Lab 5 Chemical formulas Concepts – – – – – Formula vs molecular weight % composition from formula The mole Empirical formula Atomic weight Formula Weight Formula weight – the mass of the collection of atoms represented by a chemical formula. For Ex. water contains two hydrogen atoms and one oxygen atom. 1 x 16.00 (mass of O) = 16.00 2 x 1.01 (mass of H) = + 2.02 Formula Weight 18.02 The formula weight tells us the mass of one mole of our substance. Gram Formula Weight This refers to the mass of an ionic compound ion or Ex. Mass of a Cl- Gram Atomic Weight This refers to the mass of a Ex. Mass of a Cl atom atom Gram Molecular Weight molecule or molecular compound This refers to the mass of a Ex. Mass of one molecule of H2O A. What is the Mole? • A counting number (like a dozen) • Avogadro’s number (NA) • 1 mol = 6.02 1023 items A large amount!!!! B. Molar Mass • Mass of 1 mole of an element or compound. • Atomic mass tells the... – atomic mass units per atom (amu) – grams per mole (g/mol) • Round to 2 decimal places B. Molar Mass Examples • carbon 12.01 g/mol • aluminum 26.98 g/mol • zinc 65.39 g/mol B. Molar Mass Examples • water – H2O – 2(1.01) + 16.00 = 18.02 g/mol • sodium chloride – NaCl – 22.99 + 35.45 = 58.44 g/mol C. Molar Conversion Examples • How many moles of carbon are in 26 g of carbon? 26 g C 1 mol C 12.01 g C = 2.2 mol C C. Molar Conversion Examples • How many molecules are in 2.50 moles of C12H22O11? 2.50 mol 6.02 1023 molecules 1 mol = 1.51 1024 molecules C12H22O11 Part A • Fill in data given by teacher – Mass of zinc = .45g – Mass of zinc chloride = .94 grams • Based on data given determine – Mass of chlorine – Empirical formula for zinc chloride – Balanced chemical equation for zinc and HCl • Hint: the rxn releases H2 gas Part B • Clean and mass a evaporating dish based on procedures from pg 52 • Get a 2.00g of copper and place into the crucible ** Sulfur must be treated in the hood at all times** • Add sufficent sulfur to cover the copper • Determine mass of copper sulfide • Determine mass of sulfur How to Determine Empirical Formula from data in 3 easy steps 1. Determine the # of moles present for each reactant based on the initial grams present Example data Cu = 2.0 g S = 1.0 grams CuS =3.0 grams For my trial 2.0 grams Cu = 1.0 grams S = .031 moles .032 moles How to Determine Empirical Formula from data 2. Divide both by the smaller # of moles For my trial S: .032 mols of S = 1.03 .031 mols of Cu For my trial Cu: . 031 mols of Cu = 1.00 . 031 mols of Cu How to Determine Empirical Formula from data 3. Determine Empirical Formula based on mole to mole ratio Rule # 1 – round to 1 sig fig Ex. 1.03 of S = 1 1.00 of Cu =1 Final answer is CuS How to Determine Empirical Formula from data Rule # 2 – if mole comes out as a fraction multiply both numbers to next whole number Ex. 1.5 x 2 of S = 3 1.0x 2 of Cu =2 Final answer is Cu2S3 Due next week • Pgs 55 – 57 • Quiz on lab 6