Introduction to Chemistry Chem 003A Spring 2011 Instructor: Brett Williams Lecture: TTh 6:00 PM-6:55 PM in Cunningham 319 Laboratory: TTh 7:00 PM-9:55 PM in Cunningham 301 Two ways to reach me: E-mail: balero01@cs.com E-mail: bwilliams@deltacollege.edu Course is comprised of: Lectures Problem Sets Assigned Homework Quizzes Lab Exercises Lab Experiments Worksheets 4 Exams and 1 Final Exam Lectures Presented on power point slides Lecture notes are available in hard copy To download files, go to this adjunct faculty site: www.deltacollege.edu/emp/bwilliams Not required for class, but recommended Lecture notes complement the textbook/assignments but attendance is essential to get all of the information you need Problem Sets Subsequent to specific lectures Several practice problems associated with the current lecture topic Some problems sets will be covered in class Some of the problem sets can be submitted for credit Problems sets are to assist you (supplement) with homework assignments in the text Not every type of chapter problem is represented on the problem sets Homework Assigned for each chapter Problems are placed near the beginning of each power point lecture presentation All odd numbered answers are placed at the end of the book HW will not be collected or graded HW is not mandatory but if you don’t do the HW it may affect your performance on the quizzes Quizzes Five Chapter Quizzes 20 points each No make-ups (generally) Based on the homework assignments for that chapter 20-30 minutes long Given during the first hour The best 4 of 5 chapter quizzes are used in your total score Two Name and Formula Quizzes for Chapter 5 Other Lab Assignments Lab Exercises Ten (total) exercises 10 points each Most will originate from your lab textbook Some exercises will be provided to you Worksheets Not collected or graded To be completed during lab period A review to prepare for exams Experiments Ten (total) experiments 20 Points Each Labs reports are due in one week, e.g., if an experiment is completed on Tuesday, the report is due the following week (next Tuesday) 60 % rule: A student must meet this minimum score in lab to pass the course. No exceptions The best 9 out of 10 experiments are used in your total score Exams Four exams Based on the chapters which are listed in the syllabus 100 points each All exams count in total score Time: 2 hours to complete Final Exam Thursday, 3 May th 26 , Hours Cumulative Exam 200 points 6 PM Grading Scale (Based on 1000 possible points) 90.0 - 100 % 75.0 - 89.9 % 60.0 - 74.9 % 50.0 - 59.9% < 50.0 % A B C D F Required Materials Textbook: Introductory Chemistry, 3rd ed. by Tro Laboratory Manual: Foundations of Chemistry in the Laboratory, 13th ed. by M. Hein, et al Calculator Safety Goggles & Lock Laboratory Policy No one may participate in lab wearing open toe / heel shoes. Watch what you wear on lab days. If you have inappropriate attire, you will NOT be allowed to complete the lab Goggles must be worn during all lab experiments Your attendance and participation is expected Chapter 1 The Chemical World Chemicals Compose Ordinary Things Chemistry The study of the properties and the behavior of chemicals (matter) The composition, structure, and reactions of chemicals The connection between the properties of a substance and the properties of the particles that compose it Why does soda pop fizz (effervesce)? Why is water a liquid? Why is a sunset red? All Things Are Made of Atoms and Molecules Matter is defined as anything with mass and occupies space The science of chemistry developed from observations made about the makeup and behavior of certain kinds of matter Chemistry focuses on the properties of substances and the interactions of various types of matter All things around you are composed of atoms and atoms bond together to form molecules All Things Are Made of Atoms and Molecules How atoms are bonded and the types of atoms present determine the properties of a substance The makeup and properties of matter are analyzed two ways: Macroscopic: Where observations are made (what we see) Microscopic: The atoms and molecules that compose matter (atomic level) How atoms are bonded (spatial arrangement) and the types of atoms present determine the properties of a substance Chemistry helps us to understand the connection between our world and the world of atoms and molecules Chemical Processes Chemistry occurs around you everyday and affects everything you use and do Chemical processes (reactions) occur in nature and happen around you all of the time The molecular interactions (microscopic) create your experience (macroscopic) Chemistry (reactions) occurs when cooking or baking food burning wood in a fireplace disinfecting swimming pool water with chlorine supplying power to a portable radio with batteries deicing sidewalks and roads with rock salt bleaching stains out of clothing Chemical Processes In nature: microorganisms convert sugars to alcohols (fermentation) plants (algae and bacteria) convert carbon dioxide and water plus sunlight energy into sugar (photosynthesis) leaves change color in Autumn due to the disappearance of chlorophyll and the interaction of sunlight with the remaining pigments Chemical Processes In laboratories / industrial processes: crude oil is refined (separated) into gasoline and other components synthetic fibers (nylon, polyester, acrylic) are produced and used to make apparel (textiles), home furnishings, and other industrial goods new pharmaceuticals are (designed) synthesized by organic chemical reactions water softening is used to remove certain metals from water for household use pesticides, fungicides, and herbicides are produced (synthesized) to protect our food supply Chemistry and Chemicals Everything around you is composed of chemicals A chemical is a material used or produced in a chemical process (in the laboratory, in manufacturing, or natural) A chemical substance (compound) is a material that consists of a specific chemical composition A pure (chemical) substance is one that consists of one type of matter with the same composition and properties throughout (two or more bound elements in a fixed ratio) For example, pure water has the same properties and the same ratio of hydrogen to oxygen whether it is isolated from a river or made in a laboratory Chemical substances that are commonly used: salt, sugar, baking soda, borax, ethanol, soda lye (soap), vitamin C Scientific Disciplines Science is the study in which humans attempt to explain knowledge about themselves and their surroundings As more knowledge is gained, facts are organized and explained, in a systematic and logical manner Science attempts to understand (better) how nature works Physical evidence is obtained through an observable occurrence (a phenomenon) Experiments are conducted to simulate events under controlled conditions to test explanations and predictions Scientific Disciplines Science covers an enormous range of accumulated information which is divided into branches called scientific disciplines Chemistry is one of the branches of physical science (includes astronomy, physics, geology) Branches of biological science (natural sciences) include botany, microbiology, zoology The Scientific Method Most scientific and technological advances are through the use of experimentation as a method of problem-solving Experimentation is a process that is used to explore observations and answer questions, i.e., to search for cause and effect relationships in nature In general, no two scientist will approach a problem exactly in the same manner Scientist (chemists) use a method of learning that emphasizes observation and experimentation: the Scientific Method Within the scientific method are the guidelines for the practice of science to achieve systematic experimentation The Scientific Method Scientific Method: A set of procedures (steps) used to acquire knowledge and explain an observable fact The process (steps): 1) Observations: Identify the problem and plan procedures to obtain information Collect Data: Observe, describe, and take measurements (data) Organize data to find patterns in the information 2) Once sufficient data is collected, form a hypothesis A hypothesis is a possible model or statement that offers an explanation for the observations The Scientific Method Design an Experiment The problem: How, What, When, Who, Which, Why, or Where? Research to find the best way to approach things Make an educated guess about how things work: “If ___ (I do this)___, then___ (this)___will happen.” Your hypothesis should be stated in a way that is measurable to help answer your original question Test your hypothesis by doing an experiment Design the experiment so that changes in one item causes something else to vary in a predictable way The Scientific Method: Hypothesis, Theory, Law 3) Experiments: A well-defined, controlled procedure to obtain information To validate the hypothesis perform more experiments If an experiment is performed under exactly the same conditions, the same results (facts) should occur If results are different than predicted, modify or propose a new hypothesis 4) Theory A hypothesis that has been tested and validated over a long period of time Hypothesis evolves to theory if experiments are repeated and confirm the hypothesis The Scientific Method: Hypothesis, Theory, Law If after extensive testing the reliability of a hypothesis becomes very high, it will evolve into a theory A theory allows a scientist to predict the outcome of proposed experiments If results of future experiments conflict with the current theory it must either be modified, restated, or even replaced The Scientific Method: Hypothesis, Theory, Law After determining what facts are known about a selected problem, more experimentation is performed to obtain more information As more facts are obtained, look for repeating patterns among the collected facts If a large number of facts are tied together, it can eventually lead to a single generalized statement called a scientific law Law: A concise, verbal statement that summarizes facts about a natural phenomenon Using the Scientific Method In Summary: Identify the problem and plan procedures to obtain information Collect data through observation and experimentation Qualitative: Do not involve a number Quantitative: Involve measurements Analyze and organize the data to summarize observations (form generalizations) Suggest probable explanations (form a hypothesis) Experiment further to prove or disprove the proposed explanations ExampleII Example Topic: Does the amount of sunlight a tomato plant receives affect the size of the tomatoes? You have observed the plants in the garden exposed to more sunlight appear to grow larger Your hypothesis: “The more sunlight a tomato plant receives, the larger its tomatoes will grow.” Example ExampleII Your hypothesis is based on the fact that tomato plants need sunshine to produce sugar (by photosynthesis) and bear fruit You observe that the tomato plants exposed to more sunlight appear to grow larger You set up an experiment with two sets of plants. Both receive the same care with one set exposed to more sunlight Example I Collect your data and summarize your results Conclusion: The hypothesis is supported by the data or it can be rejected (not supported by the data) The hypothesis cannot be proven with one experiment However, the original hypothesis can be supported by the collected data ExampleIIII Example Topic: You have probably noticed (observed) that soda pop fizzes (bubbles) when the bottle is opened. Step 1: State the problem. Why does soda pop fizz? Step 2: Gather information (data) Examine soda pop’s properties Its color, taste, etc. It bubbles/fizzes when opened Examine soda’s composition Example II Step 3: Organize the information (data) All the material around you is composed of chemicals Soda’s composition: The three main chemical ingredients of soda pop are water, sugar, and carbon dioxide sugar = sweetness water = liquid carbon dioxide = gas Example II Step 4: Look for patterns Structure determines properties, so the fizzing of soda must have something to do with its composition Carbon dioxide, a component of the soda (carbonated beverages), is a gas We know that: If we blow air (a gas) into water, bubbles form. When water boils it forms bubbles (into steam) Bubbles are similar to those of bubbling soda. Example II Step 5: Propose a hypothesis Based on the fact that the only gas in soda is carbon dioxide: “The reason soda pop fizzes is because the carbon dioxide is coming out of the soda.” Step 6: Test your hypothesis How would you set up an experiment to test it? Benefits to Studying Chemistry To further understand our world and its impact on our daily living (health care, natural resources, environmental protection, food supply) Provides a better understanding of other areas of modern science and technology Enhances problem-solving skills The ability to solve complicated chemistry problems can be applied to other types of problem-solving Facilitates your development of a systematic approach to scientific thought (logical, analytical) The scientific thought process also develops your ability to predict future events based on patterns of behavior A Beginning Chemist: How to Succeed Some memorization is required: Learn the terms (vocabulary) Ask about something that occurs in nature: How, what, when, who, why, which, or where? Calculation is required: Problem solving will include conceptual checkpoints, sample problems, and student exercises Commitment: Use active learning by reading the text, regularly attending class and practicing “problem solving” In-class activities include problem sets, exercises Learning Chemistry Develop your own study plan Do the recommended problems Your confidence and problem solving skills are enhanced through repetition Don’t expect to grasp every concept the first time you see it Read the text, come to class Ask questions Homework “Conceptual Checkpoint 1.1” (a, b, c, d) “Checkpoints” succeed certain chapter sections “Exercises” 1-13 (odd only) “Problems” 15-19 (odd only)