Lead II carbonate SnO2 Period 8 Day 5 115 Acid - Compound that yields H+ ions (always starts with an H) – molecular compounds that act like ionics Naming: Acids are named for their anions Binary: hydro – anion base – ic ending – the word “acid” Naming: Acids are named for their anions Binary: hydro – anion base – ic ending – the word “acid” Non-binary: ate ending becomes ic, ite ending becomes ous HF HBr HNO3 HNO2 Naming: Acids are named for their anions Binary: hydro – anion base – ic ending – the word “acid” Non-binary: ate ending becomes ic, ite ending becomes ous Hydrochloric acid Sulfurous acid sulfuric acid hydrofluoric acid carbonic acid HC2H3O2 HCl H2SO3 # 2.57 (parts a-g) AND 2.58 (parts a-e) AND 2.59 (parts a-f) BINDERS!!! Lead II carbonate Phosphoric acid H2SO4 SnO2 Periods 1 + 3 Day 5 11-5 Phosphorous acid nickel III oxide Pb(CO3)2 HClO3 Periods 3 + 8 Day 6 11-6 Ionic Compounds & Polyatomic Ions Oxyanions – polyatomic ions that contain oxygen ate = ending for most common ion (ClO3- Chlorate) ite = ending for one less oxygen (ClO2- Chlorite) hypo = prefix for another less oxygen (ClO Hypochlorite) per = prefix for one more than most common (ClO4Perchlorate) Molecule – group of atoms united by covalent bonds (molecules = molecular substance) Empirical - simplified ratio Molecular - How many atoms in a single molecule (not always a simplified ratio, glucose = C6H12O6) Empirical - Simplified ratio Molecular - How many atoms in a single molecule (not always a simplified ratio, glucose = C6H12O6) Structural - Specifies which atoms are bonded to each other (organic chem) Molecular Element – molecule of atoms of same element – NOT a compound - like O2, Cl2, O3 H BrONClIF = diatomic molecules - these elements naturally occur as diatomic molecules and not singular atoms Binary Molecular Compounds Based on Prefixes 1. Less electronegative first – prefix only if more than one atom 2. Second element – prefix, root of name, ending ide (if only two elements) 3. o or a @ the end of prefix is dropped if name begins with a vowel (monooxide, monoxide) Mono Di Tri Tetra Penta Hexa Hepta Octa Nona Deca 1 2 3 4 5 6 7 8 9 10 Binary Molecular Compounds – prefix system Binary Molecular Compounds Write the Name: N2O5 Dinitrogen pentoxide SbF3 Antimony trifluoride Write the Formula: Germanium tetraiodide GeI4 diphosphorous trioxide P2O3 Binary Molecular Compounds Write the Name: As2O5 diarsenic pentoxide ICl3 iodine trichloride Write the Formula: carbon tetraiodide CI4 dinitrogen trioxide N2O3 Phosphorous acid nickel III oxide Pb(CO3)2 HClO3 Period 1 Day 6 11-6 Day 1 11-9 For each compound below, what type is it (covalent, acid, or ionic), and write the name. NO2 HNO3 Co3(PO4)2 Green = halogens Black = carbons White = hydrogens Red = oxygen Blue = nitrogen Grey / purple = metal Formulas Names Day 2 11-10 For each compound below, what type is it (covalent, acid, or ionic), and write the name. HC2H3O2 Cu3PO3 SF6 • Molecular compounds − Nonmetals or nonmetals + metalloids − Common names − H2O, NH3, CH4 − Element furthest to the left in a period and closest to the bottom of a group on periodic table is placed first in formula − If more than one compound can be formed from the same elements, use prefixes to indicate number of each kind of atom − Last element name ends in -ide 23 Molecular Compounds HI hydrogen iodide NF3 nitrogen trifluoride SO2 sulfur dioxide N2Cl4 dinitrogen tetrachloride NO2 nitrogen dioxide N2O dinitrogen monoxide 24 Example 2.7 Name the following molecular compounds: (a) SiCl4 (b) P4O10 Example 2.7 Strategy We refer to Table 2.4 for prefixes. In (a) there is only one Si atom so we do not use the prefix “mono.” Solution (a)Because there are four chlorine atoms present, the compound is silicon tetrachloride. (b)There are four phosphorus atoms and ten oxygen atoms present, so the compound is tetraphosphorus decoxide. Note that the “a” is omitted in “deca.” Example 2.8 Write chemical formulas for the following molecular compounds: (a) carbon disulfide (b) disilicon hexabromide Example 2.8 Strategy Here we need to convert prefixes to numbers of atoms (see Table 2.4). Because there is no prefix for carbon in (a), it means that there is only one carbon atom present. Solution (a) Because there are two sulfur atoms and one carbon atom present, the formula is CS2. (b) There are two silicon atoms and six bromine atoms present, so the formula is Si2Br6. 29 An acid can be defined as a substance that yields hydrogen ions (H+) when dissolved in water. For example: HCl gas and HCl in water •Pure substance, hydrogen chloride •Dissolved in water (H3O+ and Cl−), hydrochloric acid 30 31 An oxoacid is an acid that contains hydrogen, oxygen, and another element. HNO3 nitric acid H2CO3 carbonic acid H3PO4 phosphoric acid 32 Naming Oxoacids and Oxoanions 33 The rules for naming oxoanions, anions of oxoacids, are as follows: 1. When all the H ions are removed from the “-ic” acid, the anion’s name ends with “-ate.” 2. When all the H ions are removed from the “ous” acid, the anion’s name ends with “-ite.” 3. The names of anions in which one or more but not all the hydrogen ions have been removed must indicate the number of H ions present. For example: – H2PO4- dihydrogen phosphate – HPO4 2- hydrogen phosphate – PO43- phosphate 34 35 Example 2.9 Name the following oxoacid and oxoanion: (a) H3PO3 Example 2.9 Strategy To name the acid in (a), we first identify the reference acid, whose name ends with “ic,” as shown in Figure 2.15. Solution (a)We start with our reference acid, phosphoric acid (H3PO4). Because H3PO3 has one fewer O atom, it is called phosphorous acid. A base can be defined as a substance that yields hydroxide ions (OH-) when dissolved in water. NaOH sodium hydroxide KOH potassium hydroxide Ba(OH)2 barium hydroxide 38 Hydrate – ionic substances that absorb water into their solid structures Anhydrous substance – opposite of hydrates (water-free) 1. Name ionic compound 2. use prefix to name hydrate Name CuSO4 • 5 H2O Copper (II) sulfate pentahydrate MgSO4 • 7 H2O Magnesium sulfate heptahydrate Formula Calcium sulfate dihydrate CaSO4 • 2 H2O Hydrates are compounds that have a specific number of water molecules attached to them. BaCl2•2H2O barium chloride dihydrate LiCl•H2O lithium chloride monohydrate MgSO4•7H2O magnesium sulfate heptahydrate Sr(NO3)2 •4H2O strontium nitrate tetrahydrate CuSO4•5H2O CuSO4 41 42 Organic chemistry is the branch of chemistry that deals with carbon compounds. Functional Groups: H H O H H C OH H methanol H C NH2 H methylamine H C C OH H acetic acid 43 44