Version A Armando’s Copy Chemistry 100: Summary of Chapters A & Q These two chapters refine our knowledge of what atoms are and how they are made up. Unit A deals with the discovery of subatomic particles and roughly how to organize the protons, neutrons, and electrons. Unit Q shows us how the electrons are arranged in the atom – first with the Bohr shells and then with the quantum mechanics model. Compare this handout to the Key Terms and Concepts section at the end of the chapter. UNIT A: DISCOVERY AND DEFINITION OF ATOMS & THEIR PARTICLES We covered this information to reenforce the ideas of discovery, explanation of phenomena, and the importance of being flexible about our favorite theories – they can be changed! Important Topics o Dalton’s Definitions (how many/which ones were shown to be wrong?) o The 3 particles {protons, neutrons, electrons}, how heavy are they, what charge do they have? o Isotopes (Dalton’s Rule #_____ out the window). Don’t do math on page A.9. Know A, Z, how to find number of each particle in an isotope from nuclear symbol. o Atomic Mass (amu) – 1amu ~ 1 hydrogen’s mass. o Periodic Table: organize elements, # of atoms per row = Bohr Shells. Known the names of columns (also called families or groups). Also know features of the table: metals/nonmetals, transition elements. o Memorization: Memorize 1st 3 rows of periodic table: element name, symbol, number. Look at Figure A.8 – we’ll probably know most of these by using them all quarter. Armando’s Copy Version A UNIT Q: ARRANGING ELECTRONS IN THE ATOM This chapter introduces the system that shows how electrons are arranged in the atom. This system explains just about everything in chemistry – that’s why we tackle such a tough block of information. Important Topics o Light, Spectroscope: Don’t worry too much about the deep details – but understand that the thin colored lines from the Hydrogen lamp got everything started. o Bohr Model: Electrons orbit in shells with different energies, 2 e- in 1st shell, 8 in 2nd & 3rd, 18 in 4th. Shell idea lasted into newer theory. Dark Violet Violet Blue/Aqua Red o Quantum Model: Very weird but it works! We now have 4 critera to identify electrons: 1. Principle Energy Level (n). Same as Bohr shell number. 2. Sublevel (s, p, d, or f). Shape of orbit. 3. Orbitals (x, y, z). Direction it points (up/down or left/right or front/back) Pauli Exclusion Principle. Electrons are like children – they won’t share unless they have to. They are also lazy. Energy/Order of Orbitals. Use the triangle on pg Q.8, know the order. From lowest energy to highest: n=1<2<3, s<p<d<f, Watch out: 3d<4s for some weird reason. Electron Configuration. Shorthand like a chemical formula – so we don’t have to draw the 3D picture all the time. (e.g. 1s2 means 2 electrons in the s sublevel of the 1st shell (n=1), 3p5 means 5 electrons in the p sublevel of the 3rd shell (n=3). For an atom of Nitrogen: 1s22s22p3 – add up the superscripts, 2+2+3=7, Z=7 for nitrogen. Be able to write the electronic configuration for any atom! Valence Electrons. Electrons in the outer shell of an atom. We’ll use this a lot for reactions and properties. Very simple to find: Locate the element on the periodic table. Find its group number, that’s the number of valence electrons (Na: 1A, 1 valence electron. Cl: 7A, 7 valence electrons). Chemical Families. We’ll talk about these – be able to locate them on the periodic table. Be able to draw the atom’s Lewis Dot. Lewis Dots. Another notation showing valence electrons for an atom. Put 1 dot for each valence electron around the chemical symbol: Na, Mg:, :C: