Skills Practice Answers Skills Practice 1 1. 2. 3. 4. 5. 6. 7. 9,434,880 mL 17.8 cases 0.333 pallet a) 0.1560 m b) 4.1x1010 c) 92,000 μm d) 91,600 nm a) 2.229x107 b) 8.07x106 c) 5.41x1020 d) 1.12x107 a) 2.300021x1010 b) 3.51x10-9 a) 235,400 b) 0.000000003400 Skills Practice 2 1. 2. 3. 4. 5. 6. 7. 8. 325.2 18,000 0.0175 0.790 28,910,000 27 4.9x1012 1.86x105 Skills Practice 8 1. a) 21 b) Scandium (Sc) c) 22 2. Atoms of the same element (having the same number of protons) with a different number of neutrons. 3. a) -2 b) sulfur c) 17 Symbol neutrons protons electrons atomic # mass # 4. 1;3 136 +2 80 56 54 56 136 56π΅π 5. +2 56 31 25 25 25 56 25ππ 199 6. 30 120 79 79 79 199 79π΄π’ 41 +2 21 20 18 20 41 20πΆπ 7. B) ions 8. Strontium (Sr) Skills Practice 9 1. a) 74.92 amu b) Arsenic (As) 2. a) 51.99 amu b) Chromium (Cr) 3. The most abundant is the one with a mass of 40.00 amu. 4. 41.996 amu Skills Practice 10 1) Ground state: the normal energy level that an electron occupies. Excited state: when an electron has absorbed energy to occupy a higher energy level. 2) 7.11x10-8 m 3) 8.62x10-20 J 4) 3.68x10-19 J 5) a) 8.52x1014 Hz b) 5.65x10-19 J 6) f=7.68x1014 Hz wavelength= 3.91x10-7 m Skills Practice 11 1) There is no such thing as an f sublevel in the third energy level. Also, an f sublevel if it existed would have seven orbitals instead of four. 2) 8 3) 10 4) 2 5) Orbitals = 9 Electrons =18 6) 50 7) 4p Skills Practice 13 1) a. ends in: 3d b. ends in: 4d c. ends in: 4p 2) a. 1s22s22p63s23p64s23d4 b. 1s22s22p63s23p64s23d104p65s24d105p3 c. 1s22s22p63s23p64s2 3) Because of Hund’s Rule the 2p sublevel should look like: 1s 2s 2p 4) Three Skills Practice 14 1. 2. 3. 4. a. 5 b. 2 c. 6 d. 8 e. 7 a. 2-8-3 b. 2-6 c. 2-8-6 Column 14 or IVA a. 5 dots b. 2 dots c. 4 dots d. 7 dots Skills Practice 15 1. Abbreviated electron configurations: a. b. c. d. e. f. 2. 3. 4. 5. 6. [Ar] 4s23d104p2 [Xe] 6s2 [Ar] 4s23d104p5 [Xe]6s24f145d106p3 [Ar] 4s23d5 [Xe]6s24f145d9 Column 6 (or VIB) 5th row 3rd row Each d sublevel can hold 10 electons Each p sublevel can hold 6 electrons Skills Practice 16 1. The second energy level feels a +13 charge and the outer energy level feels a +5 charge. 2. Sulfur’s outer level of electrons feels a +6 charge pulling on it from the nucleus. Silicon’s outer level feels a weaker charge of +4 and therefore it is not pulled as close to the nucleus as sulfur’s outer level. 3. Chlorine is lower in the periodic table which would indicate that it is larger than lithium, but it is also located further to the right which would indicate that it is smaller. 4. a) S, Al, Mg, Na b) C, Si, Sn, Pb c) Br, Se, Ca, K d) C, B, Be, Mg, Ca e) Cl, P, Al, Ga f) Ne, O, S, Se Skills Practice 17 1. It is relatively hard to remove the first electon. 2. a) Ca, As, Se, Br b) Bi, As, P, N c) Ga, Al, Si, S d) K, Li, C, O e) Po, Te, S, O e) In, Sn, Te, I 3. Beryllium; After its two outermost electrons are removed, the next electron would need to be removed from an inner energy level, which is much more difficult. 4. Larger atoms tend to have smaller first ionization energies because the outer electrons are farther from the nucleus. Since the electrons are farther, the force of attraction from the nucleus is less. Skills Practice 18 1. 2. 3. 4. Fluorine atom: 2-7; Fluorine ion: 2-8 0; all atoms have a neutral charge. +2 -2, -1, -1, +2, +1, +2, +3, -3, -2, -1, +2, +1 Skills Practice 19 1. Ion Symbol a. b. c. d. e. f. 2. P-3 Mg+2 Rb+1 F-1 Al+3 S-2 3. a. b. c. d. 4. BaS Rb3N LiCl AlN MgBr2 Al2O3 5. Na2S AlCl3 Ca3P2 BaO Names a. b. c. d. Rewrite a. b. c. d. e. f. Formulas Sodium sulfide Aluminum chloride Calcium phosphide Barium oxide +1, +2, +3, +/-4, -3, -2, -1 Skills Practice 20 1. LiC2H3O2 2. Na3PO4 3. Mg(OH)2 4. Omit 5. (NH4)2S 6. K2O 7. AlPO4 8. NaOH 9. Omit 10.Omit 11.Calcium oxide 12.Barium chloride 13.Potassium phosphate 14.Magnesium hydroxide 15.Omit 16.Sodium acetate 17.Lithium sulfate 18.Ammonium sulfate 19.Aluminum cyanide 20.Beryllium chlorate Skills Practice 21 1. MnF4 2. (NH4)3PO4 3. Ni(NO3)2 4. Na3N 5. Al2(SO4)3 6. Cr(OH)3 7. Fe3(PO4)2 8. CuCl2 9. Copper(II) oxide 10.Iron(II) sulfate 11.Ammonium sulfide 12.Nickel(II) Phosphate 13.Chromium(III) hydroxide 14.Barium chlorate 15.Manganese(IV) nitride 16.Copper(I) carbonate 17.6 18.3 19.4 20.8 Skills Practice 22 1. Dinitrogen pentoxide 2. Triphosphorus heptoxide 3. Trisulfur tetrafluoride 4. Carbon dioxide 5. Dinitrogen hexoxide 6. Copper(II) sulfate 7. Ammonium carbonate 8. Sulfur hexafluoride 9. H2O4 10.N3S5 11.CO2 12.N20 13.Fe(NO3)2 14.CCl4 15.C3H7 16.H3PO4 17.NO2 18.CH2 19.C6H9O 20.N2H3O2 21.S2O7 22.C4H3O4 Skills Practice 28 Skills Practice 29 Skills Practice 30 1) 7.02 x 1024 molecules 2) 1121 grams 3) Quantity of particles needed to equal an element’s atomic mass in grams. 4) 1180 grams 5) 183.4 amu; 183.4 g/mol 6) 3.32 moles 7) 1.22 x 1024 atoms 8) 78.6 g/mol 9) 4655 grams 10)1.81 x 1024 molecules Skills Practice 31 1) 15.4% 2) a- 25.8% b- 64.7% 3) a- 53.8% b- 34.4% 4) N2O5 5) N3O6 6) a- C3H4O b- C24H32O8 7) C18H27O36 Skills Practice 32 1)35.0 g Li; 345 g LiNO3; 100 g Ca 2)117 g Na3P 3)229 g CO2; 117 g H20 4)181.7 g Al(NO3)3; 142 g CaCl2 5)41.8 g of each product Skills Practice 35 1. 2. 3. 4. 5. 6. 7. 8. 9. a) 312 K 3.67 L 3.28 K 2.98 L 20 L 15.99 L 45.8 kPa 0.133 kPa 541.2 kPa b) -1460 C Skills Practice 36 1. 3. 4. 5. 6. 7. a) 0.343 moles b) 8.68 L 0.104 kPa*L/mol*K 39.97 g/mol – Argon 138.6 g a) 7.15 x 10-4 mol b) 24.5 L 19.6 L Skills Practice 37 1. 2. 3. 4. 5. 49.8 L; 33.6 g 45.0 L 485 L 4.62 L 1550 L Skills Practice 38 1. 2. 3. 4. 5. a) 97.6 kPa b) 6.9 x 10-4 moles c) 25.4 L 3.38 x 10-3 mol HCl 1.68 L P(hydrogen)= 60 kPa; P(Oxygen)= 40 kPa 3.94 g