Unit: Alkenes and Alkene reactions Lesson Plan Title: Markovnikov Addition and Carbocation rearrangement Concept / Topic o Teach: Addition of acid across a double bond. Carbocation formation and stability. Standards Addressed: General Goal(s): To learn about Markovnikov addition, what it means, and carbocations. Specific Objectives: To learn how to add HX across a double-bond, to learn why H adds to the less substituted Carbon and to introduce the possibility of Carbocation rearrangement to a more stable state. Required Materials: Computer, projector, Smart board. Anticipatory Set (Lead-In): How to name alkenes, where alkenes are reactive, what a carbocation is. Step-By-Step Procedures: 1) Start with a simple alkene. 2) Show how HX is added across the double bond. Make sure to note that it can add any way in terms of chirality and on either side of a simple alkene. 3) Start with an alkene but with one side of the double bond with a mono-substituted carbon and one with a bi-substituted carbon 4) Move to an alkene with a tertiary component away from the double bond. Show that the chlorine attaches to the most substituted carbon. 5) Describe carbocation creation and rearrangement and stability. 6) Use the carbocation question as a quick quiz. If a majority of students choose the wrong answer, use a simple problem and work way up to tougher problem. If most students choose the right answer, give an easy and a hard problem, and have them work it out on their own (Then help students who chose the wrong answers). 7) Make up problems 8) Easy Example: Is this the most stable carbocation? H3C + CH H3C CH3 9) Difficult Example: Where will the most stable carbocation form? CH3 CH3 CH3 CH3 CH3 CH3 Plan For Independent Practice: Give three different alkenes. Ask for the products of alkene + HX. Give a few carbocations and ask for them to be listed from most to least stable. Closure (Reflect Anticipatory Set): Show them the addition of H2O across a double bond. Still Markovnikov addition. Assessment Based On Objectives: Quiz the next day Adaptations (For Students With Learning Disabilities): Put the powerpoints, complete with animations, online. Put all notes pertaining to the animations online as well. Lesson on smartboard, as well as all voice, will be recorded on the smartboard and put online. Extensions (For Gifted Students): Possible Connections To Other Subjects: