section 16 other information

advertisement
MATERIAL SAFETY DATA SHEET
SECTION 1
CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Universal Fibers, Inc.
Caller #8930
Bristol, VA 24203-8930
14401 Industrial Park Road
Bristol, VA 24202
Date Prepared: 05-22-13
Date Reviewed: 05-22-13
Responsible Person: Dewey Fulton [EH&S Mgr.]
(276) 669-1161 Phone
(276) 669-3304 Fax
COMMON NAME: Pigmented Polyester BCF Fiber
CHEMICAL NAME: Proprietary Mixture
CHEMICAL FAMILY: Poly(ethylene terephthalate) CAS# 025038-59-9
SECTION 2
COMPOSITION / INFORMATION ON INGREDIENTS
Composition
CAS#
Exposure Limits
% by Wt.
Poly(ethylene terephthalate)
Ethoxylated Components
025038-59-9
Proprietary
not established
TLV: 10 ppm
>98
<0.2
NOTE: Encapsulated pigments are not considered hazardous by nature or concentration
in this fiber form.
TLV = ACGIH Threshold Limit
SECTION 3
HAZARDS IDENTIFICATION
Potential Health Effects:
Eye: Polyester fiber does not cause significant eye irritation or eye toxicity.
Skin: Polyester fiber does not present significant skin irritation. Persons with pre-existing skin
disorders may be more susceptible to the effects of this fiber.
Ingestion: Polyester fiber does not present significant potential for ingestion.
Inhalation: Avoid breathing dust. Polyester fiber, although OSHA and ACGIH have not established
specific exposure limits for this material, have established limits for nuisance dusts
(dusts from fibers is referred to as “fly”).
OSHA PEL – Total – 15 ppm, Respirable – 5 ppm
ACGIH TLV – Total – 15 ppm, Respirable – 5 ppm
The inhalation of thermal degradation by-products may lead to metal fume fever.
Chronic Information: There are no known chronic effects associated with polyester fiber.
Teratology Information: There are no known birth defects associated with polyester fiber.
Reproduction Information: There are no known reproductive effects associated with polyester fiber.
SECTION 4
FIRST AID MEASURES
Eyes: Immediately wash eyes with running water for 15 minutes. If irritation develops, get medical
attention.
1
Skin: Wash affected areas with soap and water. If irritation develops, get medical attention.
Ingestion: If swallowed, dilute with water and immediately induce vomiting. Never give fluids
or induce vomiting if the victim is unconscious or having convulsions. Get medical attention.
Inhalation: Move to fresh air. Aid in breathing, if necessary, and get immediate medical attention.
Notes to Physicians: No special procedures known.
SECTION 5
FIRE FIGHTING MEASURES
Flammable properties:
Flash point: not available
Flammable limits:
Lower flammable limit: not available
Upper flammable limit: not available
Autoignition temperature: not available
Hazardous combustion products: carbon monoxide, carbon dioxide, acetaldehyde, (possible)
metal oxides,
Extinguishing media: Use water mist, carbon dioxide, dry chemical, or foam extinguishing media.
Fire fighting instructions: Fire fighters should wear normal protective equipment (full bunker gear)
and positive-pressure self-contained breathing apparatus.
SECTION 6
ACCIDENTAL RELEASE MEASURES
Small spill: Polyester fiber does not pose a significant spill hazard. Sweep or vacuum up and
incinerate or bury in a licensed facility.
Large spill: Polyester fiber does not pose a significant spill hazard. Sweep or vacuum up and
incinerate or bury in a licensed facility.
SECTION 7
HANDLING AND STORAGE
Handling: Avoid excessive heat and sources of ignition. Protect from moisture and sunlight.
Storage: Avoid excessive heat and sources of ignition. Store in a dry area. Protect from moisture
and sunlight.
SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering controls: Control airborne concentrations of dust below the exposure limits.
Use ventilation for normal comfort.
Respiratory protection: No respiratory protection is needed unless dust is generated. Use NIOSH/
MSHA approved equipment when airborne exposure is excessive. Consult
Respirator manufacturer to determine appropriate type equipment for given
Application. The respirator use limitations specified by NIOSH/MSHA
Or the manufacturer must be observed.
Skin protection: Good industrial hygiene practice should be observed by washing after use.
Eye protection: The use of safety glasses is suggested.
Other personal protection data: Eyewash fountains and safety showers must be easily accessible.
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Boiling point: not available
2
Melting point: decomposes above 300 deg C [570 degrees F] in presence of oxygen.
Vapor pressure: not available
Vapor density (air = 1): not available
Solubility in water: <0.6 grams per 100 grams at 20 degrees C
pH: no data
Odor: no perceptible odor
Appearance: Colored fiber
Percent volatile: < 1%
SECTION 10
STABILITY AND REACTIVITY
Chemical stability: stable
Incompatibility: strong oxidizing agents, acids, and bases
Hazardous decomposition products: carbon monoxide, carbon dioxide, acetaldehyde, (possible)
metal oxides
Hazardous polymerization: does not occur
SECTION 11
TOXICOLOGICAL INFORMATION
Poly(ethylene terephthalate):
Oral ALD: > 10,000 mg/kg in rats
Poly(ethylene terephthalate) is not a skin irritant, but a mild eye irritant in animals. No adverse effects are
described in animals from short exposures by inhalation, ingestion, or skin contact. Animal testing indicates
that poly(ethylene terephthalate) does not have carcinogenic, mutagenic, embryotoxic, nor reproductive
effects.
SECTION 12
ECOLOGICAL INFORMATION
No ecological data has been found on polyester fiber in a reasonable extensive search of the scientific
literature.
SECTION 13
DISPOSAL CONSIDERATIONS
Sweep up or vacuum and incinerate or bury in a licensed facility. Any disposal practice must be in
compliance with all local, state, and federal laws and regulations.
SECTION 14
TRANSPORT INFORMATION
DOT Proper shipping name: none
DOT Technical name: none
DOT Primary hazard class: none
DOT Secondary hazard class: none
DOT Label required: none
DOT Placard required: none
DOT Poison constituent:: none
DOT UN/NA code: none
Emergency response guide #: none
Bill of lading description: Synthetic yarn, exceeds 15 pounds per cubic feet density
International transportation: no available data for this section found
3
SECTION 15
REGULATORY INFORMATION
OSHA Hazard communication rule, 29 CFR 1910.1200: Polyester fiber is not considered hazardous.
CERCLA /SUPERFUND, 40 CFR 117, 302: Polyester fiber is not regulated under CERCLA and
contains no Reportable Quantity (RQ) substances.
SARA Hazard category: Polyester fiber has been reviewed according to the EPA hazard categories
promulgated under Sections 311 and 312 of the Superfund Amendment and
Reauthorization Act of 1986 (SARA Title III) and is considered, under
applicable definitions, to meet the following categories: no hazard category
SARA 313 Information: Polyester fiber contains the following substances subject to the reporting
requirements of Section 313 of Title III of the Superfund Amendments and
Reauthorization Act of 1986 and 40 CFR Part 372: none
Toxic Substances Control Act (TSCA): All of the ingredients of polyester fiber are on the TSCA
Inventory list.
California Proposition 65: The following statement is made in order to comply with the California Safe
Drinking Water and Toxic Enforcement Act of 1986: Polyester fiber does
not contain any regulated substance under California Proposition 65.
SECTION 16
OTHER INFORMATION
HMIS Hazard Ratings: Health: 0
Fire: 1
Reactivity: 0
Special:
Manufacturer’s information: While Universal Fibers, Inc. believes the data set forth herein are accurate
as the date hereof, Universal Fibers Inc. makes no warranty with respect
thereto and expressly disclaims all liability for reliance thereon.
Such data are offered solely for consideration, investigation, and
verification.
4
Download