Chemical Bonds.doc Michelle Melby © 2010 Chemical Bonds Chemical bonds are forces of attraction that exist between atoms, ions, and molecules. There are many types of chemical bonds, but we are only going to focus on ionic, covalent, and polar covalent (hydrogen) bonds. In 1916, the American chemist Gilbert Newton Lewis proposed that chemical bonds are formed between atoms because electrons from the atoms interact with each other. Lewis had observed that many elements are most stable when they contain eight electrons in their valence (outermost) shell. He suggested that atoms with fewer than eight valence electrons bond together to share electrons and complete their valence shells. Ionic bonds exists between charged particles, called ions. These ions form when electrons jump from one atom to another. Ionic bonds usually form between a metal (which loses electrons) and a nonmetal (which gains electrons). Now that the ions are oppositely charge, they are attracted to each other by electrostatic forces. Ionic compounds form crystals and conduct electricity well. Sodium hydroxide is used to make paper and soap; sodium chloride is table salt; and calcium carbonate can be used as an antacid (like Tums). Covalent bonds exist between atoms that share electrons. Covalent bonds usually form between nonmetal atoms. Covalent molecules move about freely and tend to exist as liquids or gases at room temperature. Methane (greenhouse gas) and oxygen gas are formed through covalent bonds. Chemical Bonds.doc Michelle Melby © 2010 Polar covalent bonds are a type of covalent bond. There are many types of polar covalent bonds, but we will concentrate on one type: the hydrogen bonds of water. In the polar covalent bonds of water, the electrons shared by the atoms spend a greater amount of time, on the average, closer to the Oxygen nucleus than the Hydrogen nucleus. The result of this pattern of unequal electron association is a charge separation in the molecule, where one part of the molecule, the Oxygen, has a parital negative charge and the Hydrogens have a partial positive charge. A hydrogen bond is formed when a charged part of a molecule having polar covalent bonds forms an electrostatic (charge, as in positive attracted to negative) interaction with a substance of opposite charge. Hydrogen bonds are classified as weak bonds because they are easily and rapidly formed and broken under normal biological conditions. Hydrogen bonds are extremely important in biological systems. Their presence explains many of the properties of water. They are used to stabilize and determine the structure of large macromolecules like proteins and nucleic acids. They are involved in the mechanism of enzyme catalysis. Chemical Bonds Summary: Now that you have completed the paragraphs, summarize the different features of the three types of bonds by completing the table below: Ionic Bond Formed between? How formed? Examples of substances containing this bond Properties of substances containing this bond Covalent Bond Hydrogen Bond Chemical Bonds.doc Michelle Melby © 2010 Human Bonding Part 1: The covalent bonding of H and H to make H2 . A good example of a covalent bond is that which occurs between two hydrogen atoms. Atoms of hydrogen (H) have one valence electron in their first electron shell. Since the capacity of this shell is two electrons, each hydrogen atom will "want" to pick up a second electron. In an effort to pick up a second electron, hydrogen atoms will react with nearby hydrogen (H) atoms to form the compound H2. Because the hydrogen compound is a combination of equally matched atoms, the atoms will share each other's single electron, forming one covalent bond. In this way, both atoms share the stability of a full valence shell. Use this as an example with fewer students so that the whole class model in part 2 will be easier. Students 1 and 2 represent the single protons in the nucleus of each hydrogen atom. Students 3 and 4 represent the single electrons orbiting the nucleus of each hydrogen atom. This can be done in the class room but will require a bit of room. The electrons should be walking or running in orbit around their proton. Direct the electrons to form a covalent bond by running around their hydrogen and then the other hydrogen. This will show that the two hydrogens share their electrons to complete their valence shells and in the process become a hydrogen molecule. Part 2: The ionic bonding of Na and Cl to make salt. The element sodium is a silver-colored metal that reacts so violently with water that flames are produced when sodium gets wet. The element chlorine is a greenish-colored gas that is so poisonous that it was used as a weapon in World War I. When chemically bonded together, these two dangerous substances form the compound sodium chloride, a compound so safe that we eat it every day - common table salt! + sodium metal chlorine gas table salt Assign students to represent the different parts of sodium and chlorine atoms. You can make name tags or have the students make name tags if this helps your students remember their role. The students representing the nucleus of each atom will be the leaders of their atom. Student 1 represents 11 protons of Na Student 2 represents 12 neutrons of Na Student 3 represents 17 protons of Cl Student 4 represents 18 neutrons of Cl The students representing the electrons of each atom will follow the directions of the nucleus. Students 5-15 represent the 11 electrons of Na Students 16-32 represent the 17 electrons of Cl Chemical Bonds.doc Michelle Melby © 2010 Find a large open space and have the students form their atoms. The nucleus students should be in the middle and the electrons students should be arranged into their appropriate shells. The electrons should be running or walking around the nucleus of their atom. The nucleus of each atom will direct the transfer of an electron to make an ionic bond and table salt! Chemical Bonding Illustration. Short on space or time? Have the students pair up and make a cartoon or illustration of two bonded atoms. You may use the examples in this activity or have a list of new atoms, but they should be simple. The cartoons should be a little abstract and creative, but everything should be labeled. This can be done on paper or white boards. (See the illustration at the beginning of this activity.)