RAMAS 2004-2005 Earth-System Science Techniques Guide: Elgered Gunnar kge@oso.chalmers.se Names: Billade Bhushan Lagadrillière Pierre-Alexis Moya Espinosa Alain-Michael Rizwana Begum Vaquero Maria-Jose bhusman@student.chalmers.se pierreal@student.chalmers.se moyaespi@dd.chalmers.se begum@student.chalmers.se vaqueroh@student.chalmers.se 2 I.Introduction:....................................................................................................................5 II.Atmosphere History:.......................................................................................................6 III.Structure and functions of each layer of the atmosphere:..........................................7 III.1.Layers:....................................................................................................................7 III.1.1.Ionosphere:........................................................................................................7 III.1.2.Mesosphere:......................................................................................................9 III.1.3.Stratosphere:.....................................................................................................9 III.1.4.Troposphere:...................................................................................................11 III.2.Winds:..................................................................................................................11 III.2.1.Newton's Law : ..............................................................................................12 III.2.2.Air pressure gradient : ....................................................................................13 III.2.3.Coriolis Effect :...............................................................................................13 III.2.4.Frictional Force...............................................................................................14 III.2.5.Convergent and Divergent Flow.....................................................................14 III.2.6.Global Circulation:..........................................................................................15 III.3.Temperature :......................................................................................................17 III.3.1.Simple model of the decrease of the temperature in the troposphere:............19 III.3.2.Temperature records:......................................................................................19 III.3.3.Simple models of the world’s mean temperatures:.........................................21 IV.Interactions with biosphere, geosphere, and hydrosphere:.......................................22 IV.1.Interaction between atmosphere and biosphere:..............................................22 IV.1.1.Effect of deep rooted vegetation:....................................................................22 IV.1.2.Greenhouse effect:..........................................................................................22 IV.1.3.Effect of pollution:..........................................................................................24 IV.2.Interactions between atmosphere and hydrosphere: ......................................25 IV.2.1.Effect of water vapour:...................................................................................25 IV.2.2.Effect of water, ice caps, sea ice:....................................................................25 IV.2.3.Effect of volcanoes on atmosphere:................................................................26 3 IV.3.The Hydrologic cycle:..........................................................................................27 IV.3.1.Water reservoirs:.............................................................................................28 IV.3.2.Pathways:........................................................................................................28 IV.3.3.Anthropologic effects:....................................................................................29 IV.3.4.The energy budget of the atmosphere:............................................................30 V.Measurements techniques:...........................................................................................31 V.1.Measurement of different elements:....................................................................31 V.2.Wind Speed :.........................................................................................................32 V.3.Balloons and rockets:............................................................................................33 VI.References:..................................................................................................................35 VI.1.Bibliography:.......................................................................................................35 VI.2.Internet resources:...............................................................................................35 4 I. Introduction: In this report, we will describe the most important aspects of the atmosphere. It is the result of an investigation done in the course Earth Science techniques, in parallel with investigations on the biosphere, geosphere and hydrosphere made by other groups. The atmosphere is dated back to about 5 billion years, when the earths interior began outgasing and forming a primitive atmosphere. The atmosphere evolved from that to a complex structure of different layers. From the highest , the Ionosphere of about 600 km,, to the lowest Troposphere, the atmosphere has a specific purpose for the function of all earth systems. As it interacts with all other spheres earlier mentioned, it gives life the proper ambient to exist. Temperatures, composition, pressures are described here to give a rough idea on how the atmosphere works, and also to show that the atmosphere is quite delicate to our interventions. Finally we also mention some about the techniques used for measuring different parameters. 5 II. Atmosphere History: Earth was believed to be formed about 5 billion years ago. At that time, it was just a hot body of lava, gases present that time were mainly hydrogen and helium. Over the time, temperature decreased and earth' s crust was formed, containing hot lava underneaths, which resulted into volcanic activity. During first 500 million years, dense atmosphere was formed because of the volcanic activity and degassing from interior of earth. This atmosphere was retained because of earth's gravity. The early atmosphere was mostly dominated by carbon dioxide, and other gases like H2, water vapor, CH4 and N2. Atmosphere of the Venus is a good example of earth' s atmosphere at that time. Around after 1 billion years hydrosphere was formed because of the condensation of water vapor, rain began to fill low areas forming first ocean. In ancient environment there was no free oxygen, as evidenced by ancient rocks that contained elements such as Iron, Uranium in their reduced states. Around about one billion year ago, aquatic micro organisms were formed. These micro organisms called blue­green algae or Cyano­bacteria started using energy from the sun light to split molecules of H2O and CO2 and recombine them into organic compound and Oxygen this was the First Photosynthesis process. Some of the oxygen recombined with metals and carbon forming their oxides and some oxygen remain in atmosphere. Over the time oxygen in atmosphere increased and CO2 decreased. In higher part of atmosphere, some oxygen molecules, after interacting with UV rays of sun light, split up into single oxygen atoms. These single atoms combined with O2 and formed ozone layer in upper atmosphere. Ozone layer is believed to have in existence since 600 million years. Prior to this life was restricted to Oceans only. Presence of Ozone layer helped the organism to develop their life on land. ( Ref: II ) 6 III. Structure and functions of each layer of the atmosphere: III.1. Layers: The atmosphere changes from the ground up and four distinct layers have been identified depending on the temperature changes, chemical composition, movement, density, and ionization. The following figure shows the different layers of the atmosphere: Jet streams Figure 1: The 4 layers of the atmosphere ( Ref: III.1) Above all these layers, there is the exosphere which starts at the top of the ionosphere and continues until it merges with interplanetary gases, or space. In this region of the atmosphere, Hydrogen and Helium are the prime components and are only present at extremely low densities. III.1.1. Ionosphere: The ionosphere is known as the upper atmosphere and it extends 600 kilometers. The temperatures go up as you increase in altitude due to the Sun's energy. Temperatures 7 in this region can go as high as 1727 ºC. Chemical reactions occur much faster here than on the surface of the Earth. The existence of charged particles signals the beginning of the ionosphere a region compiling the properties of gas and plasma. The structure of the ionosphere is strongly influenced by the charged particle wind from the Sun (Solar wind), which is in turn governed by the level of Solar activity. One measure of the structure of the ionosphere is the free electron density, which is an indicator of the degree of ionization. The solar radiation strikes the atmosphere with a power density of 1370 Watts per 2 meter or 0.137 Watts per cm2, a value known as the "solar constant". This intense level of radiation is spread over a broad spectrum ranging from radio frequencies through infrared (IR) radiation and visible light to X-rays. Solar radiation at ultraviolet (UV) and shorter wavelengths are considered to be "ionizing" since photons of energy at these frequencies are capable of dislodging an electron from a neutral gas atom or molecule during a collision. The conceptual drawing below is a simplified explanation of this process. Figure 2: The solar ionization ( Ref: III.1.1) Incoming solar radiation is incident on a gas atom (or molecule). In the process, a part of this radiation is absorbed by the atom, and a free electron and a positively charged ion are produced. Cosmic rays and solar wind particles also play a role in this process but their effect is minor compared to that due to the sun's electromagnetic radiation. At the highest levels of the Earth's outer atmosphere, solar radiation is very strong but there are few atoms to interact with. So, ionization is small. As the altitude decreases, more gas atoms are present so that the ionization process increases. However, at the same time, an opposing process called recombination begins to take place, in which a free electron is "captured" by a positive ion if it moves close enough to it. As the gas density increases at lower altitudes, the recombination process accelerates since the gas molecules and ions are closer together. The point of balance between these two processes determines the degree of "ionization" present at any given time. At still lower altitudes, the number of gas atoms (and molecules) increases further and there are more opportunities to absorb the energy from a photon of UV solar radiation. However, the intensity of this radiation is smaller at these lower altitudes because some of it was absorbed at the higher levels. 8 III.1.2. Mesosphere: The mesosphere is the third highest layer in the atmosphere, occupying the region between 50 km and 80 km above the surface of the Earth, above the troposphere and stratosphere, and below the ionosphere. It is separated from the stratosphere by the stratopause and from the thermosphere by the mesopause. The chemicals are in an excited state, as they absorb energy from the Sun. Temperatures in the mesosphere drop with increasing altitude to about -100°C. The mesosphere is the coldest of the atmospheric layers. In fact, it is colder than Antarctica's lowest recorded temperature. It is cold enough to freeze water vapor into ice clouds. You can see these clouds if sunlight hits them after sunset. They are called Noctilucent Clouds (NLC). NLCs are most readily visible when the Sun is from 4 to 16 degrees below the horizon. The mesosphere is also the layer in which a lot of meteors burn up while entering the Earth's atmosphere. From the Earth, they are seen as shooting stars. The layer which separate the mesosphere from the ionosphere is the mesopause. III.1.3. Stratosphere: The stratosphere is characterized by a slight temperature increase with altitude, the temperature in this region increases gradually to –3 ºC, due to the absorption of ultraviolet radiation. This layer is also characterized by the absence of clouds. Only the highest clouds (cirrus, cirrostratus, and cirrocumulus) are in the lower stratosphere. The stratosphere extends between 17 to 50 kilometers above the earth's surface. This part of the atmosphere is dry and less dense compared to the troposphere (the layer below the stratosphere). In this layer is located the ozone layer . Ozone, a form of oxygen, is crucial to our survival, because this layer absorbs a lot of ultraviolet solar energy. The stratopause is the layer that separates the stratosphere from the mesosphere. Ozone layer: The Ozone layer is a layer in the stratosphere which protects the Earth from the harmful effects of ultra-violet radiation from space. Discussion about the Ozone Layer became popular when, in 1984, it was discovered that above Antarctica, there was a hole 9 in the layer. This was not expected and started scientists on a search to discover why the hole had appeared, and what had caused it. The use of chlorofluorocarbons ( cfc's ) in products that discharged them into the atmosphere have caused serious damage to the Ozone layer. In October 1987, scientists were surprised again when the hole over Antarctica reached the same size as the USA. However, there is a long delay between cfc's being released into the air, and their arrival in the stratosphere. It can take ten years for the gasses to reach the stratosphere, and another one hundred years before they are naturally destroyed. This means that we may have to live with the consequences of past pollution for many years to come. Apart from cfc's, which are now used far less frequently in the developed world than they used to be, two other 'greenhouse' gasses have a bad effect on ozone. These are nitrous oxide and methane. Nitrous Oxide breaks down and destroys ozone as it goes, and methane actually creates more ozone, but in the wrong part of the atmosphere. The methane generates more ozone in the tropopause, which is below the stratosphere, and this layer can hide the holes in the stratosphere above it. The main importance of ozone is that it acts like a sunblock, filtering out the dangerous ultra-violet rays from the sun. Humans and animals exposed to excessive UV light can develop cancers, their skin ages more quickly and their immune systems are reduced. Crops also seem to be damaged by extra UV. Some forms of Soya bean, an increasingly important crop, have suffered a 25 percent decrease in yield when their exposure to UV B rays was increased by 25 percent. In the seas, it has been found that phytoplankton, the foundation of the ocean food chain, are vulnerable to high exposure to UV rays, as are some fish larvae. Since the human population acquires much of this food ( especially protein from fish) from the oceans, damage to the phytoplankton might result in a massive reduction in fish stocks and the loss of an important source of food for us. Finally, and possibly the most worrying is the possibility that in the future, the ozone layer will start to let very harmful UV- C rays reach the surface of the Earth. At the moment the layer stops all UV- C before reaching us. We know that UV-C can alter and destroy DNA and proteins. We can only guess at the consequences for the human race if our DNA is exposed to UV- C for long periods. 10 III.1.4. Troposphere: The troposphere starts at the Earth's surface and it extends 8 to 14.5 kilometers high. This part of the atmosphere is the most dense. As you climb higher in this layer, the temperature drops from about 17 ºC at sea level to –52 ºC at the beginning of the tropopause. The primary gases we can find in this region are nitrogen and oxygen. The troposphere contains over 75 percent of all the atmosphere's gases and vast quantities of water and dust. As the sun heats the ground, it keeps this thick mixture churning. The weather is caused by these churnings of the mass. The troposphere is the layer in which all which we call "weather" occurs. The troposphere is normally warmest at ground level and cools higher up where it reaches its upper boundary (the tropopause). The tropopause is the layer which separate the troposphere from the stratosphere. It varies in height. At the equator it is at 8 km high, at 50 N and 50 S, 9 km and at the poles 6 km high. III.2. Winds: Wind is the result of movement of air due to difference in pressure. It is the result of flow of air from high pressure area to low pressure area, to eliminate pressure difference. Pressure that's higher at one place than another sets up a force pushing air from the high pressure area toward the low pressure area. Greater the difference in pressures, stronger the force. Distance between high pressure and low pressure area determines how fast the moving air is accelerated. Figure 3: Movements of air due to the difference in pressure( Ref: III.2a ) In the horizontal direction, pressure can change by about 10 mb in a distance of 100's of kilometers, whereas in the vertical direction, the pressure changes by almost 1000 mb in about 10-12 km. Yet, it is the horizontal variation of pressure that generates our winds. 11 Figure 4: Model of an air column warming ( Ref: III.2b ) Air can approximately be regarded as an “Ideal Gas" which obey the "Ideal gas law" P = C * ρ * T . So the factors affecting air pressure are Density(ρ) and Temperature(T). If temperature is constant, then P will increase by increasing the density of the gas. If we take a air column and increase the temperature and let the gas expand so that the column with warm air occupies more volume, then we observe that both air column will have same pressure. (Ref: III.2 ) III.2.1. Newton's Law : If we apply Newton's Law to an air parcel, then the force acting on this air parcel can be obtained from the equation : F= m * a where: F = force (a push or pull) m = mass of the object (parcel) a = the resultant acceleration (speed up or slow down) If there is only one force, the net acceleration of the wind will be : anet = F1 / m However, if there are many forces involved, the net acceleration will be: anet = ( F1 + F2 + F3 + F4 ... + Fn ) / m (where ‘a’ & ‘F’ are vectors) If we consider that earth is not rotating and does not have any friction with wind, then wind will flow in a straight line and would flow longer and harder than it does. But the forces in above equation must be taken into account. Some of the Forces affecting wind and its speed / acceleration can be listed as: 1. Air pressure gradient; 2. Coriolis effect; 3. Friction. 12 III.2.2. Air pressure gradient : Pressure gradient can be defined as a change in pressure over a given distance, i.e., Pressure Gradient = ?P / Distance = ( Phigh – PLow ) / Distance Air pressure gradient is determined by Isobar on weather map. An isobar on a weather map is a line where the air has the same pressure all along the line. Figure 5 : Examples of pressure gradient in Europe ( Ref: Blue) Spacing between isobar determines pressure gradient, closer isobar represents steep gradient whereas more spacing between isobar represents low pressure gradient. Between the steep pressure gradient air flows rapidly resulting in high speed wind. ( Ref: III.2 ) III.2.3. Coriolis Effect : Coriolis effect is an inertial force described by the 19th-century French engineermathematician Gustave-Gaspard Coriolis. If we consider an ordinary body in motion, in a rotating frame of reference, an inertial force acts to the right of the direction of body motion for counterclockwise rotation of the reference frame or to the left for clockwise rotation. The effect of the Coriolis force is an apparent deflection of the path of an object that moves within a rotating coordinate system. The object does not actually deviate from its path, but it appears to do so because of the motion of the coordinate system. 13 Figure 6 : The Coriolis deflection and its effect on the wind ( Ref: III.2.1 ) Because of this force winds in northern hemisphere bends to right side and in southern hemisphere to the left side. The coriolis force is proportional to the wind speed, that means if the speed of wind is more we will observe more bending of wind from its normal path. III.2.4. Frictional Force When wind flows near the surface of earth friction from trees, solid objects slows its speed. As magnitude of coriolis force is proportional to the speed, decrease in wind speed also decreases coriolis force, causing northern hemisphere wind to turn a little to left and southern hemisphere wind to right. Winds in the higher atmosphere does not have effect of friction. So, whenever pressure gradient increases, wind starts flowing in the perpendicular direction to isobar, steeper the gradient greater the wind speed. Once the wind flow starts, coriolis effect comes in the picture bending the wind direction. Wind direction is no longer perpendicular to isobar but now with some oblique angle. When the pressure gradient flow and coriolis deflection are in balance, the wind flows parallel to the isobar. III.2.5. Convergent and Divergent Flow In low pressure winds will flow inward from all the direction, and these wind are affected by coriolis deflection, as a result wind around center develop an inward spiral motion called Cyclone, in high pressure area wind flows spirally outward this motion is called Anticyclone. In northern hemisphere the inward flowing low pressure spiral rotates 14 in clockwise direction and outward spiral in counterclockwise. In southern hemisphere it is exactly reverse. Figure 7 : Cyclone and Anticyclone ( Ref: Blue) As air from high pressure area is going out in all directions in the Anticyclone, it causes divergence which draws air from high altitude to center, resulting drop in relative humidity and leading to clear, cloudless sky. Whereas in low pressure area incoming wind causes convergence which lead to an upward flow of air, resulting in cloud cover and rain. Figure 8 : Convergent and divergent flows ( Ref: Blue) III.2.6. Global Circulation: The circulation of air over the earth is largely due to the unequal heating of the earth surface due to solar radiation. The global circulation of pressure and wind plays an integral role in the heat balance of the earth. Global circulation of air in the atmosphere transfers warm air from low latitudes towards high latitudes, and cold air from high latitudes towards low latitudes. 15 Figure 9 : The circulation of air around the Earth ( Ref: III.2.2 ) At the equator direct rays from Sun heats the air, raising air to the upper part of atmosphere, leaving low pressure areas behind. In the upper part, air diverges and moves towards polar area, again because of coriolis force air turns eastwards, clearly this wind can not reach pole. And so air tend to pile up at 30N and 30S creating two belt of high pressure air around the world, the Hadley Cell. Air in this belt begins to cool and sink. Between thirty degrees latitude and the equator, most of the cooling sinking air moves back to the equator. The air movements toward the equator are called trade winds. At the pole, cold dense air descends, causing an area of subsidence and high pressure. As the air sinks, it begins spreading southward. Since the effect of coriolis force in polar area is strong, the southward moving air deflects sharply to the right. This wind is called the surface polar easterlies, although the upper winds are still predominantly from the southwest. Near 60ºN, the south-easterly moving air moving along the surface collides with the weak, north-westerly surface flow that resulted from spreading air at 30° N. This colliding air rises, creating a belt of low pressure near 60°N. Figure 10 : Description of the air and winds circulation ( Ref: III.2.2 ) The mid-latitude circulation cell between the Polar cell and the Hadley cell is called the Ferrel cell. The Ferrel cell circulation is somewhat complex compared with Hadley and Polar cells. It is believed that the cell is a forced phenomena, induced by interaction between the other two cells. The stronger downward vertical motion and surface convergence at 30°N coupled with surface convergence and net upward vertical motion at 60°N induces the circulation of the Ferrel cell. This net circulation pattern is greatly upset by the exchange of polar air moving southward and tropical air moving 16 northward. This explains why the mid-latitudes experience the widest range of weather types. Figure 11 : Formation of the Jet streams ( Ref: III.2.3 ) One more important flow of wind/air is Jet Stream, jet stream is flow of fast moving air in the upper path of the atmosphere around 10 Km high. Jet stream is formed because of the difference in temperature of two air masses. Jet stream flows between the boundaries of such air masses. The speed of jet stream depend on the difference in temperature between two air masses, higher the difference more the speed. Jet stream are usually formed in winter when there is a large difference in temperature between air at high latitude and at low latitude. Sometimes wind speed can exceed 200 Km/h. III.3. Temperature : The temperature is a really important parameter to describe the world. Even if we can’t see it, we can feel it and see what happen with its fluctuations. For example, according to this temperature, it can rain or snow. As a consequence, it is one of the quantities characterising the behaviour of the atmosphere, and especially the troposphere with the weather. But it is also a parameter which depends on a lot of others like the place where you measure it, the season, etc. However, scientists have defined an average Earth’s temperature (at the surface): ~13°C. But in every place, the temperature can be different. This is due to: • Exposition to the sun; Figure 12 : Sun exposition, where area(A) < area(B), which implies that the temperature at A is higher than at B 17 • • • • Altitude; Weather; Seasons; ... Figure 13 : Temperature trends by 5º latitude bands (where data are available) in three different data sets: observed surface data ( = ST ), derived surface data ( = R2–2m ), satellite-based lower tropospheric data ( = MSU ). All of these data are for the most part independent of one another. Notice how the trends from the derived surface data more closely match trends from satellite data than they do observed surface data. ( Ref: III.3.1 ) Nowadays, we have to take care about it because this average temperature has increased for a few decades from about 1°C. This value seems to be so small, but this could really have bad consequences, especially because it appears that temperature continues to increase. In fact, this could warm water and make the sea growing up (ice on the poles which would melt), modify the water cycle, etc. Figure 14 : Global average temperatures 1860-2002 (difference from 1961-1990 normals, °C), using air measurements at land stations and sea surface temperatures measured by ships and buoys. ( Ref: III.3.2 ) The variations of temperature causes atmospheric circulation. In fact, when the air is heated (especially near the equator, where the sun heats more), it expands and the density is lower (like most of the gases). It results that the air rises, and flows in the upper atmosphere towards both poles. Here(at the poles), it becomes colder, and begins to sink back, where it flows along the surface and comes back to the equator. 18 Figure 15 : Simple circulation of air ( Ref: III.3.3 ) III.3.1. Simple model of the decrease of the temperature in the troposphere: The temperature decreases with the height due to expansion. If we assume a dry air parcel with no exchange of heat with its surroundings (adiabatic), then we obtain a “lapse-rate” Γ, so that: – Γ = dT / dZ = – 9.8 K.km –1 Note: In moist air, we have: Γ = 6 K.km –1 III.3.2. Temperature records: As we can see in the different temperature profiles below, the mean temperature is related to the composition of the troposphere, and especially to the concentration in carbon dioxide. How can we obtain such profiles? Different techniques are used to estimate past temperatures, using for example corals, ice cores, tree rings, and more recently instruments like thermometers and satellites. 19 Figure 16 : Temperature records since 450 000 years ( Ref: III.3.4 ) Figure 17 : Temperatures records since 1 000 years ( Ref: III.3.4 ) These profile show us that there were a lot of variations in temperature since the last 450000 years. All these fluctuations seem to come from two different things: o Solar activity; o Variations in the Earth’s orbit. In fact, when the orbit changes, there are variations of energy coming from the Sun to the Earth. And this lead to variations in production of CO2 from the oceans and the biosphere. That can explain, with the process of greenhouse effect, why the temperatures are changing like above. We can also observe that compared with the temperatures until 450000 years, the actual temperatures seem to be normal. But compared to the temperatures until 1000 years before, we see that there was an increase of the temperature, and especially during the last century. Thereby, does it come from the industrialisation? 20 III.3.3. Simple models of the world’s mean temperatures: Here are 2 simple models of the world with the mean temperatures for July and January: Figure 18 : Mean temperature for January ( Ref: III.3.5 ) Figure 19 : Mean world temperature for July ( Ref: III.3.5 ) 21 IV. Interactions with biosphere, geosphere, and hydrosphere: IV.1. Interaction between atmosphere and biosphere: IV.1.1. Effect of deep rooted vegetation: Figure 20 shows the effect of deep rooted vegetation on the atmosphere. Deep roots provide an increase in soil water storage capacity which in turn increases the access to water stored in the soil for dry periods. Because of this, transpiration is enhanced during the dry season which leads to local cooling and moister air. In this way, more moisture is transferred to the inner tropical convergence zone which results in precipitation. The shaded areas in the fig 20 denote water. Figure 20 : Effect of deep rooted vegetation on the atmosphere ( Ref: IV.1) The depth of the root system controls the maximum amount of soil water that can be transpired by the vegetation into the atmosphere during dry periods. Water uptake from deep soil layers has been found to contribute significantly to the dry season transpiration at some sites in Amazonia and it has been estimated that large parts of the evergreen forests in Amazonia depend on deep roots to survive the dry season. Thus, the presence of deep roots will provide a significant source of atmospheric moisture during the dry season. IV.1.2. Greenhouse effect: Carbon dioxide is the most important anthropogenic greenhouse gas contributing 60%.the atmospheric concentration of carbon dioxide has increased by almost one third 22 from 280 ppm to 370 ppm in 2002. The reasons are due to the emissions produced by the burning of fossil fuels, due to burning of forests most of the CO2 present in the vegetation is burnt,due to increase in soil erosion.Measurements shows that the atmospheric carbon dioxide content has increases by 3.2 Gt C per year .The ocean and the land biosphere are the most important carbon sinks.they are interacting with atmosphere.Atmospheric CO2 is exchanged with the ocean and the land ecosystem. Figure 21: Atmospheric CO2 concentrations 900-2000; box: CO2 emissions growth rate of atmospheric concentration 1958-1998 ( Ref: IV.2 ) Figure 22: ( Ref: IV .2 ) The total amount of CO2 dissolved in the ocean is about 20 times greater than the terrestrial CO2 amount and 50 times higher than the atmospheric CO2 amount. The CO2 exchange is a dissolution and outgassing process of carbon dioxide into and from the surface layer of the ocean , and is regulated via the CO2 partial pressure difference between air and water. This exchangeleads to total of approx 90 Gt C per year which leads to compensation between the CO2 content of the atmosphere and the surface water. The land biosphere exchanges carbon dioxide with the atmosphere through photosynthesis, respiration and bacterial decomposition. The balance of exchanges with the atmosphere can be positive depending on the intensity of the processes released or absorbed carbon.In this case, the biosphere is a source of carbon dioxide for the atmosphere. Alternatively, the balance may be negative, in which case the terrestrial biosphere acts as a carbon dioxide sink. 23 Figure 23: The Carbon cycle. ( Ref: IV.2 ) IV.1.3. Effect of pollution: Humans are generating pollution.there are different types of pollution caused by people like air pollution,water pollution.but the air pollution will effect the atmosphere alot.this can be caused due to automobiles which in turn causes rain full of toxic chemicals.the incomplete combustion of fuels results in large quantity of sulphur.this sulphur combines with oxygen to form sulphurdioxide,which in turn combines with water droplets and form sulphuric acid or acid rain.the incomplete combustion of fossils fuel releases carbondioxide which causes green house effect. Air pollution also effects statosphere,the ozone layer.ozone absorbs the shortwaveultravoilet radiation from the sun.Pollutant concentrates are reduced by atmospheric mixing, which depends on such weather conditions as temperature, wind speed, and the movement of high and low pressure systems and their interaction with the local topography. But sometimes a condition called an inversion occurs, in which a cold layer of air settles under a warm layer. This prevents an upward movement of air, atmospheric mixing is retarded and pollutants are trapped near the ground. Figure 24: Air Pollution caused from heavy industry ( Ref: IV.4 ) 24 IV.2. Interactions between atmosphere and hydrosphere: IV.2.1. Effect of water vapour: The water vapour in the atmosphere is essentially molecules of steam evaporated water - bounding around very thinly diluted among the gaseous nitrogen and oxygen molecules that make up the atmosphere. This water vapor can be experienced as humidity. Water vapour plays a critical role in affecting both climate and weather. The amount of water vapor in the atmosphere is not at all uniform ,far from it,but changes drastically and abruptly, often in a matter of a few hours, to cause, for example, thunderstorms. Figure 25: Hydrological cycle ( Ref: IV.8 ) It takes a lot of energy to evaporate water. A molecule of water vapor "contains" much more energy than a molecule of liquid water. water vapor is one of the most important "storehouses" of energy in the atmosphere and in the climate system. When water vapor condenses to form clouds, it has another important effect: it "shades" Earth's surface and lower atmosphere. In the greenhouse analogy, rolling down a shade over the greenhouse would cool off the interior, just as it would cool a sunny room When clouds shade the Earth, some of the incoming solar energy is reflected back into space. Some also is absorbed by the clouds and re-radiated upwards and downwards. Thus some of the energy is caught at altitudes higher than Earth's surface, but still in the atmosphere. But water in its vaporous state has an important heat-trapping " explained by water vapor's being relatively transparent to the shorter wavelengths at the visible and ultraviolet end of the light spectrum But after this energy has warmed the Earth's surface and been re-radiated upward in the infrared bands of the spectrum, water vapor readily absorbs it - trapping heat in the lower atmosphere (troposphere). Thus the water vapor is like the heat-trapping "glass" in the greenhouse analogy. IV.2.2. Effect of water, ice caps, sea ice: Climate change is a better phrase than global warming because it encompasses many kinds of effects. Some areas will be warmer, some cooler, sea levels may rise, polar 25 ice caps may melt, deserts might spread across Europe and extreme weather events may become more frequent. The Intergovernmental Panel on Climate Change estimates that the global temperature will rise by as much as 6°C this century. near the poles, in parts of Alaska, Canada, Siberia and the Antarctic, temperatures are rising faster than elsewhere. The permafrost is melting and plants, animals and the people that live there are already being affected. Arctic sea ice is melting at a faster rate than previously thought. . Melting sea ice doesn't raise sea levels but it could threaten ocean productivity, change current systems and disrupt global weather . Sea ice also plays an important role in keeping the ice and snow covering the Antarctic continent in place. With nothing to stop it, the Antarctic ice sheet may slide into the ocean and melt. If the sea rises by half a metre, this number could double. A metre rise would inundate 1% of Egypt's land, 6% of the Netherlands and 17.5% of Bangladesh. Only 20% of the Marshall Islands would be left above water. Although the ice sheets in Greenland have been thinning, analysis of long-term climate information (presented in the journal Geophysical Review Letters) has shown that temperatures in the southern part of the island and the Labrador Sea have fallen over the last 40 years, not risen. global climate change shifts temperatures across the planet . According to UNEP, they will have to migrate 10 times as fast as they did after the last ice age. Many won't make it. Species that do move will do so at different rates, breaking up existing communities. At high latitudes, entire forest types are expected to disappear, to be replaced by new ones. During this transition, carbon will be lost to the atmosphere faster than it can be replaced by new growth, accelerating climate change. In the high atmosphere the sulphur dioxide coverts into aerosols which reflect the sun's radiation back into space and thereby cooling the surface of the Earth.Interactions between geosphere and atmosphere: IV.2.3. Effect of volcanoes on atmosphere: The volcanic dust was spread around the upper atmosphere by the jetstreams, and it has been estimated that the world temperature fell by over 1C (2F). The year after, 1816, has been described as the year without a summer. Volcanoes release large amount of sulphur compounds such as sulfurdioxide. This will effect the climate more than the dust particles ejected from jetstreams.when this sulfurdioxide combines with waterdroplets in the air forms sulphuric acid.this sulphuric acid when falls on earth causes significant cooling.but this has been the primary cause of the global cooling that occurred after the Pinatubo and Tambora eruptions . 26 Figure 26 : Popocatépetl Volcano near Mexico City, Mexico ( Ref: IV.6 ) Figure 27 : Effects of volcanoes ( Ref: IV.6 ) Volcanoes releases large amount of carbondioxide and water. these two compounds will be in the form of gases in the atmosphere, they absorb heat radiation emitted by the ground . This causes the air below to get warmer. But this will not make the globe warmer.the effect is little.over long periods of time , multiple eruptions of giant volcanoes, such as the flood basalt volcanoes, can raise the carbon dioxide levels enough to cause significant global warming. IV.3. The Hydrologic cycle: The most familiar cycle is probably the hydrologic cycle, which describes the fluxes of water between the various reservoirs of the hydrosphere ( Ref: Blue ). It is important to remember that water is extremely important for all life. It is used by different systems, biologic, geologic and atmospheric. It is almost never destroyed, instead it changes state and gets transported. There is fixed amount of water on the planet. This means that the water you drink is the same water the dinosaurs drank once upon a time. Therefore, it is essential to know about the hydrologic cycle. Another important impact of the hydrologic cycle on the earth, is that it shapes the landscape to great variety. The hydrologic cycle is closely related to the to the cycle of rocks ( Ref: Blue ). As we already know, water can exist in the stable states, solid, gaseous and liquid. The physical state of water is determined by its temperature and pressure. As we identify the reservoirs of water we need to keep this in mind. 27 Figure 28 : The Hydrologic Cycle ( Ref: Blue ) IV.3.1. Water reservoirs: The reservoirs can be divided into ground water, surface water and water in the atmosphere as clouds and air humidity. Most of the water is of course located to the oceans which make up for more than 97.5 % of all the water in the system. Meaning that most of the water is saline, not fresh water. The ice-caps contain 74 % of all fresh water. The next largest reservoir of unfrozen fresh water is the groundwater, which represents 98.5 % of this unfrozen fresh water. Water resident in lakes and streams actually make up only a small fraction of the total together with atmospheric humidity. The size of the reservoir is very important for how long the water resides in the reservoir, known as the residence time. The bigger the reservoir, the longer the water will reside in the reservoir. For example, polar ice-caps can contain water for thousands of years, in lakes the residence time is small in comparison, such as a few weeks to a month. This makes the polar ice-caps an ideal place to look for information on past atmospheric conditions. The residence time is important in its turn to know how fast changes can propagate through the system. IV.3.2. Pathways: The sun is the driving force for the whole system. The hydrological cycle starts (since its a cycle it actually doesn't start anywhere) when water evaporates from the surface of the earth, land or sea. Remember that about 70% of the earth most of the surface is covered by water ( Ref: IV.9 ). On land it also leaves the surface in transpiration from the pores of plants and even animals. Water vapor in turn forms 28 clouds that contain small water drops. When the drops grow in size and become so heavy that the gravity pulling them down is much greater than the upward winds, it falls as precipitation in the different forms. It can fall as rain, hail or snow. In many cases the precipitation doesn't reach the ground before it evaporates again and return to the clouds. When it reaches the ground it can infiltrate the soil recharging groundwater reservoirs or it remains on the surface and fills up lakes and streams. From the surface reservoirs, water makes its way back to the oceans via so called surface runoff, where the cycle starts all over again. Figure 29 : Earth's water reservoirs and fluxes ( Ref: IV.9 ) Water in the atmosphere does not rise that high, it is mostly located to the troposphere, a thin layer close to the earth. Surprisingly most of our weather occurs in this thin layer. This means that the atmosphere above the troposphere is quite dry. IV.3.3. Anthropologic effects: The large cultivations made by man influence the amount of water evaporated through altering the surface of the soil , which otherwise would be covered by wild vegetation. This vegetation has, of course not the same evaporation characteristics as our grown vegetation thus changing the evaporation properties of the surfaces. A good example of this could be the rainforests that are being devastated. This doesn't only influence the CO2 level of the atmospheres but also the hydrological cycle, by changing the total amount of forest surface of the earth. The ices melting due to the greenhouse effect is also causing a change in the surface of the earth, and affecting the hydro level on the atmosphere. The ice reflects a great deal of the solar radiation: if it melts, there will be more radiation absorbed, increasing the humidity in the atmosphere. This is a positive feedback system since the increased temperature will melt more ice, making it unstable. 29 Human release of particles into the atmosphere increase the ability for water drops and ice particles to form since they need a solid base to form onto. The increased formation of clouds works as described before. IV.3.4. The energy budget of the atmosphere: In the atmosphere, energy transport is closely related to the hydrological cycle since most of the energy is concentrated to the water. Vapor has an great ability to store heat energy and to release it. The energy absorbed by the atmosphere comes both from sun radiation and energy emitted from the surface of the earth. One often measures the energy radiated by the sun over the average of the surface of the whole earth, making it an average over a time period evolving both day and night. In figure (See the figure 30 : The energy budget) we can see that total incident short-wave radiation from the sun is 343 W.m-2. Approximately 30 % of that amount is reflected back to space. Of the remaining, 20 % is absorbed by the atmosphere. 50 % reached the surface. In it's turn, the surface of the earth emit heat radiation to the atmosphere in an intricate system of absorption and re-emission to and from clouds on different levels. Practically, for the clouds the surface of the earth acts as a heat source and the space acts as a heat sink. Energy is internally stored in the atmosphere in both thermal and mechanical form. The thermal form is the temperature of the atmosphere, i.e. the random motion of molecules. The mechanical energy form, is the potential energy of the atmospheric mass within the earths gravity, and also in the form of kinetic energy in the motion of air. These internal forms of energy are responsible for redistribution of energy within the atmosphere. Figure 30 : The energy budget [W.m-2 ] ( Ref: Salby ) 30 V. Measurements techniques: Radar is a technique often used. Doppler reflection from e.g. precipitation for determining wind speed, direction. Polarisation of reflected light is used to check the polarization direction of the reflecting media, it could be sea-waves or ices. This indicates sea-wave directions, and one can also extract information about the amplitude of the sea-waves, because the reflected lights has a dependency on the wave height. Through sending a electromagnetic waves with different amplitudes and wavelengths, and observing the reflected radiation one can extract information of the reflecting media. Since all matter has its specific spectrum, it is easy to extract information on the composition of the atmosphere through registering the spectrum of the received light. The drawbacks for the reflecting EM-radiation methods is that it is a result of the total path of the ray. It is not a local value, that sometimes is the interesting parameter. Sometimes it is an advantage, depending on the application. Satellite measurement gives a global picture of the atmosphere, which is useful for weather precipitation. V.1. Measurement of different elements: The energy of solar radiation depend on energy of photons with different frequencies. The total energy of solar radiation can be considered as the addition of energies at all emitted frequencies. E=E1+E2+E3+....En where: E1= h * ν1 E2 = h * ν2 E3 = h * ν3 En = hνn Every molecule will, depending on its characteristics; absorb radiation of a particular frequency. In atmosphere different molecules will absorb different frequencies. Satellite uses spectrometer to measure the frequency spectrum of light radiation, reradiated by earth surface. If the obtained spectrum is compared with the spectrum of sun radiation, components in the earths atmosphere can be determined. This technique can be used to measure water vapor in the atmosphere. Water molecule in the earths atmosphere will absorb solar radiation emitted by earth surface. As water vapor will absorb radiation of only certain wavelength, frequency spectrum obtained by satellite will depend on the atmospheric water vapor concentration. Also just by changing the frequency of the observation we can measure concentration of different elements. 31 Precision of measurement using this technique is only 30­40% as water has complex spectrum as compared with other gases, also most of the water vapor concentration is near earth surface in 5000m, which is a large distance from satellite therefore hard to detect. But, this method can be used measure global water vapor distribution and changes in the concentration. Figure 31 : Advanced Microwave Scanning Radiometer(AMSR) will observe various physical content concerning water (H2O) by receiving weak microwaves to be naturally radiated from the Earth's surface and atmosphere (for example, water vapor content, precipitation, sea surface temperature, sea surface wind, sea ice, etc.) and also regardless of day or night, the presence of cloud. These sensors aim at collecting energy. ( Ref: V.1.1 ) V.2. Wind Speed : Sea wind Scatterometer is used for wind speed and direction over sea surface measurement with high accuracy. This method can provide accurate measurements over 90% ice free ocean surface. Sea wind Scatterometer uses indirect approach for measurement of wind speed over ocean surface. Change in wind speed will cause change in the roughness of ocean surface, which will change the backscattered power. Figure 32 : The SeaWinds will use a one meter diameter dish antenna with two beams rotated about the satellite nadir axis at 18 RPM. SeaWinds radiates and receives microwave pulses at a frequency of 13.4 GHz across on 1800 km wide swath. ( Ref: V.2.1 ) 32 V.3. Balloons and rockets: Balloons are used for measuring meteorological data, such as temperature, pressure, humidity atmospheric composition among other. Weather balloons carry equipment not only for measuring the atmosphere but also for pinpointing its position and a communication system for transmitting live-data to a ground station. Balloons are quite cheap to implement, there are no complicated mechanics or propulsion systems. They are often filled with helium, which is lighter than air and it is an inert gas ( Ref: V.1). There are different types of balloons, small balloons called "pilot balloons" are about 1m in diameter, and there are much larger balloons called "teardrop balloons". Different sizes means that they are used for different purposes . The smaller ones are visually followed to obtain data for the computation of wind speed and direction at different levels in the atmosphere. The larger balloons are able to carry more equipment and are used for higher altitudes. Balloons can reach a height of 20-40km ( Ref: V.2 ) ( Ref: V.1 ). Airplane travel up to about half of that height. Well up in the atmosphere the balloon eventually bursts and fall to the ground. Normally balloons are equipped with a parachute to facilitate, in some cases, the reuse of the equipment. Balloons are limited in geographic and altitude coverage since they require a launch site, often a meteorological station. But the modest costs involved often makes them the choice for various atmospheric observations ( Ref: V.2 ). In figure 33, there is group of student assisting a researcher on the release of a sounding balloon. This is an experimental balloon of a diameter of about 1.5 meters that reach the height of 8km. A radiosond transmitted data back to the ground and data was recorded. Temperature and pressure is registered in figure 34. Figure 33 : A group of people releasing a sounding balloon in Vancouver Canada at about 49° Latitude and 123° Longitude ( Ref: V.3 ) 33 Figure 34 : The temperature observations are shown as dark red dots and blue circles when the sonde was ascending and descending, respectively. Dew point is in green. For reference, dry adiabats are in orange, and a moist adiabat is the violet dashed line ( Ref: V.3 ) Rockets evolved rapidly during the second world war. Not only for destructive purposes but also for atmospheric observations. Obviously, rockets have more costs but have a great advantage in altitude reach Rockets travel up to 76km ( Ref: V.1 ). These are therefore used for sounding the upper atmosphere in a more vertical ascend than balloons that has a ascent depending heavily on winds. 34 VI. References: VI.1. Bibliography: • Blue => B.J. Skinner, S.C. Porter, D.B. Botkin: The Blue Planet 2:nd edition, John Wiley & Sons. Inc., USA, 1999 • Salby => Murry L. Salby: Fundamentals of Atmospheric Physics Academic Press, Inc., USA, 1996 VI.2. Internet resources: II. Atmosphere history: • II => http://www.geocities.com/CapeCanaveral/7639/atmosphere/atmosevo.htm III. Structure and functions of each layer of the atmosphere: III.1. Layers: • III.1 => http://csep10.phys.utk.edu/astr161/lect/earth/atmosphere.html • III.1.a (Earth's atmosphere) => http://www.enchantedlearning.com/subjects/astronomy/planets/earth/Atmosphere. shtml • III.1.b => http://www.oulu.fi/~spaceweb/textbook/ionosphere.html • III.1.1.Ionosphere => http://www.haarp.alaska.edu/haarp/ionindex.html • III.1.2.Mesosphere => http://www.ace.mmu.ac.uk/eae/Atmosphere/Older/Mesosphere.html • III.1.3.Stratosphere => http://www.metoffice.com/research/stratosphere/ III.2. Winds: • III.2a => http://sync.usatoday.com/weather/photos/press2-470.jpg http://sync.usatoday.com/weather/photos/press-3-470.jpg • III.2b => http://apollo.lsc.vsc.edu/classes/met130/notes/chapter9/pg.html 35 • III.2.1 => http://zebu.uoregon.edu/~js/glossary/coriolis_effect.html • III.2.2 => http://calspace.ucsd.edu/virtualmuseum/climatechange1/08_1.shtml • III.2.3 => http://sd.znet.com/~aringler/jet.htm • III.2.4 Cell => http://www.physicalgeography.net/fundamentals/7p.html • http://sparce.evac.ou.edu/q_and_a/air_circulation.htm ( III.2 ) • http://www.weatherquestions.com/What_causes_the_jet_stream.htm ( III.2 ) • http://www.espere.net/Unitedkingdom/water/uk_measurement.html ( III.2 ) • http://kids.earth.nasa.gov/archive/nino/global.html ( III.2 ) III.3. Temperature: • III.3.1 => http://www.greeningearthsociety.org/wca/2004/wca_21b.html • III.3.2 => http://www.aip.org/history/climate/20ctrend.htm#temp2002 • III.3.3 => http://www.tpub.com/weather2/3-2.htm • III.3.4 => http://www.brighton73.freeserve.co.uk/gw/paleo/paleoclimate.htm • III.3.5 => http://www.klimadiagramme.de/ • http://web.utk.edu/~grissino/ website about tree-rings, with tree-ring dating, dendrochronology,... ( III.3 ) • http://www.ngdc.noaa.gov/paleo/ei/ei_reconsa.html : Temperature reconstructions ( III.3 ) • http://www.atmosphere.mpg.de/enid/gt.html ( III.3 ) • http://www.atmosphere.mpg.de/enid/5057ce0c8397e666f5a77ee2a0017790,55a30 4092d09/15z.html ( III.3 ) • http://www.newscientist.com/hottopics/climate/climate.jsp?id=22354400 ( III.3 ) • http://www.ngdc.noaa.gov/paleo/pubs/mann2003b/mann2003b.html ( III.3 ) 36 • http://www.ngdc.noaa.gov/paleo/globalwarming/paleolast.html ( III.3 ) IV. Interactions with biosphere, geosphere, and hydrosphere: • IV.1 => http://www.geog.umd.edu/biogeomodeling/ABINTERACT/ • IV.2 => http://www.hamburger-bildungsserver.de • IV.3 => http://wings.avkids.com • IV.4 => http://www.thegreenschool.fsnet.co.uk • IV.5 => http://www.solarviews.com • IV.6 => http://www.cotf.edu • IV.7 => http://www.classzone.com • IV.8 => http://www.ucmp.berkeley.edu • IV.9 => University of Illinois: http://ww2010.atmos.uiuc.edu/(Gh)/guides/mtr/hyd/bdgt.rxml V. Measurement techniques: • V.1 => Infoplease Encyclopedia: http://www.infoplease.com/ce6/sci/A0851701.html • V.1.1 => http://hgssac02.eoc.nasda.go.jp/satellite/sendata/amsr_e.html • V.2 => http://www.ciesin.org/docs/011-489/011-489.html • V.2.1 => http://hgssac02.eoc.nasda.go.jp/satellite/sendata/seawinds_e.html • V.3 => A balloon sounding made by ``Earth and Oceans Science at UBC'', The University of British Columbia, Vancouver Canada: http://www.eos.ubc.ca/courses/atsc201/A201Resources/SoundingUBC/BalloonLa unch.html 37