C.P. Chemistry I Midterm Review Packet 1) When recording a measurement, how many significant digits should you record? All digits known + 1 estimated digit 2) What is a significant digit? All the digits that can be known precisely + 1 estimated digit 3) The volume of liquid in the graduated cylinder below is: a) 3.3 ml b) 3.30 ml c) 3.4 ml d) 3.60 ml 4) When multiplying or dividing numbers, how many significant digits can your answer have? The same as the number in your problem with the least # of sig figs 5) The density of a block of wood is 3.20 g/cm3. Its length is 10.20 cm, its width is 4.50 cm, and its height is 3.2 cm. What is its mass recorded to the correct number of sig figs? How many sig figs should your answer have? Density = mass/volume Volume = length x width x height 3.20 g/cm3 = mass/ (10.20 cm x 4.50 cm x 3.2 cm) 3.20 g/cm3 x 146.88 cm3 = 470 g 6) List and describe 5 methods of physical separation of substances. Distillation, chromatography, filtration, crystallography, decanting, magnet, etc. 7) Which device would most accurately measure the volume of a liquid to one decimal place? A 8) Name five properties that a specific material can be identified by (only true for that material). Density, melting point, boiling point, molar mass, etc. 9) The density of 1 gram of feathers is_______________ the density of 1 kg of feathers at the same temperature? a) same as b) greater than c) less than d) can’t be determined 10) Perform the following conversions: a) 5.60 X10-5 g --- kg 5.60 x 10-5 g x 10-3 kg = 5.6 x 10-8 kg 1g b) 0.0060 kl --- ml 0.0060 kL x 1000 mL = 6000 mL 10-3 kL 11) Name the seven diatomic elements. Write their formulas. What does the term “diatomic’ mean? Hydrogen (H2), Oxygen (O2), Nitrogen (N2), Chlorine (Cl2), Bromine (Br2), Iodine (I2), Fluorine (F2) 12) List 5 properties of metals. Where are metals located on the Periodic Table? Where is the most reactive metal located? Conduct heat and electricity, malleable, ductile, luster, solids at room temp. Left of the zig-zag line. Francium 13) List 5 properties of nonmetals. Where are the nonmetals located on the Periodic Table? Where is the most reactive nonmetal located? Brittle, don’t conduct, may be solids, liquids or gases, not ductile, not malleable Right of the zig-zag line Fluorine 14) Name and describe the two main classifications of matter. Pure Substances (elements and compounds) and Mixtures 15) Name any two materials that can be classified as substances and give two ways that they are different from each other. Answers may vary 16) A combination of sugar and water would be classified as a: a) pure substance b) element c) compound d) mixture 17) When 8.0 g of magnesium burns in oxygen gas, what is the mass of magnesium oxide formed? 2Mg + O2 2MgO 8.0 g Mg x 1 mole Mg x 2 mol MgO x 40.31 g MgO = 13 g MgO 24.31 g Mg 2 mol Mg 1 mole MgO 18) What are two types of energy transfer that can occur between a system and its surroundings? Define each and give an example for each. Endothermic Process—Absorbs Energy; A cold pack Exothermic Process—Releases Energy; A fire 19) What is a physical property? Give 5 examples. A quality or condition of a substance that can be observed or measured without changing the substance’s composition. Color, size, shape, density, melting point, etc. 20) What is a chemical property? Give 5 examples. The ability of a substance to undergo a specific chemical change. Flammability, combustible, carcinogen, toxic, etc. 21) What is a physical change defined as? Give 5 examples. A change during which some properties of a material change, but the composition of the material does not change (you can easily return to the original substance). Melting, freezing, cutting, boiling, etc. 22) What is a chemical change defined as? Give 5 examples. A change the produces matter with a different composition than the original matter. Combustion, reacting, precipitating, etc. 23) What are 5 good indications that a chemical change has occurred? Briefly describe each one. Odor, bubbles, energy change, precipitate, etc. 24) What are the three phases (states) of matter (excluding plasma)? Describe each in regard to their volume, shape, kinetic energy, and the spacing of their molecules. Solid—Definite Volume/Definite Shape/Molecules packed together Liquid—Definite Volume/No Definite Shape/Molecules farther apart than solids/Flow Gas—No Definite Volume/No Definite Shape/High Energy/Molecules apart as much as they can 25) Elements are represented by: a) equations b) symbols c) moles d) formulas 26) Compounds are represented by: a) Equations b) symbols c) moles d) formulas 27) Which subatomic particle is involved in a chemical reaction? electrons 28) When metals react they (lose/gain) electrons forming (positive/negative) ions called (cations/anions). 29) When nonmetals react they (lose/gain) electrons forming (positive/negative) ions called (cations/anions). 30) Atoms react to become ___stable____________ like the __noble gases_________ which are in Group VIII or 18. This Group has a full outer shell called an ____octet___________. Since they are stable and do not want to react their oxidation number (charge) is __0____________. 31) Predict the oxidation number (charge) of the following ions: a) Sodium +1 b) Barium +2 c) Aluminum +3 d) Chloride -1 e) Helium 0 32) An atom that loses three electrons will have an oxidation number (charge) of ___+3____________ (give number and sign). 33) An atom that gains two electrons will have an oxidation number (charge) of _____-2__________ (give number and charge). 34) How do the following differ from their neutral atom? a) b) c) d) Bromide gained 1 electron tin (IV) lost 4 electrons magnesium ion lost 2 electrons oxide gains 2 electrons 35) Give the correct formula and oxidation number (charge) for the following polyatomic ions: a) sulfate SO4-2 b) hydroxide OHc) ammonium NH4+ d) chlorate ClO3e) phosphate PO4-3 f) acetate C2H3O2g) nitrate NO3h) carbonate CO3-2 36) What is the oxidation number (charge) of sulfur in SO42-? 37) What is the oxidation number (charge) of phosphorous in H3PO4? -3 38) Give the correct formulas for the following compounds: a) iron (III) sulfide Fe2S3 b) sodium hydroxide NaOH c) copper (II) chloride CuCl2 d) sulfuric acid H2SO4 e) hydrochloric acid HCl f) nickel (IV) sulfate (aq) Ni(SO4)2 39) Give the correct names for the following compounds: a) Ca(OH)2 calcium hydroxide b) HNO3(aq) nitric acid c) Al2O3 aluminum oxide d) PbCl2 lead(II) chloride e) Sn(ClO3)2 tin chlorate f) H2S (g) hydrosulfuric acid 40) What is the characteristic ion present in water solutions of all acids? H+ 41) What is the characteristic ion present in water solutions of all bases? OH42) What are the 5 main reactions types and how do you recognize each type? Synthesis: 1 product Decomposition: 1 reactant Single-Replacement: element + compound element + compound Double-Replacement: compound + compound compound + compound Combustion: O2 is a reactant a) nickel + chlorine --- Ni + Cl2 NiCl2 b) aluminum hydroxide --- 2Al(OH)3 Al2O3 + 3H2O c) magnesium sulfate + sodium hydroxide --- MgSO4 + 2NaOH Na2SO4 + Mg(OH)2 d) calcium + water --- Ca + 2H2O Ca(OH)2 + H2 e) lead + sulfuric acid --- Pb + H2SO4 PbSO4 + H2 f) mercury (II) bromide --- HgBr2 Hg + Br2 g) ammonium hydroxide ---- 2NH4OH (NH4)2O + H2O h) tin (II) carbonate --- SnCO3 SnO + CO2 i) strontium + iron (II) chloride --- Sr + FeCl2 SrCl2 + Fe j) fluorine + potassium iodide --- F2 + 2KI 2KF + I2 43) In a chemical reaction, the name(s) of the material(s) that you start with are called the reactants and appear on the left side of the arrow, 44) In a chemical reaction, the name(s) of the material(s) that you end with are called the products and appear on the right side of the arrow. 45) In a chemical reaction, the mass of reactants should be _______________ mass of the products. a) equal to b) greater than c) less than e) can’t be determined 46) Question # 44 is true due to what law? Law of Conservation of Mass 47) Knowing that all potassium compounds are soluble, and that most hydroxides are insoluble, write the correct word and balanced equation for the addition of an aqueous solution of cobalt (II) sulfate to an aqueous solution of potassium hydroxide. CoSO4(aq) + 2KOH(aq) Co(OH)2(s) + K2SO4(aq) 48) Calculate the total number of atoms in the following compounds: a) Ni3(PO4)4 3 + 4 + 16 = 23 b) (NH4)2SO4 2 + 8 + 1 + 4 = 15 49) Calculate the number of oxygen atoms in 3Al(Cr2O7)3. What is the total number of atoms in 3Al(Cr2O7)3 ? 63 oxygen atoms, 84 total atoms 51) Calculate the number of hydrogen atoms in Ba(OH)2 8H2O. This compound is known as a hydrate (barium hydroxide octahydrate). 18 hydrogen atoms 52) What are the four pieces of information that a coefficient gives you and give conditions, if necessary. Ratio of moles, molecules, atoms or formula units 53) Which of the following represents 4 moles of chlorine a) 4 Cl b) Cl4 c) Cl4 d) 4 Cl2 54) What is the empirical formula for C4H6O4? C2H3O2 55) Name the three subatomic particles, their charge, and their location within the atom. Electron, -1, outside the nucleus Proton, +1, inside the nucleus Neutron, +1, inside the nucleus 56) What is an isotope? Atoms of the same element, with the same number of protons but different numbers of neutrons 57) In what way are carbon - 12 and carbon -14 the same? In what way are they different? Carbon-12 and carbon-14 have the same number of protons, but different numbers of neutrons 58) What is the composition of a nucleus of 131 I? 53 protons, 78 neutrons 59) A monatomic ion containing 18 electrons, 20 protons, and 20 neutrons. What is the charge of this ion? +2 60) Which group contains the same number of electrons? a) O2-, S2-, Se2b) Cl1-, Ar, K1+ c) F, Ne, Na d) Ca2+, Fe2+, Zn261) How many neutrons are present in 131I? 78 62) Combustion of methane occurs according to the following equation: CH4 + 2O2 ---- CO2 + 2H2O How many molecules of water can be produced from 4 moles of methane? 4 moles CH4 x 2 mol H2O x 6.02 x 1023 molecules H2O = 5 x 1024 molecules 1 mol CH4 1 mole H2O 63) When the following chemicals are mixed together in lab, the following results occurred: Powder A B C D Unknown Liquid I bubbles some mixing bubbles some mixing bubbles Liquid II orange color black color bubbles blue color black color What is the identity of the unknown? a) A & B b) A & D c) B & C 64) Given the equation: Pb(NO3)2(aq) + 2NaI(aq) → Liquid III some mixing some mixing bubbles some mixing some mixing d) C & D 2NaNO3(aq) + PbI2(s) Which of the following is the correct net ionic equation for the reaction: a. Pb2+(aq) + 2NO3-(aq) + 2Na+(aq) + 2I-(aq) → 2Na+(aq) + 2NO3-(aq) + PbI2(s) → PbI2(s) c. Pb2+(aq) + 2I-(aq) → PbI2(s) d. 2Na+(aq) + 2NO3-(aq) → 2NaNO3(s) b. Pb2+(aq) + I2-(aq) 65) A sample of sodium metal is available in lab along with water, calcium chloride, and a Bunsen burner. Using any combination of these substances and common lab equipment, suggest a procedure below which will produce at least one new compound. Write a reaction to show how the new compound(s) form(s). Also, identify the formula for the new compound. NOTE: There are several acceptable procedures which will produce different results, but only one needs to be supplied for credit for this answer. 4Na + O2 2Na2O 2Na + 2H2O 2NaOH + H2 66) A student is supplied a sample of an oxide of aluminum. Explain how the number of molecules of aluminum oxide could be determined in this sample. The following equipment is available: Balance, ruler, calculator, pencil, funnel, periodic table and beaker. Measure the mass of aluminum oxide using a balance. Use molar conversions to convert to molecules. 67) Explain how a student could separate any mixture of dyes, such as the mixtures used to obtain markers, pens, or food dyes. Be sure to describe what supplies and equipment might be necessary. Also, what property (or properties) of the dyes allow for the separation. Chromatography