Predicting Reactions AP Style Practice Writing Equations for Reactions: Write the equation for each reaction in net ionic format. There is a reaction in each case. Do not balance. LINK TO ANSWERS AT END OF PRACTICE. 1. Sodium sulfite crystals are added to water. 2. Solid potassium dichromate is added to an aqueous solution of lead (II) nitrate. 3. Calcium carbonate chips are added to excess nitric acid. 4. Hydrogen sulfide gas is bubbled through a solution of cadmium nitrate. 5. Solutions of acetic acid and sodium carbonate are mixed. 6. Hydrogen chloride gas is bubbled through water. 7. Solutions of carbon dioxide gas and ammonia gas are mixed. 8. Solid lithium oxide is added to water. 9. Sulfur trioxide gas is bubbled through a solution of sodium hydroxide. 10. A mixture of the solid calcium oxide and solid tetraphosphorous decaoxide is heated. 11. Solid magnesium carbonate is heated in a crucible. 12. Solid phosphorus trichloride is added to water. 13. Solid sodium cyanide is added to water. 14. Solid zinc nitrate is treated with excess sodium hydroxide solution. 15. An aqueous solution of diamminesilver chloride is treated with dilute nitric acid. 16. A suspension of copper(II) hydroxide in water is treated with an excess of ammnonia 17. Gaseous boron hydride gas is mixed with ammonia gas 18. Boron trifluoride is added to gaseous trimethylamine 19. Gaseous silane (SiH4) is burned in excess oxygen. 20. Magnesium ribbon is burned in pure nitrogen gas. 21. An aqueous hydrogen peroxide solution is added to an acidified solution of potassium iodide. 22. Dilute potassium permanganate solution is added to an oxalic acid solution which was acidified with a few drops of sulfuric acid. 23. A solution containing tin (II) ion is added to acidified potassium dichromate. 24. A segment of copper wire is added to dilute nitric acid. 25. Sodium dichromate solution is added to acidified solution of sodium iodide. 26. Sodium hydride crystals are added to water. 27. Powdered iron is added to a solution of iron (II) sulfate. 28. Chlorine gas is bubbled through a solution of potassium bromide. 29. Solid sodium is added to water. 30. A dilute solution of sulfuric acid is electrolyzed between platinum electrodes. ANSWERS TO PREDICTING EQUATIONS 1. Na2SO3 + H2O Na+ + HSO3- + OH- soluble salt forms a weak base SO3- ( anion from weak acids) Hydrolysis 2. Cr2O7 + Pb2+ PbCr2O7 double displacement forms precipitant 3. CaCO3 + H+ Ca2+ + CO2 + H2O double displacement gas forming carbonic acid decomposes in water to form water and carbon dioxide 4. Cd2+ + H2S CdS + H+ displacement forming a precipitant 5. HC2H3O2 + HCO3- C2H3O2- + CO2 + H2O displacement acid- base 6. HCl + H2O H3O+ + Cl- displacement acid-base 7. CO2 + H2O + NH3 NH4+ + HCO3- carbonic acid in water write carbon dioxide and water displacement acid-base 8. Li2O + H2O Li+ + OH- metal oxides and water form metallic hydroxides combination 9. SO3 + OH- HSO4- combination nonmetal oxide and water form nonbinary acids 10. CaO + P4O10 Ca3(PO4)2 combination metal oxide and nonmetal oxide forms nonbinary salt 11. MgCO3 MgO + CO2 decomposition 12. PCl3 + H2O H+ + Cl- + H3PO3 hydrolysis does not fit pattern exactly 13. NaCN + H2O HCN + Na+ + OH- hydrolysis CN- is a base because it is an cation from a weak acid 14. Zn(NO3)2 + OH- Zn(OH)42- + NO3- formation of complex ion ~ key words "excess sodium hydroxide" 15. Ag(NH3)+ + Cl- + H+ AgCl + NH4+ breakup of complex ion achieved by adding an acid that reacts with the basic ligand 16. Cu(OH)2 + NH3 Cu(NH3)42+ + OH- formation of complex ion ~ key word "excess ammonia" 17. BH3 + NH3 BH3NH3 Lewis acid base ~ coordinate covalent bond 18. BF3 + (CH3)3N F3BN(CH3)3 Lewis acid base ~ coordinate covalent bond 19. SiH4 + O2 SiO2 + H2O combustion forms oxides of elements 20. Mg + N2 Mg3N2 synthesis, combination 21. H2O2 + H+ + I- H2O + I2 redox 22. MnO4- + H+ + H2C2O4 Mn2+ + CO2 +H2O redox 23. Sn2+ + H+ Cr2O72- Sn4+ + Cr3+ + H2O redox remember to add H2O to have H’s and O's on both sides of the equation 24. Cu + H+ + NO3- Cu2+ + NO + H2O redox 25. Cr2O7 2- + H+ + I- Cr3+ + I2 + H2O redox 26. NaH + HOH Na+ + OH- + H2 metal hydrides react with water to form metallic hydroxides and hydrogen 27. Fe + Fe3+ Fe2+ redox intermediate ox state 28. Cl2 + Br- Cl- + Br2 single displacement nonmetal displaces nonmetal 29. Na + HOH Na+ + OH- + H2 single displacement metal displaces metal 30. H2O H2 + O2 electrolysis