St Peter the Apostle High School Nuclear Chemistry N5 Homework Questions Answer questions as directed by your teacher. Chemistry Department National 5 Questions Radiation 1. Alpha, beta and gamma radiation have different penetrating properties. Name the type of radiation which is: (a) able to penetrate 5cm lead (b) stopped by a sheet of paper (c) stopped by a sheet of aluminium. (3) 2. (1) Nuclear Equations 1. Uranium 238 decays by alpha-emission to form isotope X. Isotope X then decays, emitting Y to form protactinium 234. Identify X and Y. 2. What is formed when an atom of A 3. 240 91 Pa B 239 91 239 92 (2) U emits a beta particle? Pa C 239 93 Np D 238 U 92 (1) Protactinium 231 is formed by beta emission from a radioisotope of thorium. What is the mass number of the radioisotope of thorium? A 230 4. B 231 C 232 D 235 (1) What is formed when radium 224 emits an alpha particle? A radon 220 B radon 222 5. C actinium 224 D thorium 228 (1) Copy and complete the following equations: 6. (a) 234 90 Th + 0e -1 (1) (b) 222 86 Rn + 4 2 (1) He Find X, Y and Z in: (a) (b) (c) 6 Li 3 234 U 92 + 1 0 3 1 n Y + 212 Bi 83 Z + H 4 He 2 0 -1 + X (1) (1) e (1) Half Life 1. 24 Na is a beta emitter with a half life of 15 hours. What percentage of the original isotope would remain after 45 hours? A 12.5 B 25 C 75 D 87.5 (1) 2. 14 C has a half life of 5600 years. An analysis of charcoal from a wood fire shows that its 14 C content is 25% that of living wood. How many years have passed since the wood for the fire was cut? A 1400 3. 5. 6. 7. 8. C 11200 D 16800 (1) After 48 years the level of radioactivity in a sample of an isotope was found to be 1/8th of the level originally. What is the half life of the isotope? A 6 years 4. B 4200 The half-life of 84 years. B 12 years C 16 years D 24 years 210 (1) Pb is 21 years. Calculate the mass left of a 40g sample after Calculate the half-life of (2) 220 Rn if it takes 220s to decrease its radioactivity to 1/16. (2) 24 Na has a half life of 15 hours. What fraction of a sample’s activity will remain after 5 days. (2) A luminous watch dial containing 147 Pm (t1/2 = 2.5 years) has only 1/8 of its original ‘glow’. How old is the watch? (2) The radioisotope 131I is used in hospitals. It has a half-life of 8 days and decays to give a stable product. A bag of hospital linen contaminated with 131 I was found to give a count rate of 320 counts s-1. (a) Draw a graph to show how the count rate of the linen will change with time. (b) Hospitals are not allowed to dispose of material contaminated with I 131 until the count rate has fallen to 30 counts s-1. Use the graph to determine how long the bag of linen must be stored before disposal. (3) (1) Radioisotopes 1. 2. The isotope 60Co has a half life of 5.3 years and is used to supply gamma radiation from outside the body of a patient. Give two reasons why this isotope would not be suitable for use inside the body. (2) Radioisotopes are used in a wide variety of ways. (a) Name a radioisotope used in medicine and give its use. (b) Describe an industrial use for a radioisotope. (2) Miscellaneous 1. 14C is a radioactive isotope of carbon. It is produced in the upper atmosphere when 14N atoms are bombarded by neutrons from space. If a neutron is captured by a 14N nucleus, a 14C isotope is produced along with one other particle. (a) Copy and complete the nuclear equation for the formation of carbon-14. (b) 14C (c) decays by beta emission. Why does the atomic number increase by one unit when a 14C nucleus decays? (1) (1) Carbon dating can be used to estimate the age of wood found in archaeological sites. The decay curve shows the decrease in the percentage of 14C against the number of half-lives. (i) A piece of wood was found to contain 5% of the original 14C content. The half life of 14C is 5700 years. Calculate the age of the wood in years. (ii) Suggest a reason why 14C is unsuitable for dating samples that are more than 50,000 years old. (1) (1) 2. The age of a rock found in Canada was determined by measuring the amounts of argon-40 and potassium-40 present in a sample. (a) Each potassium-40 atom can emit a single positron particle to form an argon-40 atom. Work out the mass number and atomic number for a positron. (b) 75% of the potassium-40 atoms originally present in the rock sample were found to have undergone radioactive decay. The half-life of potassium-40 is 1.26 x 109 years. Calculate the age of the rock in years. (1) (1) 3. Phosphorous-32 and strontium-89 are two radioisotopes used to study how far mosquitoes travel. (a) Strontium-89 decays by emission of a beta particle. Copy and complete the nuclear equation for the decay of strontium-89. 89Sr (b) (c) In an experiment, 10g of strontium-89 chloride was added to a sugar solution used to feed mosquitoes. (i) The strontium-89 chloride solution was fed to the mosquitoes in a laboratory at 20oC. When the mosquitoes were released the outdoor temperature was 35oC. What effect would the increase in temperature have on the half-life of the strontium-89? (ii) Calculate the mass, in grams, of strontium-89 present in the 10g sample of strontium-89 chloride, SrCl2. A mosquito fed on a solution containing phosphorous-32 is released. Phosphorous -32 has a half-life of 14 days. When the mosquito is recaptured 28 days later, what fraction of the phosphorous-32 will remain? (1) (1) (1) 4. Positron emission tomography, PET, is a technique that provides information about biochemical processes in the body. Carbon-11, 11C, is a positron-emitting radioisotope that is injected into the bloodstream. A positron can be represented as 0 e. 1 (a) Complete the nuclear equation for the decay of 11C by positron emission. 11C (b) (c) A sample of 11C had an initial count rate of 640 counts min-1. After 1 hour the count rate had fallen to 80 counts min-1. Calculate the half-life, in minutes, of 11C. (1) (1) 11C is injected into the bloodstream as glucose molecules (C6H12O6). Some of the carbon atoms in these glucose molecules are 11C atoms. The intensity of radiation in a sample of 11C is compared with the intensity of radiation in a sample of glucose containing 11C atoms. Both samples have the same mass. Which sample has the higher intensity of radiation? Give a reason for your answer. (1) 5. (1)