William Patterson and Josh Parker Period 4 Chemistry H Mid-year Review: Organic Chemistry Key Terms: Alkanes: single covalent bonds, contain maximum number of Hydrogen atoms that can bond with Carbon atoms (saturated), CnH2n+2 Alkenes: unsaturated, contain at least one double or triple bond, CnH2n Alkynes: unsaturated, one triple bond, CnH2n-2 Isomer: same formula with a different arrangement Alkyl: a group that breaks off of the main chain Alcohols: General formula- R-OH Ether: R-O-R’ Aldehyde: Look for the CHO Ketone: R-CO-R’ Carboxylic Acid: Look for the COOH Ester: Look for the COO Amine: R3N Cycloalkanes: alkanes whose carbon atoms are joined in rings (CnH2n) Concepts: Naming Compounds 1. Look for the longest carbon chain 2. Match the number of carbons with a prefix, and name the ending by identifying the types of bonds 3. Name the substituents by starting at the lowest carbon (remember there cannot be one off of the first or last carbon) 4. Give the number for where the substituents break off of, and clarify where there are double or triple bonds 5. Numbers are to be separated by commas, and use a dash to separate a number and a word. Do not leave spaces! Number of Carbons Prefix 1 Meth- 2 Eth- 3 Prop- 4 But- 5 Pent6 Hex- 7 Hept- 8 Oct- 9 Non- 10 Dec- Functional Groups Identify if the chain has an alcohol, ether aldehyde, ketone, carboxylic acid, ester, or an amine, and proceed according to the directions. Worksheet on Organic Chemistry Basic Hydrocarbon Questions 1. What carbon chain is completely saturated by hydrogen atoms and only has single bonds between the carbon atoms? 2. What is the formula for this hydrocarbon chain? 3. What hydrocarbon chain has one or more double bonds between the carbon atoms? 4. What is the formula for this hydrocarbon chain? 5. What hydrocarbon chain has one or more triple bonds between the carbon atoms? 6. What is the formula for this hydrocarbon chain? Identifying the following compounds as alkane, alkene or alkyne 1. C124H246 : 2. C233H466 : 3. C4H10 : 4. C27H52 : 5. C37H76 : 6. C72H144 : 7. C17H34 : 8. C20H38 : 9. C15H32 : 10. C133H268 : Identify molecular formula for following 1. Nonene : 2. Decyne : 3. Pentane : 4. Hexyne : 5. Ethene : 6. Butyne : 7. Heptene : 8. Octane : 9. Propene : 10. Heptane : Draw and name isomers for Hexane Name the functional group in the following 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. Naming Alkanes 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. Answer Key to Worksheet Basic Hydrocarbon Questions 1. What carbon chain is completely saturated by hydrogen atoms and only has single bonds between the carbon atoms? An Alkane 2. What is the formula for this hydrocarbon chain? CnH2n+2 3. What hydrocarbon chain has one or more double bonds between the carbon atoms? An Alkene 4. What is the formula for this hydrocarbon chain? CnH2n 5. What hydrocarbon chain has one or more triple bonds between the carbon atoms? An Alkyne 6. What is the formula for this hydrocarbon chain? CnH2n-2 Identifying the following compounds as alkane, alkene or alkyne 1. C124H246 : alkyne 2. C233H466 : alkene 3. C4H10 : alkane 4. C27H52 : alkyne 5. C37H76 : alkane 6. C72H144 : alkene 7. C17H34 : alkene 8. C20H38 : alkyne 9. C15H32 : alkane 10. C133H268 : alkane Identify molecular formula for following 1. Nonene : C9H18 2. Decyne : C10H18 3. Pentane : C5H12 4. Hexyne : C6H10 5. Ethene : C2H4 6. Butyne : C4H6 7. Heptene : C7H14 8. Octane : C8H18 9. Propene : C3H6 10. Heptane : C7H16 Draw and name isomers for Hexane Name the functional group in the following 1. aldehyde 2. ether 3. amine 4. ester 5. alcohol 6. aldehyde 7. ketone 8. ester 9. carboxylic acid 10. ketone Naming Alkanes 1. 2-methylpentane 2. 2,3-dimethylbutane 3. pentane 4. 2,2-methylbutane 5. 2,2-methylpentane 6. 2,4-dimethylheptane 7. 2,2,3-trimethylbutane 8. 4,4-diethyl-2,3-dimethylheptane 9. ethylpentane 10. 2,3,4-trimethylhexane