
Incompatible materials, strong oxidants, exposure to moist air or
water.
10.5. Incompatible materials
Avoid: Contact with alkalis. Normally stable. Hygroscopic.
10.6. Hazardous decomposition products
Fire or high temperatures create: Very toxic gases/vapours/fumes of: Carbon monoxide
(CO). Carbon dioxide (CO2).
11. Toxicological Information
Acute toxicity
Product/ingredient Result
name
Sodium Methyl
LD50 Oral
Paraben
Species
Dose
Exposure
Rat
2000
mg/kg
NA
Irritation/Corrosion
Skin: Slightly Hazardous
Eye: Hazardous
Respiratory tract: Very hazardous in case of inhalation.
SALICYLATES & CHEMICALS PVT. LTD.,
A-25, Road No.18, I.D.A. Nacharam,
Hyderabad - 500 076 – India.
Tel # 91 40 27171550, 27174691
Fax # +91 40 27171249
Email : salipl@satyam.net.in
Visit us : www.preservativesindia.com
Sensitization
Skin disorders and allergies.
Germ cell mutagenicity
No biologically relevant genotoxic activity
Carcinogenicity
No experimental or epidemiological evidence exists to justify classification of sodium
compounds for carcinogenic activity
Reproductive toxicity
No experimental or epidemiological evidence exists to justify classification of sodium
compounds for reproductive or developmental toxicity
Specific target organ toxicity (single exposure)
No experimental or epidemiological sufficient evidence for specific target organ
toxicity
Specific target organ toxicity (repeated exposure)
No experimental or epidemiological sufficient evidence for specific target organ
toxicity
12. Ecological Information
12.1. Toxicity
Not available.
12.2. Persistence and biodegradability
Possibly hazardous short term degradation products are not likely. However, long term
degradation products may arise.
SALICYLATES & CHEMICALS PVT. LTD.,
A-25, Road No.18, I.D.A. Nacharam,
Hyderabad - 500 076 – India.
Tel # 91 40 27171550, 27174691
Fax # +91 40 27171249
Email : salipl@satyam.net.in
Visit us : www.preservativesindia.com
12.3. Bioaccumulative potential
The products of degradation are more toxic. Decomposes and burns to form smoke, carbon
monoxide and carbon dioxide. Fine dust dispersed in air in sufficient concentrations, and in
the presence of an ignition source is s potential dust explosion hazard.
12.4. Results of PBT and vPvB assessment
No information has been found
13. Disposal Considerations
Material in the elemental state should be recovered for reuse or recycling. Contact a
licensed professional waste disposal service to dispose of this material. Observe all federal,
state, and local environmental regulations.
14. Transport Information
DOT Classification: Not a DOT controlled material (United States).
Identification: Not applicable.
Special Provisions for Transport: Not applicable.
IATA
No information available.
IMO
No information available.
RID/ADR
No information available.
15. Regulatory Information
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases: R 22 Harmful if swallowed.
R36 Irritating to eyes
Safety Phrases: S24 – Avoid contact with skin
S25 - Avoid contact with eyes
SALICYLATES & CHEMICALS PVT. LTD.,
A-25, Road No.18, I.D.A. Nacharam,
Hyderabad - 500 076 – India.
Tel # 91 40 27171550, 27174691
Fax # +91 40 27171249
Email : salipl@satyam.net.in
Visit us : www.preservativesindia.com
Other regulatory information
HMIS (Hazardous Materials Identification System) Classification
2 = Moderate Hazard = Temporary or minor injury may occur
1= Slight Hazard = Materials that must be preheated before ignition will occur. Includes liquids,
solids and semi solids having a flash point above 200 F. (Class IIIB)
0 = Minimal Hazard = Materials that are normally stable under fire conditions and will not react to water,
polymerise, decompose, condense or self react
E=
NFPA (National Fire Protection Association)
2= Health Hazard = Intense or continued exposure could cause temporary incapacitation or possible
residual injury unless prompt medical attention is given.
1= Flammability = Must be preheated before ignition can occur.
0 = Instability = Normally stable, even under fire exposure conditions, and are not reactive with water.
Protective Equipment:
Gloves. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or
equivalent. Splash goggles.
16. Other Information

Use data given in this Safety Data Sheet and make an inventory list of all chemicals used in the
factory
SALICYLATES & CHEMICALS PVT. LTD.,
A-25, Road No.18, I.D.A. Nacharam,
Hyderabad - 500 076 – India.
Tel # 91 40 27171550, 27174691
Fax # +91 40 27171249
Email : salipl@satyam.net.in
Visit us : www.preservativesindia.com
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Create a Register for Workplace Chemicals;
Set priorities concerning the safety in the organization
Create emergency plans for the assessed hazards;
Organize occupational health care and regular surveys as necessary;
Organize contacts with authorities/laboratories to create a monitoring system for chemical hazards,
and to reliably measure and/or estimate occupational exposures to chemicals when needed;
Start collecting case studies of accidents and sickness records in the enterprise to create a basis
for priority measures in the control of hazards;
Involve workers in safety organizations, such as the system of Safety Representatives and
Committees.
Do regular inspection using checklists made for the particular chemicals and chemical processes in
use;
Mark and label all chemicals;
Keep at hand an inventory list of all chemicals handled in the place of work together with a
collection of Chemical Safety Data Sheets for these chemicals;
Train workers to read and understand the Chemical Safety Information, including the health
hazards and routes of exposure; train them to handle dangerous chemicals and processes with
respect;
Plan, develop and choose the safe working procedures;
Reduce the number of people coming into contact with dangerous chemicals;
Reduce the length of time and/or frequency of exposure of workers to dangerous chemicals;
Train workers to know and understand the emergency procedures;
Equip and train workers to use personal protective equipment properly after everything possible
has been done to eliminate hazards by means of other methods;
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