Class TAKS Review Objective 4 Matter and Change Matter • Anything that has mass and takes up space. • Energy is NOT matter Matter is divided into 3 types: • Elements • Compounds • Mixtures The 3 types can be further separated in two categories: • Mixtures are not pure Compounds which • Pure Substances are substances formed when two or more elements and we will • Elements are the share electrons or deal with them simplest pure become ions that tomorrow. substances attract other elements. Elements:SIMPLEST KIND OF MATTER Cannot be broken down into simpler substances. – All atoms of an element have the same number of protons. – There are 109 of these currently listed and named on the Periodic Table 4 Basic Types ofElements • Metals: found on the left and center of the Table of Elements • Non-metals: found on the right side of the Table of Elements • Metalloids: found along the stair-step line • Synthetic: made in the laboratory and not yet found in nature – many of the Actinide and Lanthanide series and very large # elements. The BOHR Model of an Atom • This is the first model to have a nucleus with protons and neutrons. • The electrons are in various energy levels and circle the nucleus. • Model most people draw today. Drawing a Bohr Model of Lithium • Center (blue) circle is the nucleus. • It should contain: 3+ and 4N to represent the 3 protons and 4 neutrons. • The orange circle gets 2e-, and the purple gets 1e-. Atoms are. . . • The smallest part of a single element. • The basis of all matter. • Made of mostly empty space. • Have a positive core or nucleus. • Have electrons in orbit in clouds. 23 According to the periodic table, which element most readily accepts electrons? • A Fluorine •Fluorine B Nitrogen only needs 1 • This is a nonmetal, so it electron complete itsit will acceptstoelectrons but alsoofshare in NO31shell 8, sothem it willasaccept it. •from C Arsenic any other element • This is a metalloid, so it only very very very easily.electrons. This sometimes accepts periodic property increases • D Aluminum as youismove upsoand left in • This a metal it donates theelectrons. table, except for the Noble Gases. What about MOLECULES? These are MULTI-ATOM particles Properties of Elements Metals • Metals are: –Conductors –Lustrous –Electron donors –Malleable –Ductile Where are the metal elements? Left of the Stair-step line! Properties of Nonmetals • Nonmetals are brittle, insulators, electron acceptors • Usually form negative ions (except H) • Many are gases at room temperature • Found to the right of the stair-step line Diatomic Elements – Nonmetals that come as molecules • 7 Elements are di- (2) atomic (atoms) • The easy way to remember them is by the name •Br I N Cl H O F 3 Which of the following groups contains members with similar chemical reactivity? A Li, Be, C B Be, Mg, Sr C Sc, Y, Zr D C, N, O Lets look at the Table provided. • To have similar chemical properties of any kind, they must be in the same Group or Family. • Groups are columns, so the answer would be •B Types of matter • Compounds • Pure substances that can be broken down by a chemical change. • Molecules are the smallest particle of a compound that retains its properties and it is composed of 2 or more atoms. Compounds: Pure substances that can be broken down by chemical methods When they are broken down, the pieces have completely different properties than the compound. Made of moleculestwo or more atoms Names of Compounds – Ionic • Ionic compounds consist of cations (positive ions) and anions (negative ions). • A Roman numeral in parentheses, preceded by the name of the element, is used for elements that can form more than one positive ion. This is usually seen with metals. • Fe2+ Iron (II) Cu+ Copper (I) Fe3+ Iron (III) Cu2+ Copper (II) Ionic compounds – naming cont. • The -ide ending is added to the name of a single element when it becomes an ion of that element. Oxide, Nitride, Sulfide etc. Some polyatomic anions have a names ending in -ite for the lower # of oxygens and –ate for more oxygens. NO2 nitrite NO3 nitrate Covalent Compounds – Names are the Formulas • These are nonmetal to nonmetal compounds. • The name tells you the formula. Carbon dioxide 1 C and 2 O CO2 Special Names of Compounds Acids and Bases • Bases end in the • Acids that are two elements are named hydroxide anion Hydro-nonmetal –ic Acid OHsuch as • They are named – HCl hydrochloric acid with the metal • Group -ate becomes –ic and hydroxide. and -ite becomes –ous. • NaOH is sodium • H2SO3 sulfurous acid hydroxide • H2SO4 sulfuric acid 15 An advertisement claims that patients can be cured of the common cold in 48 hours by vitamin C tablets with secret mineral supplements. In a scientific experiment to test these claims, which data can be considered irrelevant? A The amount of vitamin C in each tablet B The severity of the patients’ cold symptoms C The chemical formula for vitamin C D The amount of time before symptoms improve What doesn’t matter to the test? A The amount of vitamin C in each tablet This should be a controlled variable! B The severity of the patients’ cold symptoms This would be very hard to control, but a large experimental group should allow for differences C The chemical formula for vitamin C Compound formulas NEVER change so this is our answer it is irrelevant!!! D The amount of time before symptoms improve This is what we are testing, it is most relevant. Density = Mass / Volume THIS IS FROM THE FORMULA PAGE 25 A block of maple wood with a volume of 405 cubic centimeters and a density of If0.67 the block in half, in youhalf. cut the in half g/cmis3 cut is sawed Themass density AND youtwo cut smaller the volume in half, or of the blocks is so nowMass/2 — Volume/2 A one-fourth the original density Mass the x 2original (whichdensity is really 1) so . . . . B one-half Volume 2 original density C two times the D the same as the original density Changes in Matter – Physical or Chemical? • Physical changes are changes in the state of matter. They do not change the substance. (Melting, boiling, condensing, freezing, cutting) • Chemical changes are reactions that result in new products with new properties. 20 A sample of an element has a volume of 78.0 mL and a density of 1.85 g/mL. What is the mass in grams of the sample? Record and bubble in your answer to the nearest tenth on the answer document. Use the formula page, D = M/V x 1.85 g/mL = 78.0 mL Multiply both sides by 78.0 mL and you get: 144.3 g Grid it in! Law of Conservation of Matter • Matter can not be created or destroyed. • The total mass of the substances before they are mixed is equal to the total mass as a mixture. Chemical Reactions Since matter can not Reactants Products be created or destroyed, chemical 100g total = 100g total reactions must be balanced in terms of mass. The amount of mass you start with must be equal to the mass of the products. 39 According to the law of conservation of mass, how much zinc was present in the zinc carbonate? Since matter can not be created or destroyed in A 40 g B 88 g C 104 g D 256 g chemical reactions, the mass on both sides of the arrow must be equal. So 64g + 192g = 256g and 152 g + Zinc = 256g There must be 104g of Zinc. Answer C. Chemical Equations • Whole numbers written in front of formulas are called coefficients. For example, 4 C6H12O6 indicates that there are 4 molecules of glucose sugar. • To determine how many total atoms of each element are present, multiply the coefficients by the subscripts for each element. • 4 C6H12O6 would contain 24 atoms of carbon (4 x 6), 48 atoms of hydrogen (4 x 12), and 24 atoms of oxygen (4 x 6). To balance equations: • The number of atoms of each type of element on the reactant side (left of the arrow) must be equal those on the product side (right side of the arrow). 2 H2 + O2 2 H2 O • There are 4 hydrogen atoms on the left (2 H2) and 4 hydrogen atoms on the right (2 H2O) • There are 2 atoms of oxygen (O2) on the left and 2 atoms of oxygen on the right (2 H2O). When a subscript is missing, it is understood to be 1. 2 2 K + 2 HHOH O KOH + H2 2 19 What is the coefficient for H2O when the above equation is balanced? • A 1 To balance this equation, make water HOH, then you will see that you need • B2 2 H and get 2 OH groups. • C3 That means the KOH gets a coefficient • D 4 of 2, the K gets a coefficient of 2 and The water must also get a coefficient of 2. Balance the equation below, the boxes should get the coefficients. 2 2 Which element does not have the same number of atoms on both sides? Oxygen. It has 2 on the reactant side and 3 on the product side. If we put a coefficient of 2 in front of PbO, we will now have 4 O and 2 Pb on the right. By placing a coefficient of 2 in front of the reactant, we have 2 Pb and 2 x 2 O. That means it is balanced! Answer? C The 3 types can be further separated in two categories: • Mixtures are • Pure Substances not pure Compounds which are formed substances. Each part when of a two mixture keepsoritsmore ownelements share electrons or properties, andbecome can be ions that • Elements are the separated out attract by a physical other simplest pure elements. change. substances Decide if the substance is Element, Compound , or Mixture? 1. Water 1. Compound 2. Table Salt 2. Compound 3. Oxygen 3. Element 4. Dirt 4. Mixture 5. Air 5. Mixture/Solution Click Mouse button to see answers! Let’s try a few more! 6. Copper 6. Element 7. Soda 7. Solution/Mixture 8. Steel 8. Solution/Mixture 9. Rain 9. Mixture 10. Ice-cream 10. Mixture Click Mouse button to see answers! Changes in Matter – Physical, Chemical or Nuclear? • Physical changes do • Chemical changes not change the are also called substance. The state chemical reactions. of the matter may • When a different change, but it keeps its substance is own properties. produced than what • Cutting a piece of was present at the wood does not change start, a chemical the wood, it is simply change has occurred. smaller. Nuclear Changes: Fission and Fusion • Fusion occurs when • Fission occurs when the the nucleus of one nucleus of an atom atom is joined by the ejects particles and nucleus of another. energy when hit by a subatomic particle such • This is the reaction as a neutron. that occurs on the sun and stars. • This also causes a release of extreme • It produces extreme energy and is the basis energy release. of atomic energy plants and bombs. There are two types of mixtures: • Heterogeneous• Homogeneous- same mixture is not the composition throughout. same from place to place. – Kool-aid, air, brass. – Chocolate chip cookie, gravel, soil. Properties of Mixtur es: •Each substance retains its own properties. •Substances can be present in any amount. •Substances can be separated by simple p h y s i c a l m e a n s. Separating Mixtures – Physical Changes • Separation of mixtures could be: • Magnetic removal (if there is Fe, Ni, Co) • Filtration (if there are large particles) • Hand sorting particles • Decanting (pouring off the less dense liquid) Another technique for separating mixtures: Evaporation: changing from a liquid to vapor state– leaves behind the other component. Distillation: – Process used to remove vapor from liquid by heating – Great for separating two or more liquids which have different boiling points. So, what is a suspension or colloid? •o Colloids Suspensions have have small larger particles particles, that are often not visible visibleinby size. just looking. An example would be o The particles can be coffee. filtered out. • However, they show o the It scatters – No Tyndalllight Effect (see Tyndall Effect. the laser light line). •o They not be the If left can undisturbed, separated filtering. particles will by settle to the bottom. Solutions: 2 parts –S o l v e n t - t h e m o s t abundant substance in the solution. –S o l u t e - t h e l e a s t abundant substance in the solution. – Homogeneous: You can not see any particles of either part! The three methods to increase the rate of solution for a solid are? •Heat it! •Crush it! •Stir it! 17 All of these can affect the rate at which a solid dissolves in water except — A decreasing air pressure B stirring the water C increasing the temperature of the water D using larger crystals of the solid The three methods to increase the rate of solution for a solid are? • • • • Heat it! C Crush it! D slows it Stir it! B So this eliminates choices B, C & D • Which will NOT change it? • A Answer choices were: A decreasing air pressure B stirring the water C increasing the temperature of the water D using larger crystals of the solid Solubility Factors – What will dissolve? • • • • Solubility Rules 1. All sodium, potassium, and ammonium salts are soluble. 2. All silver, lead, and mercury salts are insoluble. 3. All carbonates, sulfides, and hydroxides are insoluble. 4. All nitrates and sulfates are soluble except calcium sulfate and barium sulfate. 10 A 0.2 g crystal of gypsum dissolves very slowly in 100 mL of water while the water is stirred. Which of these would cause the gypsum to dissolve faster? What are the 3 ways to increase the rate at which a solid F Decreasing the dissolves? water temperature Heat it! G Stopping the stirring Crush it! H Lowering the air Stir it! pressure ANSWER? J Crushing the crystal J the amount of each solute that will dissolve in 100g H20 at each temperature. Saturated is on the line. Unsaturated is below the line. Supersaturated is above the line. Grams solute/100 g H2O How much solute will dissolve? A solubility curve shows 51 At which temperature do KBr and KNO3 have the same solubility? A 27°C B 48°C C 65°C D 80°C Try this one! 49 According to the graph, about how much hemoglobin would be saturated at an O2 pressure of 7.3 kPa? A 32% B 67% C 89% D 92% Concentrated or Dilute? • A concentrated solution has as little solvent as possible. • A dilute solution has added solvent. • After adding more solvent, there is still the same mass of solute that you started with. pH is a measure of the Strength of Acids & Bases • Acids have 0-6.99 pH • Bases have 7.01-14 pH • Remember because A begins the alphabet and zero begins numbers • Litmus turns red in acids and blue in bases • Phenothalein turns pink in a base and stays clear in acids. Higher pH levels means? 33 Two clear solutions are placed in separate beakers. The first solution has a pH of 4, and the pH of the second solution is unknown. If the two solutions are mixed and the resulting pH is 5, the second solution must have — A fewer suspended solids and have no Solutions are homogeneous Nothing is mentioned about temperature so B is suspended solids. B invalid. a lower temperature NaCl solutions are neutral so have no effect on C more dissolved salt (NaCl) particles pH. D a higher concentration of OH– ions Chemical Reactivity • Metals increase in reactivity left and down. • Nonmetals become more reactive up and to the right. • Most reactive metal is? Fr • Most reactive nonmetal is? F Now its your turn! • Answer on your own paper the questions from the handout. We will check your answers before you leave.