Mg 2+

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Mg 2+

Supplementary Material for Perkin Transactions 2
This journal is © The Royal Society of Chemistry 2002
Supplementary Data
(a)
(b)
2+
Fig. S1. Spin density distribution of (a) 1• and (b) Mg –1• calculated by using
the ADF method.
4
3
–1
–1
s
–3
k
HT
/
M
10
2
1
0
0
0.1
0.2
0.3
0.4
0.5
[Mg2+ ] / M
2+
Fig. S2. Dependence of kHT on [Mg ] for hydrogen transfer from 1H to DPPH•
(white circles) and G• (black circles) in the presence of Mg(ClO4)2 in deaerated MeCN
at 298 K.
2

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