Earth is a peculiar planet. -Water -Water at all the phases -Plate Tectonics -Life -Planets Near Earth -Inner Planets -Earth,Mars,Mercury (has little atmosphere) and Venus (has hyperactive atmosphere) -Does not have the same atmosphere as Earth -Earth Has "environmental fitness" -Life altered environment at global level -Earth's unique atmosphere shows it contains life. -Rise of Oxygen -Before 2.3 billion years ago, the Earth's atmosphere had low oxygen -There are rocks called pyrite made of iron, and when iron is oxidized, it begins to rust. -Photosynthesis began the rise of oxygen. -First things that would photosynthesize: stromatolites (3.4 billion years old) -CO2 and Water taken in by plant and added with sunlight, to create oxygen and sugar. -Took 2 billion years before oxygen was going into the atmosphere, but it first had to oxidize the unoxidized iron. -Early Organisms on Earth -Prokaryotes -Had a simple cell structure -Lacked organelles and nucleus -Took to much energy to maintain -Get their energy from fermentation -Low energy yield -Waste CO2 and alcohol -Live single, or had end-to-end chains -Cannot become 3-D structures -Eukaryotes -Uses oxygen for respiration -Had large cells with a nucleus and organelles. -Can form a 3-D colony of cells -Evolution of Biosphere -Began to evolve because of the complexity of the eukaryotes -Biosphere began to change -Plants and Animals began to evolve 700-500 million years ago -Changed the biogeochemical cycle on Earth -Life and Global Chemical Cells -Micronutrients -Elements needed in small amounts by all life, some forms of life need a moderate amount -Macronutrients -24 elements needed by all organisms -'Big Six': Building blocks of life -Carbon,oxygen,hydrogen,nitrogen,phosphorus and sulfur. -Each play a special role in an organism -For life to continue, elements need to be available in the right time, with the right amount. -Too much can be toxic -Too little can limit growth -Some elements are neutral for life -Biogeochemical Cycles -Complete path a chemical takes through 4 major components of Earth's system -Atmosphere, Hydrosphere, Lithosphere, Biosphere -General Aspects of Biogeochemical Cycles -Chemicals cycle quickly and are readily regenerated. -Have a gas phase and is carried by hydrolic cycle, soluble -Ex:/Oxygen and Nitrogen -Other elements are immoble and is returned by geological processes -Lack a gas phase and is insoluble -Ex:/ Phosphorus -Most required nutrient is light -Heaviest is iodine (atomic weight of 53) -Evolution of live changed the biogeochemical cycles -Modern tech transfers rate of elements in air, water and soil change -Can benefit the society but can also be a hazard -Simplest way to view a cycle: box and arrow diagram -Boxes: Places where chemical is stored -Source: Donating compartment -Sink: Receiving compartment -Residence Time: Amount of time atom spends in any compartment -Arrows: pathways of transfer -Flow: amount moving from one box to another -Flux: Rate/Speed -The Geologic Cycle -Rocks and soil is continually created, maintained, changed and destroyed the last 4.6 billion years -Changed due to physical, chemical and biological processes -Geologic Cycle- Group of Cycles -Tectonic -Hydrologic -Rock -Biogeochemical -Tectonic Cycle -Involves creation/destruction of lithosphere (outer layer of Earth) -About 100km thick and is broken in several plates -Slow movement of plates: Plate Tectonics -Move 2-15cm/year -Large Scale Effects -Location and Size of continent -Change in climate -Ecological Islands -Areas of volcanic activity/earthquakes -Types of Plate Boundaries -Divergent:Plates move away from each other -New lithosphere is produced -Convergent: Plates move into each other -Heavy ocean plates meeting lighter continental plates will cause a subduction zone -Two light plates creates a mountain -Transform: Plate slides past another -The Hydrologic Cycle -Transfer of water from oceans to the atmosphere to land and back to oceans -Driven by solar energy -Evaporation-Ocean -Precipitation-Land -Transportation-Water by plants -Evaporation-Land -Runoff from streams,rivers and subsurface groundwater -Total water on earth=1.3 billion cubic kilometers -97% Ocean -2% Glaciers and Ice caps -0.001% in atmosphere -Rest is on freshwater on land -Fundamental unit of the landscape is a drainage basin -Area that contributes surface runoff to particular stream or river -Vary greatly -Named for main stream or river -The Rock Cycle -Has numerous processes that produce rock and soil -Depends on the tectonic cycle for energy and hydrologic for water -Rocks: Igneous, Sedimentary, Metamorphic -Freezing and thawing produces the sediment such as gravel, sand and silt -Chemical weathering occurs when weak acids in water dissolve chemicals from rocks. -The Carbon Cycle -Carbon is element that anchors all organic substances -Has a gaseous phase -Enters atmosphere as CO2 and CH4 through respiration, fire and diffusion -Is removed from atmosphere by photosynthesis -Occurs in several forms in ocean -Dissolved CO2 carbonate and bicarbonate -Marine organisms produce CaCO3 -Carbon enters ocean by simple diffusion and then dissolve/transfer from land in rivers as dissolved carbon/Wind. -Carbon enters biota (life) through photosynthesis and returned by fire or respiration -Dead organism decomposes and released carbon -Buried under certain conditions: carbon not released -Turns into fossil fuels -The Carbon-Silicate Cycle -Cycling of carbon is intimately involved with cycling of silicon -Carbonic acid falls as rain and weathers silicate rich rocks -Transferred into oceans and is used by marine animals to make shells -Ca^2+(Calcium) and HCO3- (Bicarbonate) -Shells deposited on sea floor and become part of the sedimentary rock layer and returns to surface in subduction zones -Affects CO2 and O2 in atmosphere -The Nitrogen Cycle -Nitrogen is essential to life because it is need for protein and DNA -N2 makes up 78% of atmosphere -Most organisms can't use it directly -Unreactive element and must be converted to NO3-(Nitrate) and NH4+ (Immonia) -Performed by bacteria -Nitrogen fixation: process of converting atmospheric N to NO3- or NH4+ -Denitrification- process o releasing fixed N back to molecular N (Soil to atmosphere) -Almost all organisms depend on N converting bacteria -Formed symbiotic relationship in roots of plants/animal stomach -Without it, we can't use the nitrogen -Industrial processing can now convert molecular N into compounds that can be used by the plants -Main component of nitrogen fertilizers -Nitrogen in agricultural runoff is a potential source of water pollution -Nitrogen and Oxygen combine at high temps -Oxide of Nitrogen is a source of air pollution -Phosphorus Cycle -Often a limiting factor for plants and algal growth -No gaseous phase -Low transfer rate -Enters life through uptake by plants, algae and bacteria -Goes back to soil when the plants die/ lost to oceans by runoff -Returned to land by feeding birds (guano) -Guano deposits a major source of Phosphorus for the fertilizers