Properties of Atoms and the Periodic Table Chapter 18 18-1: Structure of the Atom Atoms Atom – the smallest unit of matter that can’t be broken down by chemical means Atoms are made up of three types of particles: Proton: (+) charged Neutron: no charge Electron: (-) charged Nucleus – consists of protons and neutrons Atoms A proton is about 1000 times larger than an electron Electron cloud – the region where electrons orbit the nucleus 18-2: Masses of Atoms Atomic Mass Atomic mass = protons + neutrons Atomic number - The number of protons in the nucleus of an atom, which determines its place in the periodic table Atomic Mass Atomic Facts Atomic number = protons = electrons Atomic mass - Atomic number # of neutrons Maximum number of electrons 1st energy level – 2 electrons 2nd energy level – 8 electrons 3rd energy level – 18 electrons Atomic Mass Element – A substance made up a group of similar atoms that have the same number of protons Atomic Mass Isotopes – Atoms of an element that have different numbers of neutrons Chemical Bonds Valence electron – An electron that is found in the outermost shell of an atom Lewis dot diagrams can be used to show the transfer of valence electrons Chemical Bonds Chemical bonds form between groups of atoms because most atoms become stable when they have eight electrons in the valence shell (Octet rule) Chemical Bonds Compound – A substance made of the bonded atoms of two or more different elements Chemical Bonds Ion – an atom or group of atoms that has an electric charge because it has gained or lost electrons Ionic bond – the attractive force between oppositely charged ions Chemical Bonds Covalent bond – chemical bond that shares electrons Molecule – A group of atoms held together by covalent bonds Chemical Bonds Hydrogen bond - A chemical bond in which a hydrogen atom of one molecule is attracted to an electronegative atom Chemical Bonds Polarity Polar – molecules with partial charges on opposite ends Water is the most abundant compound in organisms Average Atomic Mass Average atomic mass is not a straight average but a weighted average based upon the percent isotopic ratio of the element. (Mass1 x % Isotope1) + (Mass2 x % Isotope2) + (etc.) 100 100 Average Atomic Mass 43.00% of 74.2 amu; 57.00% of 77.1 amu (Mass1 x % Isotope1) + (Mass2 x % Isotope2) + (etc.) 100 100 (74.2 amu x 43.00) + (77.1 amu x 57.00) 100 100 (3190.6 amu) + (4394.7 amu) 100 100 31.906 amu + 43.947 amu 75.853 amu 18-3: The Periodic Table The Periodic Law The modern periodic table is based on atomic number, or number of protons. The Periodic Law Period – Each row in the table of elements Hydrogen, the first element in Period 1, has one electron in its first energy level. Lithium, the first element in Period 2, has one electron in its second energy level. The Periodic Law Group – Each column in the periodic table The elements in a group have similar electron configurations The Periodic Law Classes of Elements Metals – elements that are good conductors of electric current and heat Except for mercury, metals are solids at room temperature Classes of Elements Metals (cont.) Malleable – able to be hammered or pressed permanently out of shape without breaking or cracking Ductile – can be drawn into thin wires Classes of Elements Transition metals – elements that form a bridge between the elements on the left and right sides of the table Many of their compounds are colored Classes of Elements Nonmetals – elements that are poor conductors of heat and electric current Many nonmetals are gases at room temperature Nonmetals that are solids at room temperature tend to be brittle Brittle – hard but liable to break or shatter easily Classes of Elements Metalloids – elements with properties that fall between those of metals and nonmetals 18-3: Representative Groups Representative Groups Elements in a group have similar properties because they have the same number of valence electrons Representative Groups Alkali metals – (Group 1A) These metals have a single valence electron and are extremely reactive Representative Groups Alkaline earth metals (Group 2A) – have two valence electrons Representative Groups Boron family (Group 3A) – have three valence electrons Representative Groups Carbon family (Group 4A) – have four valence electrons Clay used to produce this pottery contains silicon Representative Groups Nitrogen family (Group 5A) – have five valence electrons The numbers on the bags of fertilizer are, from left to right, the relative amounts of nitrogen, phosphorus, and potassium. Representative Groups Oxygen family (Chalcogen) – (Group 6A) have six valence electrons Representative Groups Halogens (Group 7A) – have seven valence electrons Representative Groups Noble gases (Group 8A) – Helium has two valence electrons. Each of the other noble gases has eight valence electrons. Noble gases are extremely unreactive