Nature of Matter SECTION 2.1 Matter Defined as anything that occupies space and has mass Everything we see around us is matter Soil Air Water Rocks Plants Animals States of Matter Kinetic Energy—energy of motion; all particles of matter are in constant motion and therefore have kinetic energy The temperature of matter is an indirect measurement of the particles’ average kinetic energy At low temperatures, the particles have very little kinetic energy and move very little At high temperatures, the particles can have enough kinetic energy to fly about at thousands of kilometers per hour States of Matter Solid Has a definite shape A definite volume Very difficult to compress Particles are packed close together and held rigidly States of Matter Liquid Has the shape of its container Has a definite volume Difficult to compress Particles close together but free to move States of Matter Gas Has no definite shape Has no definite volume Relatively easy to compress Particles far apart Plasma A hot gas in which atoms are partially broken down to form charged particles, or ions States of Matter When the substance reaches a certain temperature, called the melting point, the particles have enough energy to break loose from their rigid positions and form a liquid When a liquid is heated to the boiling point, the particles gain enough kinetic energy to break away from each other forming a gas Classification of Matter Substance: a form of matter with unique properties that make it different from every other substance Examples: Water, copper, baking soda, table salt, aluminum, etc. Atoms: the smallest particles of an element (not the smallest particles of matter) Elements: substances that cannot be broken down into simpler substances by ordinary chemical means Examples: Oxygen, hydrogen, gold, iron, lead, potassium, nitrogen, silicon (other elements listed in the periodic table of the elements) Not all elements are found as single atoms Molecules: groups of two or more atoms that are linked by chemical bonds to form distinct units These two-atoms elements are called diatomic elements; other elements exist as larger molecules Examples of diatomic elements: hydrogen, oxygen, nitrogen, flourine, chlorine, bromine, and iodine Atomic Symbols Memorize tables 2.2 and 2.3 Abundance of Elements 118 elements identified thus far 88 occur naturally in significant amounts More than 99% of the earth’s crust, oceans, and atmosphere is made up of only eight elements Oxygen-the most abundant element in the earth’s crust Iron-the most abundant element in the earth as a whole Hydrogen-the most abundant element in the universe Compounds A substance that can be decomposed into simpler substances Examples: water (H2O) and table salt (NaCl), A compound has properties quite different from those of the elements from which it is formed Example: hydrogen-highly flammable; oxygen-flammable; H2O-commonly used to put out fires Formula A molecule of a compound is composed of different types of atoms linked together The compound may be represented by a formula-a grouping of symbols that tells what types of atoms compose the compounds and the number of each type of atom in one molecule of the compound Ex. H2O; CO; CO2; C6H12O6 Pure Substances Elements and compounds Definite composition (relative amounts of each element in a given compound are unchangeable, no matter where the compound may be found) Homogeneous (same kind)-composed of the same kind of matter throughout the sample Mixtures A substance consisting of two or more pure substances that are physically mixed but not chemically combined Each component retains its own properties Each can be present in various proportions and can be separated from the mixture by physical means Homogenous Mixtures Solutions; same throughout Examples: air, vinegar, sweetened coffee, steel Heterogeneous Mixtures Consists of pure substances that are incompletely mixed Each component in a heterogeneous mixture forms a distinct phase—a homogeneous part of a system that is in contact with but physically distinct from other parts of the system Examples: Dalton’s Atomic Theory 1. Every element consists of tiny, indivisible, indestructible particles called atoms 2. All of the atoms of a particular element have the same size, mass, and chemical behavior 3. Differences in properties of elements result from differences in the atoms of the elements 4. The atoms of the elements combined in a compound are combined in a definite ratio 5. A chemical reaction is the result of rearrangement, combination, or separation of atoms The Law of Definite Composition States that the ratios of the masses of each element in a given compound are always the same Example on pg. 22 The Law of Multiple Proportions States that when two elements can combine to form more than one compound, the masses of one element that combine with a fixed amount of the other element are in a ratio of small whole numbers Example on pg. 22 Section 2.2: Properties and Changes of Matter One type of matter may be described, identified, or distinguished from another by its properties. Physical Properties Properties that describe a substance’s appearance Include: color, odor, density, hardness, solubility, taste, state, boiling point, and melting point Can be measured without changing the identity or composition of the substance Chemical Properties Properties that describe how matter reacts to change into other chemically different substances having different properties That iron rusts easily in moist air and that propane burns readily are chemical properties of these substances Can only be determined through chemical reactions, which change the identity of a substance Physical Changes Changes in the physical appearance of matter that do not change the identity or chemical composition of a substance Physical changes may often be reversed by physical processes Change of state, conversion of heterogeneous to homogeneous matter, metal hammered into a sheet, tearing a sheet of paper, crushing a large rock into gravel, cutting your hair, etc. No change in chemical identity results, only changes in shape or size Chemical Changes A change in which a substance becomes a different substance with a different composition and properties Sodium–a shiny, soft, poisonous metal that reacts violently with water Chlorine—a greenish, poisonous gas with an irritating odor When sodium and chlorine react chemically, a white crystalline solid with a salty taste is formed, namely sodium chloride Chemical Changes Other examples: Rusting of iron The digestion of food The grilling of steaks The burning of gasoline The cooking of eggs The burning of a match Chemical Changes Chemical changes can be reversed only by other chemical changes Not all chemical changes can be reversed The cooking of an egg Chemical Changes A number of observations can be made that will suggest that a chemical change has occurred Formation of a gas Formation of a precipitate (an insoluble substance) Liberation or absorption of heat, light, or some other form of energy A distinct change in color Separation of Mixtures Distillation—used to separate homogeneous mixtures in liquid form if the components have widely differing boiling points Simple Distillation When a mixture has components with boiling points that are close together, fractional distillation is used Separation of Mixtures Fractional Crystallization Used to purify a solid containing a relatively small amount of solid impurity Chromatography Used to separate complex mixtures Paper Chromatography Column Chromatography Gas Chromatography Section 2.3: Subatomic Particles Subatomic Particles Protons, neutrons, and electrons Electrons—has a negative charge Proton—has a positive charge, located in the nucleus Neutron—has no charge, located in the nucleus Rest of the notes in this section will come from the videos Section 2.4: Atomic Number, Mass Number, Isotopes, and Ions The number of protons in the nucleus determines the identity of an element Atomic number—the number of protons in the nucleus Denoted by the symbol Z All atoms of the same element have the same number of protons and hence the same atomic number, Z Mass Number Denoted by the symbol A The sum of the number of protons and the number of neutrons in a nucleus A=Z+N Nuclear particles, whether protons or neutrons, are known collectively as nucleons The mass number is not really a mass; it is a number of nucleons and must be a whole number Isotopes Atoms of the same element that differ in their mass numbers Examples: Pg. 31 Ions Atoms or molecules that have a different number of electrons than protons An ion with more electrons than protons is called and anion Has a negative charge An ion with fewer electrons than protons is called a cation Has a positive charge In neutral atoms, there are equal numbers of electrons and protons Examples: pg. 32 Example 2.1 Application 1-3 Section 2.5: Atomic Mass An atom’s atomic mass measured in atomic mass units approximately equals the atom’s mass number Atomic mass units denoted a u Mass Spectrometer Used to measure atomic masses with high precision Mass Spectrum A record of the mass distribution of particles in a sample Average Atomic Mass Calculated by finding the weighted average Example: pg. 34 Track team Example 2.2 pg. 35 Chapter 2 Homework and Groupwork will be due Friday They will be handed out at the beginning of class on Tuesday Chapter 2 Quiz on Friday