Lhoist North America May 1, 2014 LNA Experience DSI and Ceramic Filter Technology using Sorbacal® Lhoist North America sounds like ‘Luh-wost’ Chemical Lime and Franklin Industrial Minerals merged to form Lhoist North America Suppliers of high quality chemical grade calcium products including Limestone, Quicklime, Slurry, and Hydrate (Sorbacal®) Lhoist Group – Worldwide World’s largest lime company Lhoist has been in business for more than 120 years 88 plants in 25 countries in Asia, Europe and the Americas Ste Genevieve, MO Plant 2 DSI Effectiveness Factors Reagent Properties – physical and chemical Reagent reactivity Reagent surface area Reagent porosity Flue Gas Properties Temperature Flue gas moisture Other competing acid gases Injection System Configuration Particulate control device In flight residence time Reagent mixing Injection location 3 Calcium based Additives for DSI Reaction of Ca(OH)2 with acidic gas components: Acid – Base reaction through Gas – Solid contact Surface area and pore volume very important 4 DSI Sorbacal® Applications HCl Power Plants Coal Fired boilers Biomass boilers SO3 SO2 HF Waste Incineration Municipal Waste Hospital Waste SO2 HF HCl Industrial Waste Sludge HF Industrial Processes Cement Industry Glass Industry SO3 SO2 HCl Se Brick Industry … 5 DSI in Ceramic Filters Source: www.tri-mer.com 6 Temperature Considerations Example Curve of Standard Hydrate Performance Source: Carmeuse NA Sorbacal® SPS performance greatly improves the SO2 removal in this temperature zone Source: www.tri-mer.com 7 Test with Tri-Mer Ceramic Filter and Sorbacal Optimized Hydrated Lime Products 8 Test with Tri-Mer Ceramic Filter and Sorbacal Optimized Hydrated Lime Products Test with Tri-Mer Ceramic Filter and Sorbacal Optimized Hydrated Lime Products 9 Test with Tri-Mer Ceramic Filter and Sorbacal Optimized Hydrated Lime Products 10 Test with Tri-Mer Ceramic Filter and Sorbacal Optimized Hydrated Lime Products 11 Test with Tri-Mer Ceramic Filter and Sorbacal Optimized Hydrated Lime Products 12 Test with Tri-Mer Ceramic Filter and Sorbacal Optimized Hydrated Lime Products Sorbacal® SP Performance 13 US Industry Examples Utilizing DSI with Ceramic Filters Dry Sorbent Injection using: 14 Thank You! Questions? Contact: Howard Fitzgerald Lhoist North America 3700 Hulen Street Fort Worth, Texas 76107 howard.fitzgerald@lhoist.com 817-995-3011 www.lhoist.us www.sorbacal.us 15