1. Steam enters the condenser of a steam power plant at 20 kPa and a quality of 95 percent with a mass flow of 20000 kg/h. It is to be cooled by water from a nearby river by circulating the water through the tubes within the condenser. To prevent thermal pollution, the river water is not allowed to experience a temperature rise above 10oC. If the steam is to leave the condenser as saturated liquid at 20 kPa, determine the mass flow rate of the cooling water required. 3 2 1 4 Solution: Steam is condensed by cooling water in the condenser of a power plant. If the temperature rise of the cooling water does not exceed 10oC, determine the minimum mass flow rate of the cooling water. Assumptions: 1). This is a steady flow process since there is no change in properties with time. 2). Kinetic and potential energy changes are negligible. 3). There are no work interactions. 4). Heat loss from the device to the surroundings is negligible and thus heat transfer from the hot fluid is equal to the heat transfer to the cold fluid. 5). Liquid water is an incompressible substance with constant specific heats at room temperature. Properties: The cooling water exists as compressed liquid at both states, and its specific heat at room temperature is c = 4.18 kJ/kgK (Table A 4). The enthalpies of the steam at the inlet and the exit states are: π3 = 20 πππ π₯3 = 0.95 therefore β3 = βπ + π₯βππ = 251.38 + 0.95(2358.33) = 2491.8 ππ½/ππ π4 = 20 πππ saturated liquid from here β4 = βπ@20 πππ = 251.38 ππ½/ππ We take the heat exchanger as the system, which is a control volume. The mass and energy balance for this steady flow system can be expressed in the rate form as: Mass balance (for each fluid steam): πΜπ − πΜπ = βπΜπΆπ steady state, so πΜπ = πΜπ πΜ1 = πΜ2 = πΜπ€ππ‘ππ πΜ3 = πΜ4 = πΜπ π‘πππ Energy balance under stated assumptions becomes: πΜ1 β1 + πΜ3 β3 = πΜ2 β2 + πΜ4 β4 Combining the two: πΜπ€ππ‘ππ (β1 − β2 ) = πΜπ π‘πππ (β3 − β4 ) Solving for πΜπ€ππ‘ππ : πΜπ€ππ‘ππ = = β3 − β4 β3 − β4 πΜπ π‘πππ = πΜ β2 − β1 πΆπ (π2 − π1 ) π π‘πππ (2491.7 − 251.38) (20000/3600 ππ/π ) = 297 ππ/π ππ½ (10β) (4.18 ) ππβ 2. In a steady state process, the high-pressure water at 20 MPa and 300°C with flow rate 1 m3/min is throttled into an 1000 lit/min evaporator chamber which forms liquid and vapor at a lower pressure as shown in the figure. Saturated vapor having quality x =1 comes out of outlet A, while saturated water (x=0) having specific volume 0.00103 m3/kg comes out of the outlet B. Calculate: a). the mass flow rate (kg/s) of incoming stream. mediate equilibrium (state 2). Subsequently, the nly. Estimate the net heat transferred to air while to state 3 via state 2. ved simultaneously and suddenly, estimate heat g the system directly from state 1 to state 3. be 10 m/s2] (12 Points) b). Estimate, temperature, pressure, and mass flow rate (kg/s) of saturated water stream me of superheated water vapor at 10 MPa and of outlet B. steam tables (2 Points), quation (2 Points), (ii) the ssibility chart (4 Points). ss, the high Compr essed water d 300°C with 20 MPa and 300°C 1000 lit/min tled into an ms liquid and Outl et A shown in the satur ated steam, x=1 quality x =1 ile saturated Evaporator ecific volume Outl et B the outlet B. satur ated water te (kg/s) of v=1.03×10–3m3/kg Estimate, ass flow rate (kg/s) of saturated water stream of Solution: Outlet B (saturated water x = 0): Page 1 of 2 π£π΅ = 0.00103 π3 (πππ£ππ) ππ look for this volume at table TB1.1 and interpolate to find TB and PB. TB = 81.6oC and PB = 50.87 kPa To find hB therefore you look at TB1.2 at PB = 50.87 kPa and T ≈ 81.33β βπ΅ = 340.47 ππ½/ππ Outlet A (saturated vapor x = 1): Use T B1.2 at 50 kPa: βππ΄ = 2645.87 ππ½/ππ π£ππ΄ = 3.24034 π3 /ππ Mass balance equation: πΜ1 = πΜπ΄ + πΜπ΅ πΜπ΄ + πΜπ΅ = 12.5 ππ/π πΜ1 = πΜ 0.017π3 /π = = 12.5 ππ/π π£1 0.00136 π3 /ππ 0.00136 π3 π£1 = (πππππ π΅. 1.4 ππ‘ 20000 πππ πππ 300β) ππ Energy balance: πΜ1 β1 = πΜπ΄ βπ΄ + πΜπ΅ βπ΅ 12.5 π₯ 1333.29 = πΜπ΄ π₯2645.87 + πΜπ΅ π₯ 340.47 12.5π₯ 1333.29 = 2645.87(12.5 − πΜπ΅ ) + πΜπ΅ π₯ 340.47 πΜπ΅ = 7.1168 ππ/π 3. A well-insulated piston–cylinder assembly is connected by a valve to an air supply line at 8 bar (1 bar=100 kPa), as shown in the figure. Initially (state 1), the air inside the cylinder is at 1 bar, 300 K, and the piston is located 0.5 m above the bottom of the cylinder. The atmospheric pressure is 1 bar, and the diameter of the piston face is 0.3 m. The valve is opened and air is admitted slowly until the volume of air inside the cylinder has doubled (state 2). The weight of the piston and the friction between the piston and the cylinder wall can be ignored. Using the ideal gas model, obtain a relationship between final temperature (T2) and temperature of air supply line (Ts). Estimate the final temperature, in K, and mass, in kg, of the air inside the cylinder for supply temperatures: of Ts =500 K. ents of the second law of thermodynamics by Kelvin – 4 Points) ed piston–cylinder by a valve to an air (1 bar=100 kPa), as re. Initially (state 1), er is at 1 bar, 300 K, ted 0.5 m above the r. The atmospheric the diameter of the e valve is opened and ntil the volume of air doubled (state 2). The d the friction between ylinder wall can be l gas model, obtain a nal temperature (T2 ) supply line (Ts). Estimate the final temperature, in K, and nside the cylinder for supply temperatures: of Ts =500 K. Solution: static (quasiequilibrium) process, and (II) A reversible Supply line state: compressor is to be upled adiabatic steam ving a generator. Steam 2.5 MPa and 500°C at a xits at 10 kPa and a rs the compressor at 98 of 10 kg/s and exits at termine the net power enerator by the turbine. (12 Points) is rotated in a rigid and insulated closed vessel with ππ = 800 πππ Cylinder: Initially (state 1): π1 = 100 πππ; π1 = 300 πΎ Final state (state 2): π2 = 100 πππ; π2 =? Mass balance equation: ππ = π2 − π1 Energy equation: π2 π’2 − π1 π’1 = −π1−2 + (π2 − π1 )βπ βπ = βπ βπ = 2π1 − π1 = π1 = π (0.15)2 π₯0.5 = 0.03534 π3 π1 = π΄β1 = 0.03534 π3 π2 = 2π΄β1 = 0.07068 π3 Work term: π = πβπ = 100 πππ (0.03534 π3 ) = 3.534 ππ½ Enthalpy: βπ = ππ ππ Cp air = 1.004 kJ/kg.K Initial mass: π1 = π1 π1 100π₯ 0.03534 π3 = = 0.04105 ππ π π1 0.287 π₯ 300 π2 = π2 π2 100π₯ 0.07068 π3 24.627 = = π π2 0.287 π₯ π2 π2 Internal energy term: π’2 = ππ£ π2 = 0.717π2 Substitute in the main energy equation: 24.627 24.627 π₯ 0.717π2 − 215.4 π₯ 0.04105 = ( − 0.04105 ) π₯1.004ππ − 3.534 π2 π2 for Tline = 500K 12.312 24.627 = − 0.04105 ππ π2 π2 = 375πΎ π2 = 0.065ππ 4. A tank having a volume of 0.85 m3 initially contains water as a two-phase liquid-vapor mixture at 260oC and a quality of 0.7. Saturated water vapor at 260oC is slowly withdrawn through a pressure-regulating valve at the top of the tank as energy is transferred by heat to maintain the pressure constant in the tank. This continues until the tank is filled with saturated vapor at 260oC. Determine the amount of heat transfer, in kJ. Solution: 1. For the CV, ππΆπ = 0 and kinetic and potential energy effects can be neglected. 2. At the exit, the state remains constant. 3. The initial and final states of the mass within the vessel are equilibrium states. Since there is a singe exit and no inlet, the mass rate balance takes form: πππΆπ = −ππ ππ‘ With assumption 1, the energy rate balance: ππΈπΆπ π12 π12 = ππΆπ − ππΆπ + ∑ ππ (βπ + + ππ§π ) − ∑ ππ (βπ + + ππ§π ) ππ‘ 2 2 π reduces to: π πππΆπ = ππΆπ − ππ βπ ππ‘ Combining the mass and energy rate balances results in: πππΆπ πππΆπ = ππΆπ + βπ ππ‘ ππ‘ By assumption 2, the specific enthalpy at the exit is constant. Accordingly, integration of the last equation gives: βππΆπ = ππΆπ + βπ βππΆπ Solving for the heat transfer ππΆπ : ππΆπ =βππΆπ − βπ βππΆπ ππΆπ = (π2 π’2 − π1 π’1 ) − βπ (π2 − π1 ) where m1 and m2 denote, respectively, the initial and final amounts of mass within the tank. The terms u1 and m1 of the above equation can be evaluated with property values from Table at 260oC and the given value for quality. Thus: π’1 = π’π + π₯1 (π’π − π’π ) = 1128.4 + (0.7)(2599.0 − 1128.4) = 2157.8 ππΏ/ππ Table B1.1 π£1 = π£π + π₯1 (π£π − π£π ) = 1.2755 π₯ 10−3 + 0.7(0.04221 − 1.2755π₯10−3 ) = 29.93π₯10−3 π3 /ππ Using the specific volume v1 the mass initially contained in the tank is: π1 = π 0.85 π3 = = 28.4 ππ π£1 29.93π₯10−3 π3 /ππ The final state of the mass in the tank is saturated vapor at 260C so from the table: π’2 = π’π (260β) = 2599.0 ππ½/ππ π£2 = π£π (260β) = 42.21π₯10−3 π3 /ππ, Table B1.1 The mass contained within the tank at the end of the process is: π 0.85 π3 π2 = = = 20.14 ππ π£2 42.21π₯10−3 π3 /ππ Table also gives: βπ = βπ (260β) = 2796.89 ππ½/ππ Substituting values into the expression for the heat transfer yields: ππΆπ = (π2 π’2 − π1 π’1 ) − βπ (π2 − π1 ) ππΆπ = 20.14π₯2599.0 − 28.4π₯2157.8 − 2796.6(20.14 − 28.4) = 14162 ππ½ In this case, idealizations are made about the state of the vapor exiting and the initial and final states of the mass contained within the tank. 5. A vessel has a volume of 1.45 m3. Initially, 80% of its volume is filled with saturated liquid ammonia at -25oC and the rest is filled with ammonia vapor. Liquid leaves through a small valve while heat is added to maintain the temperature at -25oC. The final mass of liquid in the vessel is one-third of the initial mass of liquid. Determine the amount of heat that must be added. ππ»3 , π‘ππππ ππππ‘ πππππππ (ππππ π‘ πππ€ πππππ¦π ππ ) Both states (1 and 2) are saturated at T = -25oC. NH3 Q State 1: ππ1 = ππ1 = 0.2π 0.2(1.45) = = 0.376 ππ π£π 0.7712 0.8π 0.8(1.45) = = 778.52 ππ π£π 0.001490 π1 = ππ1 + ππ1 State 2: ππ2 = ππ1 778.52 = = 259.5 ππ 3 3 ππ2 = ππ2 π£π = (259.5)(0.001490) = 0.387 π3 ππ2 = π − ππ2 = 1.45 − 0.387 = 1.063π3 ππ2 = ππ2 1.063 = = 1.379 ππ π£π 0.7712 π2 = ππ2 + ππ2 ππ1 π’π + ππ1 π’π + 1Q2 = ππ2 π’π + ππ2 π’π − (π1 − π2 )βπ 1Q2 = (ππ2 − ππ1 )π’π − (ππ2 − ππ1 )π’π + (π1 − π2 )βπ = 1350 kJ 6. Acetylene initially at 95 kPa, 40oC is held in an insulated tank having a volume of 0.30m3. Heat is added to the system at a constant rate of 100W. Acetylene is bled from the tank to hold the pressure constant. Assuming, that conditions are uniform, determined the time required for the acetylene to reach a temperature of 120 oC. Solution: Assumptions: 1). Assume an ideal gas 2). Neglect KE and PE effects 3). π1−2 = 0 π2 π’2 − π1 π’1 = π1−2 − π1−2 + ππ βπ − ππ βπ (π2 − π1 ) = ππ = 0.058 ππ Table A5: πΆπ£ = 1.38 ππ½/πππΎ πΆπ = 1.699 ππ½/πππΎ π’2 = πΆπ£ π2 = (1.38)(120β + 273.15) = 542.55 ππ½/ππ π’1 = πΆπ£ π1 = (1.38)(40β + 273.15) = 432.15 ππ½/ππ π1 = π1 π1 (95πππ)(0.3) = = 0.285 ππ π π1 (0.3193)(313.15) π2 = π2 π2 (95πππ)(0.3) = = 0.227 ππ π π2 (0.3193)(393.15) (π2 − π1 ) = ππ = 0.058 ππ βπ = β1 + β2 2 β1 = πΆπ π1 = (1.699)(313.15) = 532.04 ππ½/ππ β2 = πΆπ π2 = (1.699)(393.15) = 667.96 ππ½/ππ ππ½ βπ = 600 ππ π1−2 = π2 π’2 − π1 π’1 + ππ βπ = = (0.227)(542.55) − (0.285)(432.15) + (0.058)(600) = 34.796 ππ½ βπ‘ = π1−2 (34.796)π₯103 π½ = = 347.96 π ππ 100 π½/π πΜ 7. A rigid container has two rooms filled with water, each 1 m3 separated by a wall (see fig). Room A has P = 200 kPa with a quality x = 0.80. Room B has P = 2 MPa and T = 400°C. The partition wall is removed and the water comes to a uniform state, which after a while due to heat transfer has a temperature of 200°C. Find the final pressure and the heat transfer in the process. 8. A water cooler for drinking water should cool 25 L/h water from 18oC to 10oC using a small refrigeration unit with a COP of 2.5. Find the rate of cooling required and the power input to the unit. 9. A cyclic machine, receives 325 kJ from a 1000 K energy reservoir. It rejects 125 kJ to a 400 K energy reservoir and the cycle produces 200 kJ of work as output. Is this cycle reversible, irreversible, or impossible? 10. A household freezer operates in a room at 20°C. Heat must be transferred from the cold space at a rate of 2 kW to maintain its temperature at −30°C. What is the theoretically smallest (power) motor required to operate this freezer? 11. As shown below, a Carnot refrigeration cycle is performed in a closed system in the region of saturated liquid–vapor mixture with 0.6 kg of R-134a. The maximum and minimum temperatures of the cycle are shown in the figure. At the end of the heat rejection process, the refrigerant is saturated liquid and the input network to the cycle is 12 kJ. Determine: a) the fraction of the mass of the refrigerant that vaporizes during the heat addition process b) the pressure at the end of the heat rejection process s Knowing the high and low temperatures, the coefficient of performance of the cycle is: πΆπππ = 1 1 = = 9.464 ππ» /ππΏ − 1 (20 + 273πΎ)/(−8 + 273 πΎ) − 1 The amount of cooling is determined from the definition of the coefficient of performance to be: ππΏ = πΆπππ × πππ = 9.464 × 12 = 113.5 ππ½ The enthalpy of vaporization R-134a at -8β is βππ = 204.59 kJ/kg (Table B.5.1). Then the amount of refrigerant that vaporizes during heat absorption becomes: ππΏ = πππ£ππ βππ@−8β → πππ£ππ = 113.5 ππ½ = 0.554 ππ 204.59 kJ/kg Therefore, the fraction of mass that vaporized during heat addition process to the refrigerant is: πππ£ππ 0.554 πππ π πππππ‘πππ = = = 0.93 ππ 93% ππ‘ππ‘ππ 0.6 The pressure at the end of heat rejection process is simply the saturation pressure at heat rejection temperature: π4 = ππ ππ‘@20β = 572.8 πππ 12. A Carnot heat engine gets heat from a reservoir at 900 β and with rate of 800 kJ/min. It rejects the waste heat to the ambient air at 27 β. The whole work output of the heat engine is used for a refrigerator that removes heat from the refrigerated space at -5β and transfer that to the same ambient air at 27β. Determine: a) the maximum rate of heat removal from the refrigerated space b) the total rate of heat rejection to the ambient air a) The highest thermal efficiency a heat engine operating between two specified temperature limits can have is the Carnot efficiency, which is determined from: Θ π‘β,πππ₯ = Θ π‘β,πΆ = 1 − ππΏ 300 πΎ =1− = 0.744 ππ» 1173 πΎ Then the maximum power output of this heat engine is determined from the definition of thermal efficiency to be: πΜπππ‘,ππ’π‘ = Θ π‘β πΜπ» = 0.744 ∗ 800 = 595.2 ππ½/πππ which is also the power input to the refrigerator: The rate of heat removal from the refrigerated space will be a maximum if a Carnot refrigerator is used. The COP of the Carnot refrigerator is: πΆπππ ,πππ£ = 1 1 = = 8.37 ππ» /ππΏ − 1 (27 + 273)/(−5 + 273) − 1 Then the rate of heat removal from the refrigerated space becomes: πΜπΏ,π = πΆπππ ,πππ£ (πΜπππ‘,ππ ) = 8.37 ∗ 595.2 = 4982 ππ½/πππ b) πΜπΏ,π»πΈ = πΜπ»,π»πΈ − πΜπππ‘,ππ’π‘ = 800 − 595.2 = 204.8 ππ½/πππ πΜπ»,π = πΜπΏ,π + πΜπππ‘,ππ = 4982 + 595.2 = 5577.2 ππ½/πππ And πΜπππππππ‘ = πΜπΏ,π»πΈ + πΜπ»,π = 204.8 + 5577.2 = 5782 ππ½/πππ 13. A room which is 4m*5m*8m is being heated using an electric resistance heater that is located in a short duct inside the room. At first, the room temperature is 15β and the local atmosphere pressure is 98 kPa. The room steadily loses heat to the outside with the rate of 150 kJ/min. There is a 200W fan that circulates the air through the duct and the heater at the average mass flow rate of 40 kg/min. The duct is adiabatic. There is no air leakage in or out the room. To reach the average temperature of 25β of the room air, it takes 20 minutes. Determine: the power rating of the electric heater The total mass of air in the room is: π = 4 ∗ 5 ∗ 8 = 160 π3 π= π1 π 98 πππ ∗ 160 π3 = = 189.7 ππ π π1 (0.287 πππ. π3 /ππ. πΎ)(288 πΎ) We first take the entire room as our system, which is a closed system since no mass leaks in or out. The power rating of the electric heater is determined by applying the conservation of energy relation to this constant volume closed system: πΈππ − πΈππ’π‘ = βπΈπ π¦π π‘ππ ππ,ππ + ππππ,ππ − πππ’π‘ = βπ βπ‘(πΜπ,ππ + πΜπππ,ππ − πΜππ’π‘ ) = πππ£,ππ£π (π2 − π1 ) Solving for the electrical work input gives: πΜπ,ππ = πΜππ’π‘ − πΜπππ,ππ + πππ£,ππ£π (π2 − π1 )/βπ‘ = 150 ππ½ ππ½ 1 ( ππ½/π ) − (0.2 ) + (189.7 ππ) (0.718 . β) (25 − 15)β = 3.435 ππ 60 π ππ 20 ∗ 60 14. A piston/cylinder contains 50 kg of water at 200 kPa with a volume of 0.1 m3 . Stops in the cylinder are placed to restrict the enclosed volume to a maximum of 0.5 m3 . The water is now heated until the piston reaches the stops. Find the necessary heat transfer. 15. A piston/cylinder contains air at 1380 K, 15 MPa, with V1 = 10 cm3, Acyl= 5 cm2. The piston is released, and just before the piston exits the end of the cylinder the pressure inside is 200 kPa. If the cylinder is insulated, what is its length? How much work is done by the air inside? 16. A closed tank, V = 10 L, containing 5 kg of water initially at 25°C, is heated to 175°C by a heat pump that is receiving heat from the surroundings at 25°C. Assume that this process is reversible. Find the heat transfer to the water and the change in entropy. 17. A mass of 1 kg of air contained in a cylinder at 1.5 MPa, 1000 K, expands in a reversible isothermal process to a volume 10 times larger. Calculate the heat transfer during the process and the change of entropy of the air. 18. A spring loaded piston cylinder contains 1.5 kg air at 27oC and 160 kPa. It is now heated in a process where pressure is linear in volume, P = A + BV, to twice the initial volume where it reaches 900 K. Find the work, the heat transfer and the total entropy generation assuming a source at 900 K.