Hannah Ambinder & Lauren Stone Naming Compounds -Ionic compounds are made up of metals and nonmetals, which form cations and anions. Together, their net charge must equal zero. The metal goes first, and the ending “-ide” gets added to the nonmetal. Example: NaCl is written as sodium chloride. If the compound contains a polyatomic ion, do not change anything. Example: LiNO3 is written as lithium nitrate. Use roman numerals to indicate the number of valence electrons in transition metals. Example: Fe(OH)2 is written as iron (II) hydroxide. Aluminum (III), Zinc (II), and Silver (I) are all exceptions to this rule. If there is a hydrate in a compound, you must use number prefixes. Follow the format of compound · prefix-hydrate. Example: CuSO4 · 5H2O is copper (II) sulfate pentahydrate. -Covalent compounds are formed from multiple nonmetals, and include acids, bases, and organic compounds. Name the element furthest left or closest to the bottom of the period table first. Use number prefixes on both words, but do not write “mono” on the first word. Drop double vowels. Example: CO2 is written as carbon dioxide. Acid is a substance that yields H+ ions when dissolved in water. If there is a hydrogen ion at the front of the formula, you should name it as an acid. There are two types of acids. o Binary acids are composed of two elements, usually hydrogen and a halogen. To name them, use the format hydro-element name-ic acid. Example: HCl is written as hydrochloric acid. o Oxyacids are formed from hydrogen, oxygen, and a third element. To name one, you must know the name of the polyatomic ion that it contains. If the polyatomic ends with “–ate,” change the ending to “–ic.” HNO3 is written as nitric acid. If the polyatomic ends with “–ite,” change the ending to “–ous.” H2SO3 is written as sulfurous acid. o If a covalent compound contains OH-, name it as a base. Do not use number prefixes to name bases. Example: NaOH is written simply as sodium hydroxide. Hannah Ambinder & Lauren Stone Mixed Practice Problems 1. CuCO3 2. CCl4 3. Li2O 4. HBr 5. LiClO4 · 3H2O 6. H2SO3 7. Sc2(SO4)3 8. HClO 9. MgSO4 10. Al2O3 11. NH4OH 12. PCl5 13. Ba3(PO4)2 14. MgI2 15. LiOH 16. HF 17. AgCH3COO 18. N2O3 19. NiSO4 · 6H2O 20. HC2H3O2 Hannah Ambinder & Lauren Stone Answer Key 1. Copper (II) carbonate 2. Carbon tetrachloride 3. Lithium oxide 4. Hydrobromic acid 5. Lithium perchlorate trihydrate 6. Sulfurous acid 7. Scandium (III) sulfate 8. Hypochlorous acid 9. Magnesium sulfate 10. Aluminum oxide 11. Ammonium hydroxide 12. Phosphorous pentachloride 13. Barium phosphate 14. Magnesium iodide 15. Lithium hydroxide 16. Hydrofluoric acid 17. Silver acetate 18. Dinitrogen trioxide 19. Nickel (II) sulfate hexahydrate 20. Acetic acid