بسم هللا الرحمن الرحيم Final Exam Period 2 Chem. 541 / Group 34142 Date: 13/03/1431- 32/05/2010 Student Name:---------------------------------------------------------------------Student’s Id. No.:------------------------------1. The correct IUPAC name for the following compound is CH3CH2 CH2CH3 N O a) N,N-diethyl-3-amino-2-pentanone b) Diethylbut-2-one-3-amine c) Diethylbut-4-one-3-amine d) N,N-diethyl-3-amino-4-pentanone 2. Which is the most reactive compound in the electrophilic aromatic substitution? CH3 a) CHO b) c) NH2 d) 3. Addition of Grignard reagent to any ketone will give : a) Primary alcohol b) Scondary alcohol c) Tertiary alcohol 1 d) Carboxylic acid 4. The correct IUPAC name for the following compound is O Cl a) Isobutanoyl chloride b) 3-Methyl-butanoyl chloride c) 1-Chloro-3-methylbutanone d) 2-Methyl-butanoyl chloride 5. Which of the following is a correct name according to IUPAC rules? a) 2-Methylcyclohexane b) 2-Ethyl-2-methylpentane b) 3,4-Dimethylpentane d) 3-Ethyl-2-methylpentane 6. The structure of Styrene is CH3 NH2 a) b) CH=CH2 OCH3 c) d) 7. Which of the following amines is the most basic NH2 NH2 NO2 NH2 c) d) NO2 a) b) 2 8. How are these compounds related? H H H C C H H H O H H C H O C H a) The same H H b) Geometrical isomers c) Structural isomers d) Not related at all 9. All of the following compounds can form intermolecular hydrogen bonds except a) Acids b) Alcohols c) Thiols d) Aldehydes 10. What is the product of this reaction? + CH3MgI a) CH4 H2O b) CH3CH3 c) CH3OH d) CH3OCH3 11. The compound of the highest acidity is O O O O OH OH OH OH F a) 12. OCH3 HO b) c) 2,3-Dimethyl-2-butene undergoes catalytic hydrogenation to give: a) 2,3-Dimethylbutane b) 2-Methylpentane c) 2,2-Dimethylbutane d) 3-Methylpentane 3 d) 13. The main product of the following reaction is CH3CH2OH H / + CH3CH2COOH O O O b) a) O O d) c) O O 14. The correct IUPAC name of the following compound is a) 2-Hydroxy-butanal b) 2-Hydroxy-butan-3-one c) 3-Hydroxy-butan-2-one d) 3-Oxo-2-butanol 15. 3-Cyclopentene carboxylic acid is CHO a) COOH COOH CHO b) c) d) 16. Which of the following compounds will show geometrical isomerism? a) CH2=CHCl2 b) ClCH=CHBr c) CH2=CHCl d) Cl 2C=CBr2 17. Which of the following is ketal OR NHR NHOH NHNH2 RO a) b) c) 4 d) 18. The structure of vinyl bromide is Br Br CH2=CH-Br Br a) b) c) 19. What is the best name for the following compound? H H C CH3-CH2 CH2-CH2CH3 C a) 3-Methylenehexane b) 2-Propyl-1-butene c) 4-Ethyl-4-pentene d) 2-Ethyl-1-pentene 20. Amines can be prepared by the reaction of a) Acid + Alcohol b) Alkyl halides + Ammonia c) Acid +Base d) Two molecules of alcohols 21. The molecule of the highest boiling point is a) CH3-CH2-CH2-CHO b) CH3CH2CH2CH2OH c) CH3CH2OCH3CH2 d) CH3CH2CH2COOH 5 d) 22. The main product of the following reaction is i) O3 / CCl4 ii) Zn / H2O O a) O b) O O O c) O d) H H H H O O 23. Which of the following compounds is not aromatic a) b) c) d) 24. What is the major product expected from the following reaction? H3C a) C C CH3-C=CH2 Cl HCl H H3C b) H C H C Cl c) CH3-CH2-C-H Cl 6 Cl Cl d) CH3-C-CH3 Cl 25. What is the major product of the following reaction? HBr H2C CH-CH2-OH Br b) CH2=CH-CH2-Br a) CH3-CH-CH2-Br OH Br d) CH3-CH-CH2-Br CH3-CH-CH2-OH c) 26. What is the major product of the following reaction? CH3-CH2-CH-CH3 + ethanol / heat KOH Cl a) CH2 =CH-CH2-CH3 b) CH3-CH=CH-CH3 c) CH3-CH2-CH2-CH3 d) CH3-CH2-CH-CH3 OH 27. The structure of 2-butyne-1,4-dioic acid is a) HOOC C c) HOOC H2C C COOH C C COOH b) HOOC C H C H COOH d) HOOC C C COOCH3 28. The correct name for the following structure is: CH3 CH2CH3 Cl a) 1-Chloro-3-ethyl-4-methylcyclohexane b) 4-Chloro-2-ethyl-1-methylcyclohexane c) 1-Methyl-2-ethyl-4-chlorocyclohexane d) 5-Chloro-1-ethyl-2-methylcyclohexane 7 29. The product of the following Coery-House synthesis is: + CH3CH2Br Li(CH3)2Cu a) n-Butane b) n-Hexane c) Isobutane d) n-Propane ___________________________________________________________ 30. What is the major product of the following reaction? CH3-CH=CH2 + Br2, H2O b) CH3-CH-CH2 a) CH3-CH2-CH2 Br Br Br OH OH Br OH d) CH3-CH-CH2 c) CH3-CH-CH2 31. Which compound of the following would not give Aldol condensation reaction O a) b) O Cl c) CH3CHO Cl H d) O 32. The correct IUPAC name of the following compound is O O a) Ethoxypropanone b) Ethyl propanoate c) Ethyl propyl ether d) Ethyl propyl anhydride 33.The major product for the following reaction is: CH2=CH-CH3 a) CH2-CH2-CH3 OH + KMnO4 cold, OH-, H2O b) CH3-CH2-CH3 c) 8 CH2-CH-CH3 OH OH d) CH2-CH2-CH2 OH OH 34. The alkyl bromide of the highest boiling point is: c) CH3Br b) CH3CH2Br a) CH3CH2CH2Br d) CH3CH2CH2CH2Br 35. Alkenes can be converted to epoxides using a) CH3COOH b) CH3COCH3 c) CH3CHO d) CH3COOOH 36. Which amine of the following is tertiary amine N N N H NH2 a) b) c) d) 37. The major product of this reaction is: CH3-CH2-CH3 + UV / heat Cl2 Cl CH3-CH-CH3 a) c) b) CH3-CH2-CH2-Cl CH2-CH2-CH2 Cl d) CH3-CH2-CHCl2 Cl 38. The following compound is considered as O OH CH3 a) Aldol product CH3 b) Enol c) Cyanohydrine d) Acetal 39. The structure of phthalic acid is COOH COOH COOH a) COOH COOH OH b) c) d) OCH3 9 40. The correct IUPAC name of the following compound is O H a) 3-Methyl-5-Hexenal b) 1-Heptenal c) 4-Methyl-5-hexenal d) 4-Methyl-5-hexyneal 41. The main products of the following reactions are: i. O NaOH / I2 a) CH3CH2COONa + CHI3 c) CH3CH2COOCOCH2CH3 + CHI3 b) CH3CH2COOH + CHI3 d) CH3CH2CHO + CHI3 O ii. 1) LiAlH4 Cl a) CH3COOH 2) H3O b) CH3CHO c) CH3CH2OH d) CH3OCH3 NO2 iii. KMnO4 / NO2 a) O b) c) NO2 d) O 10 COOH CN iv. Br2 / FeBr3 CN CN CN CN Br Br Br Br Br a) b) c) v. O d) i) LiAlH4 ii) H3O a) CH3CH2OH b) OHCH2CH2OH c) CH3COOH d) CH3OCH3 vi. CH3-CH2-CH-CH2-CH3 HBr Zn Br b) CH3-CH2-CH=CH-CH3 a) CH3-CH2-CH-CH2-CH3 Br Zn d) c) CH3-CH2-CH2-CH2-CH3 CH3-CH-CH-CH2-CH3 Br 11 O vii. P2O5 CH3 a) CH3CH2NH2 NH2 b) CH3NH2 c) CH3COOH d) CH3CN O viii . Br2 / NaOH NH2 a) CH3CN ix. b) CH3CH2NH2 O c) CH3NH2 d) CH3COOH O NH3 O a) CH3COOCH3 + CH3CH2CONH2 c) CH3CH2CHO + b) CH3CH2COOH + CH3CH2CONH2 CH3COOCH3 d) CH3CH2CHO + CH3CONH2 12 x. What is the major product of the following reaction? OH CH 3 H2SO4 / heat CH 3-CH 2-C-CH CH 3 CH 3 CH 3 H 3C C a) CH 3 CH 3 CH H b) C H CH 3 CH C C H 3C CH 3 CH 3 H c) CH C H H 3C CH 3 d) C CH 2CH 3 CH 3 C CH 2CH 3 ،،،وباهلل التوفيق Dr. Nahed Nasser EL Sayed / Dr. Noha Elnagdi 13 C CH 3 CH 3