THERMAL ANALYSIS OF A DISCARDED PLASTIC BOTTLE SOLAR WATER WALL Ramal Janith Samarasinghe, Richard John Schuhmann B.S., Mechanical Engineering, Department of Mechanical and Nuclear Engineering; Assistant Professor of Engineering Design and Science Technology and Society ABSTRACT 2. SCIENTIFIC BACKGROUND Solar Trombe walls have the ability to passively store and subsequently radiate solar energy into a dwelling. The objective of this project was to investigate the feasibility of using a solar water wall constructed of discarded plastic water bottles to heat and insulate a house in an urban Moroccan slum community. Initial testing was aimed at determining the heat absorption and radiation properties of different liquids and developing a thermal model of the system. Subsequently, a scale model of a house with a solar water wall was built and temperature variations in the bottles and the inside of the house were measured at various times of the day. This test was repeated using bottles with various types of liquids. The data were used to determine the effectiveness of the wall in the absorption, retention and radiation of heat. A wall of bottles filled with water and black dye proved to be the most effective at absorbing heat during the daytime and radiating it back into the house during the nighttime. A solar Trombe water wall is a closed system with a fixed mass; therefore the principles of conservation of mass, energy and momentum can be applied to this system in accordance with the First Law of Thermodynamics. 1. INTRODUCTION Morocco is a country in Northern Africa with a population of around 32 million and a land area of 446,550 km² [1]. Out of the 5 million tons of solid waste generated annually in Morocco only 2% is recycled.[2] Much of the waste generated in Morocco is plastic and much of the plastic waste is empty water bottles. Morocco has an equatorial climate with extreme temperatures (i.e. upward of 80°F during the daytime and close to 40°F in the nighttime).[3] An appropriate thermal wall must absorb heat during the day and radiate heat into the house during the night. Enabling poor urban Moroccan residents to make use of discarded plastic bottles to create a heating system for households meets with the triple bottom line[4] of sustainable engineering design; plastic is kept out of landfills (and streets) and homes provide greater comfort to occupants at little or no cost. Water has a much higher volumetric heat capacity (4186KJ/m3-K) than wood, adobe, or concrete whose heat capacity values range from 1300KJ/m3-K to 2600KJ/m3-K and thus can store thermal energy better than traditional building materials. The stored thermal energy is then released as heat into a building space through convection; the thermal conductivity of water (0.6W/m-K) is also higher than wood and dry adobe and aids in this heat transfer process.[5] A wall constructed with water has better absorption and heat releasing properties than a wall constructed with more traditional building materials. The following equation which is a simplification of the conservation of energy equation describes the thermodynamics of the solar water wall system. Qin – Qout = ΔU Where: Qin = Heat energy into the system Qout = Heat energy out of the system ΔU = Change in system internal energy This experimental system consisted of the water filled bottles in the wall and a data acquisition unit. The energy input to the system consisted of solar radiation from sunlight. The output of energy corresponded to the heat that was radiated from the wall into the home. In order to quantify this, temperature was measured as voltage change across the data acquisition unit. 3. EXPERIMENTAL PROCEDURE 3.1. Test to determine properties of liquids Experiments were conducted in Spring 2010 to analyze the heat absorption and retention capacities of various test liquids. Bottles filled with a test liquid were monitored with thermocouples and temperature variation recorded by an Agilent 34970A data acquisition unit. A total of 15 bottles were tested, consisting of 3 bottles each of 5 different modifications. All 15 bottles were one liter (approximately 33.81oz) AquafinaTM bottles. The water used was plain tap water from the State College area. Because the color black absorbs all the wavelengths of incident solar radiation, and reflects none, the first modifications to a clear bottle and pure tap water were to paint one bottle black and add black food dye to the water in another.[6] The effect of having photosynthetic organic matter in the bottle was tested by using aquatic plants in three of the bottles. To compare the efficiency of heat absorption by water with the efficiency of heat absorption of another liquid with a different heat capacity, commercial vegetable oil was used in 3 of the bottles. In summary, the final experimental setup comprised: i. 3 bottles with tap water ii. 3 bottles with tap water dyed black using five drops of food dye per Liter of water iii. 3 bottles containing tap water with their outside surfaces painted black iv. 3 bottles with tap water containing aquatic plants v. 3 bottles with commercial vegetable oil The bottles fitted with thermocouples were placed next to a large south facing window. The Agilent 34970A data acquisition unit collected readings once every 10 minutes for 8 days (3/25/2010 – 4/2/2010) from the thermocouples inside the bottles. A total of 1129 readings were collected from 17 channels: 15 channels for collecting temperature data from inside the bottles, 1 channel for collecting room temperature data and 1 channel for collecting sunlight intensity data from the pyranometer. The data were transferred to a computer and graphs were plotted in Excel to view the results. 3.2 Constructing a pyranometer Insolation is a measure of the sunlight reaching the horizontal surface of the Earth and is measured in W/m2. Insolation is affected by various factors including time of the day, time of the year, geographical location, and humidity and can be measured using a pyranometer. An inexpensive pyranometer can be constructed using a miniature silicon solar cell detector. The photo detector is enclosed in a plastic casing (covered by Teflon) and measures the voltage of wavelengths emitted by the sun It is important to keep the photo detector face clean and unobstructed in order to ensure accurate results. Fig 1: Pyranometer Circuit Diagram 3.3. Construction of model In Fall 2010 a model of an urban house in Morocco was constructed using wood and cardboard into which a scaled wall was built. The wall frame was designed to withstand the weight of 30 0.5L bottles filled with water. A 21”x21” frame was constructed to house the water bottles at a 60° angle so as to obtain the maximum effect of the incoming sunlight and to allow easy access to the bottles to modify experimental conditions. The solar water wall contained three rows of ten bottles each for a total of thirty bottles. Thermocouples were placed inside of each plastic water bottle as well as at locations behind the wall and inside of the model home to measure temperatures. (Fig 2) The wall was placed at the end of a 21”x21”x40” cardboard box which was used to model the house. 3.4. Selection of liquid In order to achieve a set of comparative results, two tests were conducted using two different liquids inside the plastic water bottles. The initial test was performed between 11/5/2010 and 11/12/2010 with State College tap water. A subsequent test was performed between 11/15/2010 and 11/20/2010 with water (0.5 L) mixed with black food dye (5 drops) inside of the bottles. Black dye was selected based on the results of the experiment conducted in spring 2010 which studied and compared the properties of various liquids. 3.5. Experimental setup The experimental apparatus was located in a temperature controlled room used to house computer servers on the south side of the third floor of the Hammond Building at the Pennsylvania State University in University Park, Pennsylvania. This allowed for a comparative analysis between the temperature of the room and the temperature inside the model to observe the insulating effects of the solar water wall. The experiments were conducted between 11/5/2010 and 11/20/2010 and the southern exposure allowed the bottles to capture and absorb the maximum amount of sunlight throughout the day. An Agilent 34970A data acquisition system collected and stored temperature readings from the thermocouples every ten minutes over a span of 5 days for the first test and over a span of 7 days for the second test. not included in the results as the thermocouple failed after the first several readings. Hence, only two groups of readings were used to determine the average for the bottles containing the aquatic plants. Once the averages were determined, a graph of temperature against time was plotted. Fig 2 shows the distribution of the thermocouples in the wall and the house. The blue rectangles represent the water bottles in the wall and numbers represent the channels of the data acquisition unit. Channels 6 to 11 monitored thermocouples that measured the bottle temperatures. Channels 12 to 16 monitored thermocouples that measured the temperatures inside the house. Channel 1 monitored a thermocouple which measured the temperature at the exterior of the house and Channel 17 was connected to the pyranometer[7] that was used to measure solar intensity. Fig 3: Graph of temperatures vs. time comparing the properties of liquids (spring 2010) Analysis of this graph indicated that the bottle painted black had the maximum heat absorption followed closely by the bottle that contained the aquatic plants. The temperature fluctuations in the bottles changed consistently relative to pyranometer readings. 4.2 Analysis of heat absorption and heat retention in the model house Fig 2: Distribution of thermocouples in the wall and the house 4. RESULTS 4.1 Comparison of properties of liquids The readings from the data acquisition unit acquired in Spring 2010 were first transferred to a spreadsheet on the computer. The data for each bottle type included three readings every ten minutes for duration of 8 days. The 3 data points for each ten minute interval (corresponding to one data point each 10 minutes for each bottle within a bottle type) were averaged to yield a single 10-minute average temperature for each bottle type. The readings obtained from one of the bottles with aquatic plants were The data acquired in Fall 2010 was downloaded into a computer and plots of temperature vs. time were created. Each data point increment represented 10 minutes of real time. The first data set was acquired with the bottles filled with just tap water. Figures 4 and 5 show the temperature variation with respect to time for the wall and the inside of the house respectively. Fig 4: Graph of temperatures in wall of bottles filled with water (fall 2010) Fig 5: Temperatures in house with wall of bottles filled with water (fall 2010) It was observed that when the exterior temperature was high, the bottles heated up to around 20°F above the outside temperature and the temperature of the inside of the house rose proportionally. This result is undesirable since in Morocco the daytime temperatures can reach upward of 80°F which exceeds a comfortable indoor temperature. During the nighttime, however, when the temperature drops, the house remains warmer than the outside as the bottles radiate heat that was absorbed earlier in the day. Next, a data set was obtained with the bottles filled with water with black food dye added. Data was acquired for a period of 5 days and graphs of temperature vs. time were plotted. Figures 6 and 7 show the graphs for the wall and the house respectively. Fig 6: Temperatures in wall of bottles filled with water and black dye (fall 2010) Fig 7: Temperatures in house with wall of bottles filled with water and black dye (fall 2010) In this case, the temperatures of the bottles fluctuated similar to the earlier data. Since black color absorbs all wavelengths of light, it was expected to increase the ability of the liquid to store more energy. The fact that the sunlight was now blocked from entering the house by the dye was also a cause for seeing lower interior daytime temperatures. When clear water was used, the direct exposure of the air inside the house to sunlight caused the high temperatures during daytime as shown in figure 5. Adding the black dye to the water blocked the sunlight from going inside and heating the air and thus the daytime indoor temperatures were lower as shown in figure 7. In summary, temperature within the house followed a similar trend to the outside temperature during the daytime and remained comfortable (i.e. around 70°F). The temperature within the house stayed warmer than the outside during the night. These combined results are a more ideal outcome for practical use in Morocco. 5. CONCLUSIONS 8. REFERENCES The goal of this project was to observe how a solar water wall would heat up and insulate a house through determining the heat absorption and radiation properties of different liquids, developing a thermal model of the system and conducting experiments on a scale model. Data was collected for walls constructed with plastic bottles filled with water and water with black dye. From the results of the experiments, a conclusion was reached that the wall made of bottles filled with water and black dye was more suitable for the purpose of insulating and heating the house. The bottles with black dye absorbed solar energy and heat from the outside air during the day without increasing the temperature of the inside of the house and more effectively radiated the heat back to the house during the night when the solar energy ceased and outside temperatures dropped. [1] Statistics by country – Morocco, Central Intelligence Agency – World Fact Book, 2010. [2] Solid Waste Management Summary, Mediterranean Environmental Technical Assistance Program, Morocco, 2003. [3] Casablanca, Morocco: Climate, Global Warming, and Daylight Charts and Data, http://www.climatecharts.com/Locations/f/FM60155.php [4] Elkington, J., Cannibals with forks: The triple bottom line of 21st century business. New Society Publishers, British Columbia, Canada, 1998. [5] Incopera F.P., DeWitt D.P., Bergman T.L., Lavine A.S., Fundamentals of Heat and Mass Transfer, 6th Edition, Wiley, Hoboken, NJ, 2006. [6] Tipler, P.A., Loewellyn, R.A., Blackbody Radiation, Modern Physics, 5th edition, W. H. Freeman, New York, NY, 2008. [7] Brooks, D., Measuring sunlight at earth’s surface: Build your own pyranometer, 2009. 6. RECOMMENDATIONS These results showed the effects that different liquids had on the absorption and radiation rates of a solar wall. Future studies should continue experimenting with various other liquids with better thermal properties. (e.g. seawater) It would also be useful to build two identical models which enable comparison of two different liquids, bottles, bottle angles etc. under the same operating conditions. Also, conducting these experiments in an outdoor environment would produce results that would better simulate a real world situation. Another possible solution to increase the efficiency of the wall would be to drape a tarp on the inside of the wall during the day and on the outside of the wall during the night so as to improve absorption and radiation rates. To improve the validity of the model, scaled bottle sizes would also be an improvement 7. ACKNOWLEDGEMENTS The authors extend their sincere thanks to researchers Shruthi Baskaran, Abhinav Chowdhri, Bill Finney, Tyler Pritz, Justin Markel, Majd Daher, Andy Gula and Christian Glaug for all their hard work, Dr. Lau and Dr. Poese of The Pennsylvania State University for offering their knowledge and expertise, and Adam Hackenberg and Scott Pusey for allowing access to Room 303 Hammond to conduct the experiments. The project would not have been possible without all of their guidance and assistance.