Assignment 10-1 Molecular Weight & Molar Mass A. Define molecular weight: B. Define molar mass: Determine the molecular weight Determine the molar mass in grams in amu of the following substances: of the following substances. (Answers at bottom) (Answers at bottom) 1. H2 2. Mg 3. Au 4. O2 5. Kr 6. CO 7. NaI 8. MgCl2 9. FePO4*2H2O (*means added H2O) 10. Pb(NO3)2 1. Mn 2. Ca 3. CO2 4. BaF2 5. AlCl3*3H2O (*means added H2O) 6. SiO2 7. Hg2O 8. Fe2O3 9. MgSO4 10. Sr(CN)2 Percent Composition Problems - Determine the percentage composition of mass of each element in the compound relative to the total molecular weight of each compound below. 1. H2O 5. K3PO4 (for strong roots & stems) 2. CO2 6. KNO3 (in gun powder) 3. NaCl 7. NH4NO3 (explosive fertilizer) 4. CaCl2 8. (NH4)2SO4 (greens lawns) Assignment 10-2 Quantities of Matter: One step conversions with elements I. Convert to moles. 1. 12.04 x 1023 atoms He 6. 24 grams of carbon 2. 3.01 x 1023 atoms Cu 3. 3.612 x 1023 atoms Fe 4. 100. atoms of Ar 5. 1 atom S II. Convert to mass in grams. 11. 10.0 moles Na 12. 2.20 moles Sn 13. 5.00 moles Ag 14. 0.000 300 mole of gold 15. 1.00 x 107 moles of boron 7. 59.3 grams of tin 8. 98.9 grams of sodium 9. 4999 grams of potassium 10. 0.005 00 gram of neon III. Convert to number of atoms 16. 3.00 moles Ar 17. 8.50 moles Fe 18. 25.0 moles Ar 19. 0.001 00 mole of sodium 20. 1.0 x 10-5 mole of aluminum Assignment 10-3 Quantities of Matter: One step conversions with compounds I. Convert to moles. 1. 6.02 x 1023 molecules CO2 6. 34 g NH3 2. 1.806 x 1023 molecules Cl2 7. 50.0 g CaCO3 23 3. 1.51 x 10 molecules H2O 8. 360 g H2O 4. 1000 molecules P4O10 9. 9.00 grams of sulfuric acid, H2SO4 5. 1 molecule of NH3 10. 1.00 gram of sodium chloride II. Convert to mass in grams. III. Convert to number of molecules. 11. 12. 13. 14. 5.0 moles NH3 4.50 moles NaCl 0.30 mole HCl 0.002 00 mole Na2SO4 15. 1.50 x 10-4 mole silver chloride, AgCl 16. 17. 18. 19. 2.0 moles CO2 1.8 moles PCl3 35.0 moles ammonia, NH3 0.0500 mole sulfur dioxide, SO2 20. 1.00 x 10-3 mole CO Assignment 10-4 Quantities of Matter: 2 Step Problems Suggestion: Begin each problem by sketching a diagram that outlines the steps in the solution to the problem. I. Convert to mass in grams. III. Convert to number of molecules. 23 1. 6.02 x 10 atoms Ca 11. 72 grams HCl 2. 1.204 x 1023 atom Bi 3. 3.01 x 1023 atoms Ni 12. 9.0 grams H2O 4. 1000 atoms of aluminum 5. 1 atom of sodium II. Convert to number of atoms. 13. 14. 15. IV. 6. 540 grams Al 16. 7. 294 grams Au 17. 8. 6.35 grams Cu 9. 2000. grams of magnesium 10. 1.00 gram of lithium 18. 19. 20. 22 grams CO2 500 grams of nitrogen(II)oxide, NO 1.00 gram CCl4 Convert to mass in grams. 6.02 x 1023 molecules Cl2 3.01 x 1023 molecules SO2 1.81 x 1024 molecules CO2 1000. molecules of hydrosulfuric acid, H2S 1 molecule of water Assignment 10-5 Calculations Involving Volume of Gasses at STP Define: a) STP b) molar volume What volumes will the following samples occupy at STP? One step 1. 6.0 moles of O2 Two step 5. 22.0 g of CO2 2. 0.50 moles of CO2 6. 3.01 x 1023 molecules of N2 3. 4. 5.5 moles of ammonia NH3 0.0020 moles of methane, CH4 7. 8. 1.20 x 1023 molecules of NO2 479.4 g of Neon Mixed problems 9. What volume, in liters, will be occupied by 4.70 moles of helium gas at STP? 10. What is the volume, in liters, occupied by 1.00 x 10-3 mole of ammonia gas, NH3, at STP? 11. How many moles are represented by 38.8 ml of hydrogen gas, H2, at STP? 12. What volume in liters at STP is occupied by 1.80 x 1023 molecules of oxygen, O2, gas? 13. What volume in liters at STP is occupied by 1.00 x 10 20 molecules of methane, CH4, gas? 14. How many molecules of nitrogen dioxide, NO2, are present in 11.2 L of the gas at STP? 15. What volume would 8.0 g of methane (CH4) occupy at STP? 16. What volume would 24.0 g of oxygen gas, O2, occupy at STP? 17. What is the mass of 33.6 L of carbon dioxide, CO2, at STP? 10-1 Answers A 1. 2.0 amu (H2) 2. 24.3 amu 3. 197.0 amu 4. 32.0 amu 5. Kr 83.8 amu 6. 28.0 amu 7. 149.9 amu 8. 95.3 amu 9. 186.8 amu 10. 331.2 amu 10-2 Answers 1. 2.00 mol He 2. 0.500 mol Cu 3. 0.600 mol Fe 4. 1.66 x 10-22 mol Ar 5. 1.66 x 10-24 mol S 6. 2.0 mol C 7. 0.500 mol Sn 8. 4.30 mol Na 9. 128 mol K B 1. 54.9 g 2. 40.1 g 3. 44.0 g 4. 175.3 g 5. 187.5 g 6. 60.1 g 7. 417.2 g 8. 159.6 g 9. 120.4 g 10. 139.6 g 10-3 Answers -4 10. 2.47 x 10 mol Ne 1. 1.00 mole CO2 10. 11. 230 g Na 2. 0.300 mole Cl2 11. 12. 261 g Sn 3. 0.251 mole H2O 12. 13. 540 g Ag 4. 1.66 x 10-21 molP4O10 14. 0.0591 g Au 5. 1.66 x 10-24 molNH3 14. 15. 1.08 x 108 g B 6. 2.0 moles NH3 15. 16. 1.81 x 1024 at Ar 7. 0.500 mole CaCO3 16. 24 17. 5.12 x 10 at Fe 8. 20.0 moles H2O 17. 18. 1.50 x 1025 at Ar 9. 0.0918 mole H2SO4 18. 20 19. 6.02 x 10 at Na 19. 1. 40.1 g Ca 2. 41.8 g Bi 3. 29.4 g Ni 4. 4 x 10-20 g Al 13. 11 g HCl 0.284 g Na2SO4 0.0215 g AgCl 1.2 x 1024 mlc CO2 1.1 x 1024 mlc PCl3 2.11 x 1025 mlcNH3 3.01 x 1022 mlc SO2 20. 6.02 x 1020 mlc CO 20. 6.02 x 1018 at Al 10-4 Answers 0.0171 mole NaCl 85 g NH3 263 g NaCl 10-5 Answers 11. 1.2 x 1024 mlc HCl 12. 3.0 x 1023 mlc H2O 13. 3.0 x 1023 mlc CO2 14. 1.00 x 1025 mlc NO 1. 130 L O2 11. 1.73 x 10-3 mol H2 2. 11 L CO2 12. 6.70 L O2 3. 120 L NH3 13. 3.71 x 10-3 L CH4 4. 0.045 L CH4 14. 3.01 x 1023 mlc NO2 5. 3.82 x 10-23 g Na 15. 3.91 x 1021 mlc CCl4 5. 11.2 L CO2 15. 11 L CH4 25 6. 1.20 x 10 atoms Al 16. 71.0 g Cl2 6. 11.2 L N2 16. 16.8 L O2 7. 8.98 x1023 atoms Au 17. 32.1 g SO2 7. 4.47 L NO2 17. 66.0 g CO2 8. 6.02 x 1022 atoms Cu 18. 132 g CO2 8. 532 L Ne 25 -20 9. 4.95 x 10 atoms Mg 19. 5.65 x 10 g H2S 9. 105 L He 10. 8.67 x 1022 atoms Li 20. 2.99 x 10-23 g H2O 10. 2.24 x 10-2 L NH3