The Effect of Solvent on the Crystal Structure and Size Distribution of ZnS nanocrystals. ZnS nanocrystals with different structures were synthesized by the solution precipitation method using thiourea and zinc acetate as starting materials in different solvents: water, methanol and N,N- dimethyl formamide(DMF). Our results show that the solvent has direct effect on the structure and size of the final nanoparticles. It was found that using, DMF as solvent, results in producing smaller nanoparticles ,while using the other solvents gives rise to larger nanoparticles. It was also found that using heat during washing the precipitate results in a more homogenous size distribution of ZnS nanocrystals.