SALICYLATES & CHEMICALS PVT. LTD.,
A-25, Road No.18, I.D.A. Nacharam,
Hyderabad - 500 076 – India.
Tel # 91 40 27171550, 27174691
Fax # +91 40 27171249
Email : salipl@satyam.net.in
Visit us : www.preservativesindia.com
Safety Data Sheet
Saligin PP
1.
IDENTIFICATION OF THE SUBSTANCE AND OF THE COMPANY
1.1

EC#
Identification of the substance
202-307-7

CAS#
94-13-3

NIOSH, Registry
of Toxic Effects
(RTECS)
Identification
Number
DH280000


Substance
Name
Synonym:
Benzoic acid, 4-hydroxy-, propyl ester
Propyl p-hydroxybenzoate

Chemical
Formula

Cosmetics

Hair care

Preservative

The recommended use level is 0.10.6% by weight of product as supplied.

It is easy to handle, very stable and cost-effective.

It is stable over a wide range of pH and temperature conditions

It does not discolor product when combined with additives or by changes in pH.
1.2
1.3
Propyl Praben (Propyl 4-hydroxybenzoate)
C10H12O3
Use of the substance/mixture
Company/undertaking identification
1
SALICYLATES & CHEMICALS PVT. LTD.,
A-25, Road No.18, I.D.A. Nacharam,
Hyderabad - 500 076 – India.
Tel # 91 40 27171550, 27174691
Fax # +91 40 27171249
Email : salipl@satyam.net.in
Visit us : www.preservativesindia.com


The person
responsible for
placing the
substance on
the market
within
Community
Full address

Telephone No.

Emergency
telephone
number of the
company
Specification if
this phone
number is
available only
during office
hours
1.4
SALICYLATES & CHEMICALS PVT. LTD
A-25, ROAD NO.18, IDA NACHARAM,
HYDERABAD – 500 076
ANDHRA PRADESH
INDIA
+91- 40-27171550, 27174691
Emergency telephone

2.
+91- 40-27171550, 27174691
HAZARDS IDENTIFICATION
Classification according to REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND
OF THE COUNCIL
Skin Irr. 2
 Hazard Class
and Category
Eye Irr.2
Code(s)
Resp. Sens. 1
 Hazard statement H315
Code(s)
H319
H334
Most important adverse physicochemical, human health and environmental effects and symptoms
relating to the uses and possible misuses of the mixture that can reasonably be forseen

May be harmful in case of inhalation.

CARCINOGENIC EFFECTS: None found

Slightly harmful in the aquatic environment or are otherwise designed for biocidal action

Causes irreversible eye damage
2
SALICYLATES & CHEMICALS PVT. LTD.,
A-25, Road No.18, I.D.A. Nacharam,
Hyderabad - 500 076 – India.
Tel # 91 40 27171550, 27174691
Fax # +91 40 27171249
Email : salipl@satyam.net.in
Visit us : www.preservativesindia.com
Substance
Name
Propyl 4hydroxyben
zoate
CAS#
94-13-3
EC#
202-307-7
Hazard
Class and
Category
Code(s)
Hazard
statement
Code(s)
Percentage
by weight
Risk
phrases
100%
R 37
Resp.
Sens. 1
H334
R 36/38
Skin Irr. 2
Eye Irr. 2
H315,
H319
Pictogram,
Signal
Word
Code(s)
Wng
Wng
3 COMPOSITION / INFORMATION ON INGREDIENTS.
Propyl 4-hydroxybenzoate
4.
94-13-3
100%
FIRST AID MEASURES
Subdivision of information according to route of exposure
 Eye contact
Check for and remove any contact lenses.

Skin Contact

Serious Skin
Do not use an eye ointment
Seek medical attention
After contact with skin, wash immediately with plenty of water.
Gently and thoroughly wash the contaminated skin with running water and
non-abrasive soap.
Be particularly careful to clean folds, crevices, creases and groin.
Cover the irritated skin with an emollient.
If irritation persists, seek medical attention.
Wash contaminated clothing before reusing.
Wash with a disinfectant soap and cover the contaminated skin with an antibacterial cream
3
SALICYLATES & CHEMICALS PVT. LTD.,
A-25, Road No.18, I.D.A. Nacharam,
Hyderabad - 500 076 – India.
Tel # 91 40 27171550, 27174691
Fax # +91 40 27171249
Email : salipl@satyam.net.in
Visit us : www.preservativesindia.com
Contact
Seek medical attention.

Inhalation

Serious
Inhalation
Allow the victim to rest in a well ventilated area.
Seek medical attention.
Evacuate the victim to a safe area as soon as possible.
Loosen tight clothing such as a collar, tie, belt or waistband.
If breathing is difficult, administer oxygen.
If the victim is not breathing, perform mouth-to-mouth resuscitation.

Ingestion
5.
Seek medical attention.
Do not induce vomiting.
Loosen tight clothing such as a collar, tie, belt or waistband.
If the victim is not breathing, perform mouth-to-mouth resuscitation.
Seek medical attention.
FIRE-FIGHTING MEASURES
Suitable extinguishing media


SMALL FIRE
LARGE FIRE
Other information
 Flammability of
the Product
 Products of
Combustion
6.
Use DRY chemical powder or carbon dioxide.
Use water spray or fog.
Cool containing vessels with water jet in order to prevent pressure
build-up, autoignition or explosion.
During a fire,highly toxic and irritating gases carbon oxides (CO, CO2) may
be generated
Non Flammable
Products of combustion are toxic. At high temperatures, this will release CO
and Co2
ACCIDENTAL RELEASE MEASURES
Methods for cleaning up:
Use appropriate tools to put the spilled solid in a convenient waste disposal
 Small Spill
container. Finish cleaning by spreading water on the contaminated surface
and dispose of according to local and regional authority requirement
Wear appropriate protective equipment and NIOSH/MSHA approved
 Large Spill
respirator where mists or vapors of unknown concentrations may be
generated (self-contained breathing apparatus preferred)
4
SALICYLATES & CHEMICALS PVT. LTD.,
A-25, Road No.18, I.D.A. Nacharam,
Hyderabad - 500 076 – India.
Tel # 91 40 27171550, 27174691
Fax # +91 40 27171249
Email : salipl@satyam.net.in
Visit us : www.preservativesindia.com
Dike and contain spill with inert material (sand, earth, etc.) and transfer the
powder to containers for recovery or disposal
Keep spill out of sewers and open bodies of water
7.
HANDLING AND STORAGE
7.1
Handling








Keep locked up Keep away from heat.
Keep away from sources of ignition.
Ground all equipment containing material.
Do not ingest.
Do not breathe dust.
Wear suitable protective clothing In case of insufficient ventilation.
Wear suitable respiratory equipment if ingested, seek medical advice immediately and show the
container or the label.
Avoid contact with skin and eyes
7.2
Storage



Keep away from heat.
Keep away from sources of ignition.
Keep container tightly closed




Keep in a cool, well-ventilated place
Ground all equipment containing material.
Keep container dry.
Keep in a cool place.
8.
EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1
Exposure limit values
No Limits have been found from OSHA
Consult local authorities for acceptable exposure limits.
Source
OEL
8.2
Type
TWA
OEL
LLV
Value
No Limits have been found
No Limits have been found
No Limits have been found
Exposure controls
5
SALICYLATES & CHEMICALS PVT. LTD.,
A-25, Road No.18, I.D.A. Nacharam,
Hyderabad - 500 076 – India.
Tel # 91 40 27171550, 27174691
Fax # +91 40 27171249
Email : salipl@satyam.net.in
Visit us : www.preservativesindia.com
8.2.1

Occupational Exposure controls
Engineering
Controls
Use process enclosures, local exhaust ventilation, or other engineering
controls to keep airborne levels below recommended exposure limits.
If user operations generate dust, fume or mist, use ventilation to keep
exposure to airborne contaminants below the exposure limit.
Respiratory protection
(a)



Dust respirator
Be sure to use an approved/certified respirator
A self contained breathing apparatus should be used to avoid inhalation of the product.
(b)
Eye protection

Splash goggles
(c)
Skin protection



Lab coat
Be sure to use approved/certified or equivalent Gloves.
Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this
product.
9.
PHYSICAL AND CHEMICAL PROPERTIES
9.1


Physical state
Color
9.2
General Information
Solid
White
Important health, safety and environmental information
Not Available
180.2 g/mol
96°C (204.8°F
Soluble in methanol, diethyl ether, acetone. Very slightly soluble in
cold water, hot water
Not Known
68 deg C
1.063 (Water = 1



pH at 250C
Molecular Weight
Melting Point

Solubility



Density
Boiling point
Specific Gravity

Stability: The product is stable.
10.
STABILITY AND REACTIVITY
6
SALICYLATES & CHEMICALS PVT. LTD.,
A-25, Road No.18, I.D.A. Nacharam,
Hyderabad - 500 076 – India.
Tel # 91 40 27171550, 27174691
Fax # +91 40 27171249
Email : salipl@satyam.net.in
Visit us : www.preservativesindia.com
10.1 .


Materials to avoid:
Oxidising agents
Mineral acids
.
Note

Corrosivity: Non-corrosive in presence of glass, steel, stainless steel(304), stainless steel(316).

Polymerization: No.
11.
TOXICOLOGICAL INFORMATION
Acute effects (acute toxicity, irritation and corrosivity)

The substance (as fume or dust) is mildly irritating to the respiratory tract.
Sensitisation

May cause allergic skin reaction.
CMR effects (carcinogenicity, mutagenicity and toxicity for reproduction)
 Carcinogenic
None Found
Effects
Other Toxic Effects on Humans:
The substance is toxic to lungs
 Lungs

ORAL LD50(RAT) : LD50 = 6332 mg/kg.

DERMAL(RABBIT): MILD IRRITANT

EYES(RABBIT) : MILD IRRITANT

INHALATION LD50(RAT ): No information found
12.
ECOLOGICAL INFORMATION
12.1.
Ecotoxicity
No information has been found
7
SALICYLATES & CHEMICALS PVT. LTD.,
A-25, Road No.18, I.D.A. Nacharam,
Hyderabad - 500 076 – India.
Tel # 91 40 27171550, 27174691
Fax # +91 40 27171249
Email : salipl@satyam.net.in
Visit us : www.preservativesindia.com
12.2.

Bioaccumulative potential
Not bioaccumulative
12.3.

Products of Biodegradation
Using a Zahn-Wellens test(2), which requires a 0.2 - 1.0 g/L dry inolculum and 50-400 dissolved
organic carbon/L test concentration(1), analogous methylparaben degraded 100% after 6 days with
a 2 day acclimation period in a sludge inoculum(2), suggesting that propylparaben may be subject
to biodegradation(SRC).
12.4.

Toxicity of the Products of Biodegradation
The products of degradation are as harmful as the original product.
13.
DISPOSAL CONSIDERATIONS
Substance Disposal
 Material in the elemental state should be recovered for reuse or recycling. Contact a licensed
professional waste disposal service to dispose of this material. Observe all federal, state, and local
environmental regulations.
14.
TRANSPORT INFORMATION

DOT(Departmen
t of
Transportation)
Classification
Not classified

Identification
Shipping name: Propyl Paraben

RID(Regulations
Concerning the
International
Transport of
Dangerous
Goods by Rail)
/ADR(Agreemen
t on Dangerous
Goods by Road)
IMDG( Internatio
nal Maritime
Dangerous
Goods)
IATA(Internation
al Air Transport
Non-hazardous for road transport


Non-hazardous for sea transport
Non-hazardous for air transport
8
SALICYLATES & CHEMICALS PVT. LTD.,
A-25, Road No.18, I.D.A. Nacharam,
Hyderabad - 500 076 – India.
Tel # 91 40 27171550, 27174691
Fax # +91 40 27171249
Email : salipl@satyam.net.in
Visit us : www.preservativesindia.com
Association)

UN number
15.
REGULATORY INFORMATION
Classification and Labelling according to REGULATION (EC) No 1272/2008 OF THE EUROPEAN
PARLIAMENT AND OF THE COUNCIL
 Respiratory and Skin sensitisation
Label elements
GHS Pictogram
Signal Word
Hazard Statement
Precautionary
Statement prevention
Respiratory sensitisation
Skin sensitisation
Warning
Warning
H334: May cause allergy or asthma
symptoms or breathing difficulties if
inhaled
P261: Avoid breathing dust/fume/
gas/mist/vapours/spray.
H315: Causes skin irritation
H319: Causes serious eye irritation
P285: In case of inadequate
ventilation wear respiratory protection.
P272: Contaminated work clothing
should not be allowed out of the
workplace.
P261: Avoid breathing dust/fume/
gas/mist/vapours/spray
P280: Wear protective
gloves/protective clothing/eye
protection/face protection.
Precautionary
Statement Response
P304 + P341: IF INHALED: If
breathing is difficult, remove victim to
fresh air and keep at rest in a position
comfortable for breathing.
P342+ P311: symptoms: Call a
POISON CENTER or
doctor/physician.
P302 + P352: IF ON SKIN: Wash with
plenty of soap and water.
P333 + P313: If skin irritation or rash
occurs: Get medical advice/
attention.
P321: Specific treatment as per first
aid measure.
P363: Wash contaminated clothing
before reuse.
Precautionary
Statement Storage
Precautionary
P501: Dispose of contents/container
P501: Dispose of contents/container
9
SALICYLATES & CHEMICALS PVT. LTD.,
A-25, Road No.18, I.D.A. Nacharam,
Hyderabad - 500 076 – India.
Tel # 91 40 27171550, 27174691
Fax # +91 40 27171249
Email : salipl@satyam.net.in
Visit us : www.preservativesindia.com
Statement Disposal

in accordance with
local/regional/national/international
regulation
in accordance with
local/regional/national/international
regulation
May be harmful to the aquatic environment
Other regulatory information

HMIS (Hazardous Materials Identification System) Classification
2 = Moderate Hazard = Temporary or minor injury may occur
1= Minimal Hazard = Materials that must be preheated before ignition will occur.
0 = Minimal Hazard = Materials that are normally stable under fire conditions and will not react to water,
polymerise, decompose, condense or self react
E=

NFPA (National Fire Protection Association)
2= Health Hazard = Intense or continued exposure could cause temporary incapacitation or possible
residual injury unless prompt medical attention is given.
10
SALICYLATES & CHEMICALS PVT. LTD.,
A-25, Road No.18, I.D.A. Nacharam,
Hyderabad - 500 076 – India.
Tel # 91 40 27171550, 27174691
Fax # +91 40 27171249
Email : salipl@satyam.net.in
Visit us : www.preservativesindia.com
1= Flammability = Must be preheated before ignition can occur.
0 = Instability = Normally stable, even under fire exposure conditions, and are not reactive with water.
 Federal and State Regulations
No information found
 OSHA
No information found
16.
OTHER INFORMATION
Technical Advice
 Use data given in this Safety Data Sheet and make an inventory list of all chemicals used in the
factory
 Create a Register for Workplace Chemicals;
 Set priorities concerning the safety in the organization
 Create emergency plans for the assessed hazards;
 Organize occupational health care and regular surveys as necessary;
 Organize contacts with authorities/laboratories to create a monitoring system for chemical hazards,
and to reliably measure and/or estimate occupational exposures to chemicals when needed;
 Start collecting case studies of accidents and sickness records in the enterprise to create a basis
for priority measures in the control of hazards;
 Involve workers in safety organizations, such as the system of Safety Representatives and
Committees.
 Do regular inspection using checklists made for the particular chemicals and chemical processes in
use;
 Mark and label all chemicals;
 Keep at hand an inventory list of all chemicals handled in the place of work together with a
collection of Chemical Safety Data Sheets for these chemicals;
 Train workers to read and understand the Chemical Safety Information, including the health
hazards and routes of exposure; train them to handle dangerous chemicals and processes with
respect;
 Plan, develop and choose the safe working procedures;
 Reduce the number of people coming into contact with dangerous chemicals;
 Reduce the length of time and/or frequency of exposure of workers to dangerous chemicals;
 Train workers to know and understand the emergency procedures;
 Equip and train workers to use personal protective equipment properly after everything possible
has been done to eliminate hazards by means of other methods;
List of relevant R phrases
Irritating to respiratory system
 R37
Irritating to eyes and skin
 R36/38
11
SALICYLATES & CHEMICALS PVT. LTD.,
A-25, Road No.18, I.D.A. Nacharam,
Hyderabad - 500 076 – India.
Tel # 91 40 27171550, 27174691
Fax # +91 40 27171249
Email : salipl@satyam.net.in
Visit us : www.preservativesindia.com
Created By:
ELC GROUP
momaja s.r.o.
Krakovska 9, Prague 1, 110 00
Czech Republic Tel. +420 22 491 0000
Fax. +420 22 491 0671
Contact Person
Jastin Sardhara
The information above is believed to be accurate and represents the best information currently available
to us. However, we make no warranty of merchantability or any other warranty, express or implied, with
respect to such information, and we assume no liability resulting from its use. Users should make their
own investigations to determine the suitability of the information for their particular purposes. In no event
shall Salicylates and Chemical Pvt. Ltd. be liable for any claims, losses, or damages of any third party or
for lost profits or any special, indirect, incidental, consequential or exemplary damages.
12