Imperial College of Science, Technology and Medicine Royal School of Mines T H Huxley School of Environment, Earth Science & Eng Field work at Northern Italian Landfill Sameh Ahmed 1 Samples at one Penetration point 2 3 4 5 Container for saving the samples At the end, instrument cleaning and protection 6 Purging and Samples from water well 7 8 9 Multivariate Results Na Cl Br EC HCO3 Ca Mg Li K NH4 F NO2 Temp S pH Factor 1 Factor 2 Factor 3 Factor 1 Factor 2 Factor 3 Factor 1 Factor 2 Factor 3 0.9059 0.1757 -0.2667 0.9293 0.5681 -0.2961 0.5074 0.0171 0.0537 0.8870 0.2713 -0.2745 0.7929 0.2960 -0.2674 0.6853 -0.1931 0.0118 0.8843 0.3099 -0.2858 0.9041 0.7648 -0.4555 0.5238 0.2993 -0.0404 0.8814 0.3315 -0.2084 0.9626 0.7088 -0.4125 0.5365 0.1639 -0.0307 0.7809 0.4224 -0.0968 0.9615 0.7109 -0.3942 0.5052 0.1505 0.0061 0.6365 0.6507 -0.2408 0.5157 0.7424 -0.2994 0.0901 0.5310 0.0358 0.5595 0.7077 -0.2644 0.7075 0.9427 -0.4267 0.7075 0.9427 -0.4267 0.4807 0.7319 -0.1123 0.3218 0.1415 -0.0703 0.0946 -0.0610 -0.0992 0.3633 0.6751 -0.1556 0.7513 0.8836 -0.2907 0.2120 0.5235 0.1197 0.0419 0.8381 -0.1636 0.2806 0.8468 -0.4201 -0.1843 0.7964 -0.0827 -0.1039 -0.0470 0.0945 -0.1797 -0.1391 0.0824 -0.2122 0.0097 0.0503 -0.1496 -0.1689 0.5107 -0.3659 -0.2996 0.8191 0.0228 0.0666 0.6569 -0.2182 -0.1008 0.4249 -0.3921 -0.2956 0.3956 -0.0994 -0.0423 0.0736 -0.3316 -0.3036 0.2345 -0.4499 -0.5171 0.7497 -0.0127 -0.1367 0.6186 -0.4257 -0.1958 0.6925 -0.5646 -0.4686 0.4520 -0.0790 -0.0300 0.1628 10 Factor 1 Factor 2 Factor 3 Na NH4 pH Cl Li NO2 Br Mg Temp EC Ca HCO3 11 Interpretation • There is quite good link between the salt (Na, Cl, Br) and the carbonates in solution (HCO3) which agrees with the conductivity that is controlled by the same factor. The cations are grouped together in the second factor. • The good relationship (correlation) between these two factors most probably has to do with the fact that positive and negative ions have to be in equilibrium in the solution. 12