Effects of Aerosols in the Earth's Atmosphere Carroll Ellis, Science Educator, MathScience Innovation Center Questions In this activity, you will measure the effect of excess carbon dioxide on the temperature of gas inside of soda bottles and see what the effects of aerosols are on the heating of the gas. What are aerosols and how could they possibly affect the global climate? What are some of the sources of stratospheric aerosols entering the atmosphere? Virginia Standards of Learning 2010 Earth Science (ES.1, ES.13); 2010 Physical Science (PS. 2, PS.7) 21st Century Curriculum Nanotechnology: Size-Dependent Properties—The properties of matter can change with scale. During the transition from bulk material to the nanoscale, a material often exhibits unexpected properties that lead to new functionality. Materials Two or more 2-liter clear soda bottles with the label removed. Identical thermometers for each soda bottle or Vernier LabQuest® Data Logger & 2 Temperature Probes. Opaque tape. Source of carbon dioxide (CO2). Spray glitter. Modeling clay. Safety Use caution goggles when using Alka-Seltzer® and baking powder in water. Directions For your source of carbon dioxide, you may use one of the following methods: 1. Dry CO2 Source - Seltzer Bottle Charges Fill a dry seltzer bottle with one charge of carbon dioxide. You will use the carbon dioxide in the seltzer bottle to fill one of the bottles with carbon dioxide. For this method, both bottles can be left dry. The Effects of Aerosols http://MathInScience.info © MathScience Innovation Center/NASA, 2011 2. Wet CO2 Source - Alka-Seltzer You will put a cup of water into both bottles, then put a couple of AlkaSeltzers into the water in one of the bottles. A tablespoon of baking powder can be substituted for the Alka-Seltzer. 3. Wet CO2 Source - Alka-Seltzer You will put a cup of water into both bottles, then put two Alka-Seltzers into the water in one of the bottles. A tablespoon of baking powder can be substituted for the Alka-Seltzer. 4. Wet CO2 Source Put a cup of club soda or seltzer water in one of the bottles and a cup of tap water into the other bottle. 5. The caps of the bottles will have holes drilled to the same diameter as your thermometer. Place the thermometers through the holes in the caps several inches. Use the modeling clay to hold the thermometers in place and seal the hole. 6. Insert the Vernier temperature probe through the holes in the caps and use the modeling clay to seal the hole. 7. Use the seltzer bottle to fill one of the bottles with CO2, or for the wet CO2 source (method 2), fill the bottles with identical quantities of water and place the Alka-Seltzer into one of the bottles, or (method 3) place identical quantities of seltzer/club soda into one of the bottles and plain tap water into the other. Make sure the liquids are at the same temperature when starting the experiment. 8. Place the caps with thermometers onto the tops of the bottles. 9. Put the bottles into sunshine. Make sure they receive the same amount of sun. NOTE: A heat lamp may be substituted for the sun, but you must be very careful to place the bottles exactly the same distance from the lamp. 10. Shade the thermometers or temperature probes by putting a strip of opaque tape on the outside of the bottles. The tape must be the same length on both bottles. 11. Measure the temperature of the bottles over time. Record the temperature of each bottle every five minutes for a half hour. 12. You now add aerosols to your experiment by using two bottles with spray glitter on the outside of the bottle. 13. Repeat steps 1-7. The Effects of Aerosols http://MathInScience.info © MathScience Innovation Center/NASA, 2011 Time Bottle #1 (air) Temperature C0 Bottle #2 (CO2) Temperature C0 Bottle #3 Aerosols (air) Temperature C0 Bottle #4 Aerosols (CO2) Temperature C0 5 min 10 min 15 min 20 min 25 min 30 min The Effects of Aerosols http://MathInScience.info © MathScience Innovation Center/NASA, 2011 Additional Background Information: Aerosols are tiny liquid and solid particles suspended in the atmosphere. These particles play a critical role in the climate system and are present nearly everywhere, from the upper reaches of the atmosphere to the surface air that humans breathe. They range in size from .01 microns, about the size of the smallest bacteria, to several tens of micrometers, the diameter of human hair. Most aerosols tend to cool Earth’s surface. Overall, scientists estimate that aerosols have a net cooling impact about half the strength of the warming caused by the build-up of greenhouse gases. But, the particles are distributed very differently than greenhouse gases, primarily because the average lifetime of an aerosol particle in the atmosphere is much shorter than that of most greenhouse gases. To predict the impact of climate change on human society, it is critical that scientists know precisely how much warming and cooling aerosols produce in each of Earth's regions. For this, comprehensive knowledge of certain aerosol properties—their size, shape and chemical composition—is needed. However, existing satellite instruments provide only partial information about such aerosol properties. As a result, the impact of aerosols on climate remains much less certain in comparison to that of greenhouse gases. Scientists use ground-based sensors and airborne field campaigns to fill in important details about common aerosols. Such research shows that the bulk of aerosols—about 90 percent—have natural origins. Volcanoes inject huge columns of gases high into the atmosphere that can become sulfate particles, and sandstorms in desert regions whip small pieces of mineral dust into the air. Fires send partially burned black carbon and other smoke particles aloft. The spray from surface waves injects sea salt particles into marine air, and even certain plants produce gases that react with other substances in the atmosphere to produce aerosols. The other 10 percent of aerosols are manmade, or anthropogenic. Fossil fuel combustion produces large amounts of sulfates. Biomass burning, a common method of clearing land, yields smoke comprised mainly of organic matter and black carbon. Diesel engines are another especially prolific producer of black carbon. Deforestation, overgrazing, drought, and excessive irrigation change the soil, often leading to higher rates of dust entering the atmosphere. Aerosol emissions are in flux around the world as economies develop and land use changes. Although sulfate aerosol emissions have declined during recent decades in North America and Europe because of clean air regulations, particle emissions are increasing in many other regions of the world. Biomass burning is a major source of aerosols in South America and Africa. Emissions of black carbon are increasing rapidly in parts of Asia. The Effects of Aerosols http://MathInScience.info © MathScience Innovation Center/NASA, 2011