Half - Life We have already learned the types of decay that a radioactive isotope can undergo (alpha, beta, gamma), but we have not talked about how long it takes for decay to happen. Different isotopes have different half-lives. Half-Life: the time required for a substance to decay onehalf of its initial value. Here is a table that lists half-lives of selected radioisotopes: This rate of decay is constant for each isotope and different from any other. The rate is not affected by factors like temperature or pressure. We can’t predict when an individual atom will decay, but we can know when half of the sample will, just like predicting the probability that a coin will land heads-up. Nuclear decay is an exponential function: Each time a half-life passes half of the sample decays and turns into something else (depending on the decay mode). For example, every 5715 years, half of the nuclei in a sample of C-14 will undergo beta decay and turn into N-14: 14 6C 0-1e + 147N The shorter a half-life is, the less time an unstable isotope is emitting radiation before it decays into something more stable and less dangerous. For this reason, elements with shorter half-lives are used for medical reasons. They can decay before they cause harm to the body. Elements with longer half-lives can be used to trace the age of substances, since their rate of decay is constant. As long as a substance contains a radioactive element its approximate age can be traced. For example, all living things are made of carbon, such as people, plants and animals. C-14 can be used to trace the age of any of these things, such as a Viking ship, or papyrus used in ancient Egypt. (Watch C-14 dating video clip) Elements like uranium, with an extremely long half-life, can be used to trace the age of the Earth, since uranium is a natural part of some rocks. Half-Life Calculations For example, if a substance has a half-life of 14 days, half of its atoms will have decayed within 14 days. In 14 more days, half of the remaining half will have decayed. If we start with 10g, after 14 days 5g will be undecayed and after another 14 days, 2.5g will be undecayed. This continues. Initial After 14 Days: Half-Life 1 After 28 Days: Half-Life 2 Decayed 10g 5g Decayed 5g 2.5g 7.5g Each time a half-life passes, half of the sample decays. We can also visualize this using arrows to represent each half-life that passes: 10g 5g 2.5g 14d 14d 1.25g 14d If one half-life is 14 days, 3 half-lives takes 42 days (14 x 3). We can also consider this as fractions of a whole: 1 1/2 1/4 1/8 Example 1: Consider the radioactive isotope (or radioisotope) iodine-131. If we started with 20g of this isotope, how much would we have left after 32.08 days? First, you can find on the table that the half-life of iodine-131 is 8.021 days. We have a half-life of 8.021 days and the time the problem gives us is 32.08 days. How many half-lives have passed? # of Half-Lives = Total Time = 32.08d = 4 half-lives have gone by Half-Life 8.021d Each time a half-life passes, half of the sample decays. Start with 20g and divide that in half 4 times: Draw 4 arrows, which represent each of the 4 Half Lives [then start with 20g] 20 [then proceed to halve each of the end results] 20 10 5 2.5 1.25 At the end of 32,08 days, 4 half-lives have gone by and 1.25g of the original 20g of I-131 remains undecayed. Example 2: What total mass of a 32g sample of 220Fr will remain unchanged after 82.2 seconds? Look up the half-life: Half-Life = 27.4 seconds # of Half-Lives = Total Time = 82.2s/27.4s = 3 half-lives Half-Life 32g 16g 8g 4g At the end of 82,2 seconds, 3 half-lives have gone by and 4g of the original 32g of Fr-220 remains undecayed.