MATERIAL SAFETY DATA SHEET SECTION 1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Universal Fibers, Inc. Caller #8930 Bristol, VA 24203-8930 14401 Industrial Park Road Bristol, VA 24202 Date Prepared: 05-22-13 Date Reviewed: 05-22-13 Responsible Person: Dewey Fulton [EH&S Mgr.] (276) 669-1161 Phone (276) 669-3304 Fax COMMON NAME: Pigmented Polyester BCF Fiber CHEMICAL NAME: Proprietary Mixture CHEMICAL FAMILY: Poly(ethylene terephthalate) CAS# 025038-59-9 SECTION 2 COMPOSITION / INFORMATION ON INGREDIENTS Composition CAS# Exposure Limits % by Wt. Poly(ethylene terephthalate) Ethoxylated Components 025038-59-9 Proprietary not established TLV: 10 ppm >98 <0.2 NOTE: Encapsulated pigments are not considered hazardous by nature or concentration in this fiber form. TLV = ACGIH Threshold Limit SECTION 3 HAZARDS IDENTIFICATION Potential Health Effects: Eye: Polyester fiber does not cause significant eye irritation or eye toxicity. Skin: Polyester fiber does not present significant skin irritation. Persons with pre-existing skin disorders may be more susceptible to the effects of this fiber. Ingestion: Polyester fiber does not present significant potential for ingestion. Inhalation: Avoid breathing dust. Polyester fiber, although OSHA and ACGIH have not established specific exposure limits for this material, have established limits for nuisance dusts (dusts from fibers is referred to as “fly”). OSHA PEL – Total – 15 ppm, Respirable – 5 ppm ACGIH TLV – Total – 15 ppm, Respirable – 5 ppm The inhalation of thermal degradation by-products may lead to metal fume fever. Chronic Information: There are no known chronic effects associated with polyester fiber. Teratology Information: There are no known birth defects associated with polyester fiber. Reproduction Information: There are no known reproductive effects associated with polyester fiber. SECTION 4 FIRST AID MEASURES Eyes: Immediately wash eyes with running water for 15 minutes. If irritation develops, get medical attention. 1 Skin: Wash affected areas with soap and water. If irritation develops, get medical attention. Ingestion: If swallowed, dilute with water and immediately induce vomiting. Never give fluids or induce vomiting if the victim is unconscious or having convulsions. Get medical attention. Inhalation: Move to fresh air. Aid in breathing, if necessary, and get immediate medical attention. Notes to Physicians: No special procedures known. SECTION 5 FIRE FIGHTING MEASURES Flammable properties: Flash point: not available Flammable limits: Lower flammable limit: not available Upper flammable limit: not available Autoignition temperature: not available Hazardous combustion products: carbon monoxide, carbon dioxide, acetaldehyde, (possible) metal oxides, Extinguishing media: Use water mist, carbon dioxide, dry chemical, or foam extinguishing media. Fire fighting instructions: Fire fighters should wear normal protective equipment (full bunker gear) and positive-pressure self-contained breathing apparatus. SECTION 6 ACCIDENTAL RELEASE MEASURES Small spill: Polyester fiber does not pose a significant spill hazard. Sweep or vacuum up and incinerate or bury in a licensed facility. Large spill: Polyester fiber does not pose a significant spill hazard. Sweep or vacuum up and incinerate or bury in a licensed facility. SECTION 7 HANDLING AND STORAGE Handling: Avoid excessive heat and sources of ignition. Protect from moisture and sunlight. Storage: Avoid excessive heat and sources of ignition. Store in a dry area. Protect from moisture and sunlight. SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering controls: Control airborne concentrations of dust below the exposure limits. Use ventilation for normal comfort. Respiratory protection: No respiratory protection is needed unless dust is generated. Use NIOSH/ MSHA approved equipment when airborne exposure is excessive. Consult Respirator manufacturer to determine appropriate type equipment for given Application. The respirator use limitations specified by NIOSH/MSHA Or the manufacturer must be observed. Skin protection: Good industrial hygiene practice should be observed by washing after use. Eye protection: The use of safety glasses is suggested. Other personal protection data: Eyewash fountains and safety showers must be easily accessible. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Boiling point: not available 2 Melting point: decomposes above 300 deg C [570 degrees F] in presence of oxygen. Vapor pressure: not available Vapor density (air = 1): not available Solubility in water: <0.6 grams per 100 grams at 20 degrees C pH: no data Odor: no perceptible odor Appearance: Colored fiber Percent volatile: < 1% SECTION 10 STABILITY AND REACTIVITY Chemical stability: stable Incompatibility: strong oxidizing agents, acids, and bases Hazardous decomposition products: carbon monoxide, carbon dioxide, acetaldehyde, (possible) metal oxides Hazardous polymerization: does not occur SECTION 11 TOXICOLOGICAL INFORMATION Poly(ethylene terephthalate): Oral ALD: > 10,000 mg/kg in rats Poly(ethylene terephthalate) is not a skin irritant, but a mild eye irritant in animals. No adverse effects are described in animals from short exposures by inhalation, ingestion, or skin contact. Animal testing indicates that poly(ethylene terephthalate) does not have carcinogenic, mutagenic, embryotoxic, nor reproductive effects. SECTION 12 ECOLOGICAL INFORMATION No ecological data has been found on polyester fiber in a reasonable extensive search of the scientific literature. SECTION 13 DISPOSAL CONSIDERATIONS Sweep up or vacuum and incinerate or bury in a licensed facility. Any disposal practice must be in compliance with all local, state, and federal laws and regulations. SECTION 14 TRANSPORT INFORMATION DOT Proper shipping name: none DOT Technical name: none DOT Primary hazard class: none DOT Secondary hazard class: none DOT Label required: none DOT Placard required: none DOT Poison constituent:: none DOT UN/NA code: none Emergency response guide #: none Bill of lading description: Synthetic yarn, exceeds 15 pounds per cubic feet density International transportation: no available data for this section found 3 SECTION 15 REGULATORY INFORMATION OSHA Hazard communication rule, 29 CFR 1910.1200: Polyester fiber is not considered hazardous. CERCLA /SUPERFUND, 40 CFR 117, 302: Polyester fiber is not regulated under CERCLA and contains no Reportable Quantity (RQ) substances. SARA Hazard category: Polyester fiber has been reviewed according to the EPA hazard categories promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories: no hazard category SARA 313 Information: Polyester fiber contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372: none Toxic Substances Control Act (TSCA): All of the ingredients of polyester fiber are on the TSCA Inventory list. California Proposition 65: The following statement is made in order to comply with the California Safe Drinking Water and Toxic Enforcement Act of 1986: Polyester fiber does not contain any regulated substance under California Proposition 65. SECTION 16 OTHER INFORMATION HMIS Hazard Ratings: Health: 0 Fire: 1 Reactivity: 0 Special: Manufacturer’s information: While Universal Fibers, Inc. believes the data set forth herein are accurate as the date hereof, Universal Fibers Inc. makes no warranty with respect thereto and expressly disclaims all liability for reliance thereon. Such data are offered solely for consideration, investigation, and verification. 4