Work hard. Be nice. 100% EVERYDAY. Name: ____________________________________ General Chemistry Period: ________ UNIT 10: Solutions and Gases Date: ___________________ KIPP NYC College Prep Lecture 2: Table F Solubility Guidelines By the end of today, you will have an answer to: How do we determine if a substance is soluble? Do Now: Consider the dissolving of 100 g of LiCl in 5.00 L of water. 1. Which substance is the solute: _______________ solvent: _________________ 2. Determine the gram-formula mass of LiCl. 3. Determine the number of moles of LiCl in 100 g. 4. Determine the Molarity of the solution in 5.00 L. 5. Describe why increasing the temperature could increase the solubility of LiCl in water. Water is polar (has positive H and negative O). This allows it to dissolve some ionic compounds, like NaCl. However, some ionic compounds are insoluble. --How do you think the strength of the ionic bonds in these compounds compares to soluble ionic compounds? 1. Based on Figure 1 and the two solutions in front of you, which substance is soluble MgS or KI? Figure 1 What is the evidence? --What two ions make MgS? ______________________ --What two ions make KI? ________________________ --Which has stronger ionic bonds? _______________ 2. Based on Figure 2, describe what happens to the ions in an ionic compound that dissolve in water. Figure 2 --What two ions make KCl? ___________________ --How are the K+ and Cl- ions dissolved in water? Work hard. Be nice. 100% EVERYDAY. Review Key Terms: If a solid substance is soluble it dissolves in the solvent. If it is insoluble it forms a precipitate and does not dissolve. A precipitate is the solid in an undissolved mixture. Solid Added to Solvent Dissolves or does not dissolve? Formation of Precipitate? Soluble Insoluble Table F determines solubility of Ionic Compounds. So how do we use Table F? Listen and annotate Question: Is NH4Cl soluble in H2O? --Step 1: What are the two ions? ________________________ --Step 2: find ONE ion on ONE side of the Table! --Step 3: Determine if soluble or insoluble. --Step 4: Examine exceptions. Answer: ______________________________________ Example 2: Is AgCl soluble in H2O? Example 3: Is CaCO3 soluble in H2O? --Two ions: _______________________________ --Soluble or insoluble? _______________________ --Two ions: _______________________________ --Soluble or insoluble __________________________ In-class Practice: Directions: State whether the ionic compound will be soluble (precipitate does not form) or insoluble (precipitate forms) Ionic Compound LiF HNO3 NaOH Ca(OH)2 AgBr Fe3(PO4)2 Soluble (S)/ Insoluble (I) Ionic Compound PbCl2 H2SO4 AgI CaS (NH4)2S KClO4 Soluble (S)/ Insoluble (I) Work hard. Be nice. 100% EVERYDAY. Name: ____________________________________ General Chemistry WORK 10.2 Determining Solubility Using Table F Period: ________ Date: ___________________ KIPP NYC College Prep 10 points Important Information First: 1. Why are many ionic compounds soluble in water? Explains in-terms of charge. ____________________________________________________________________________________________________________________________ ____________________________________________________________________________________________________________________________ 2. Explain what happens to ions in an ionic compound that are soluble vs. those that are insoluble. ____________________________________________________________________________________________________________________________ ____________________________________________________________________________________________________________________________ Consider NaClO3. 3. What types of bond()s are found in this compound? _____________________________ and ________________________ 4. Using Table F, explain the process of determining how you know that NaClO3 is soluble in water. ____________________________________________________________________________________________________________________________ ____________________________________________________________________________________________________________________________ Consider AgCl. 5. What types of bond(s) are found in this compound? ___________________________________________________________ 6. Using Table F, explain the process of determining how you know that AgCl is insoluble in water. ____________________________________________________________________________________________________________________________ ____________________________________________________________________________________________________________________________ Regents Practice: 1. Which ion, when combined with chloride ions, Cl-, forms an insoluble substance in water? (1) Fe2+ (2) Mg2+ (3) Pb2+ (4) Zn2+ 2. According to Table F, which of these salts is least soluble in water? (1) LiCl (2) RbCl (3) FeCl2 (4) PbCl2 3. Which type of bonding is found in all molecular substances? (1) covalent bonding (2) hydrogen bonding (3) ionic bonding (4) metallic bonding 4. Which compound is insoluble in water? (1) BaSO4 (2) CaCrO4 (3) KClO3 (4) Na2S 5. Which substance contains bonds that involved the transfer of electrons from one atom to another? (1) CO2 (2) NH3 (3) KBr (4) Cl2 6. According to Reference Table F, which of these compounds is the least soluble in water? (1) K2CO3 (2) KC2H3O2 (3) Ca3(PO4)2 (4) Ca(NO3)2 Work hard. Be nice. 7. Based on Reference Table F, describe the solubility of magnesium hydroxide in water. 8. Based on Reference Table F, describe the solubility of zinc sulfide in water. 9. Identify one ion from Table F that can combine with Pb2+(aq) to produce an insoluble compound. The dissolving of solid lithium bromide in water is represented by the balanced equation below. 10. Based on Table F, identify one ion that reacts with Br− ions in an aqueous solution to form an insoluble compound. 11. You’re walk along the beach and stop to reach down and grasp a handful of warm sand and water. Your friend reaches down and does the same but instead continues to bring the handful of water to their mouth– but you stop him/her. They argue that it is fresh water and perfect for drinking on a hot day, but you know better. Explain why the clear water is still not pure water. Use the terms soluble/ insoluble and mixture/pure substance.