Name ___________________________ Block _____ Date ________ Chapter 3 & 4 Test Review AP Chemistry Directions: Each set of lettered choices below refers to the numbered statements immediately following it. Select the one lettered choice that best fits each statement and then fill in the corresponding oval on the answer sheet. A choice may be used once, more than once, or not at all in each set. 1) A chemical reaction is a process in which a) reactants change into products b) substances with new chemical and physical properties are formed c) the law of conservation of mass applies d) all of the above 2) Carbon – 12 is the standard isotope for expressing the ___________ of the elements. a) nuclear charge b) atomic mass c) atomic number d) ion distribution e) molarity 3) What number of atoms of O are in 4.2 mol of P 4O10? (Molecular weight P4O10 = 284) a) 2.52 X 1023 b) 2.52 X 1024 c) 2.52 X 1025 d) 6.98 X 10-24 e) 6.98 X 10-25 4. When the equation, C4H10 + O2 CO2 + H2O is balanced with the smallest set of integers, the sum of the coefficients is a. 4 b. 28 c. 33 d. 15 5. Baking powder, a mixture of cream of tartar (KHC4H4O6, molar mass 188 g/mol) and baking soda (NaHCO3, molar mass 84.0), undergoes the following reaction at baking temperatures: KHC4H4O6 + NaHCO3 KNaC4H4O6 + H2O + CO2 (The CO2 makes the cake rise.) A recipe calls for two level teaspoons (a total of 8.0 g) of cream of tartar. How much baking soda must be added for both materials to react completely? a. 0.45 g b. 3.6 g c. 18 g d. 8.0 g 6. Consider the following unbalanced equation: KO2 + H2O KOH + O2 + H2O2 For every 3.0 mol of KO2, ______ mol of H2O is needed for a complete reaction. a. 1.0 b. 2.0 c. 3.0 d. 6.0 7. How many moles of P4 molecules are there in 143.8 g of phosphorus? a. 0.2154 mol b. 0.8615 mol c. 1.161 mol d. 4.643 mol 8. What is the subscript of aluminum in the formula for aluminum phosphate? a. 1 b2 c. 3 d. 4 9. In the reaction 2 A + B 3 C + D, 3.0 mol A and 2.0 mol B react to form 4.0 mol C. What is the percent yield of this reaction? a. 50% b. 67% c. 75% d. 89% 10. Determine the concentration of a solution made by dissolving 10.0 g of sodium chloride in 750.0mL solution. a. 0.0133 M b. 0.133 M c. 0.171 M d. 0.228 M 11. What volume of 2.00 M sodium hydroxide is required to prepare 150.0 mL of 0.800 M NaOH? a. 375 mL b. 150. mL c. 120. mL d. 60.0 mL 12. How many grams of solute are contained in 141 mL of a 0.175 M silver nitrate solution? a. 6.85 g b. 4.19 g c. 0.145 g d. 3.80 g 18. What volume of 0.25 M HNO3 is necessary to react exactly with 7.4 g of Ca(OH)2? a. 2.0 × 102 mL b. 2.5 × 102 mL c. 4.0 × 102 mL d. 8.0 × 102 mL 13. An unknown substance is 49.32% C, 6.85% H, and 43.84% O by mass. What is its empirical formula? a. C3H5O2 b. C3H3O4 c. C2HO3 d. C2H5O4 15. Lead(II) nitrate reacts with sodium chloride in aqueous solution to form a precipitate. What is the net ionic equation for this reaction? a. Pb2+(aq) + 2NO3-(aq) Pb(NO3)2(s) b. Na+(aq) + Cl-(aq) NaCl(s) c. Pb2+(aq) + 2Cl-(aq) PbCl2(s) d. Na+(aq) + NO3-(aq) NaNO3(s) 16. When aqueous sodium hydroxide is added to aqueous nitric acid, what is the balanced molecular equation for the reaction that takes place? a. 2 NaOH(aq) + H2NO3(aq) Na2NO3(aq) + 2H2O(l) b. Na(OH)2(aq) + H2NO3(aq) Na2NO3(aq) + 2 H2O(l) c. NaOH(aq) + HNO3(aq) NaNO3(aq) + H2O(l) d. NaOH(aq) + HNO4(aq) NaNO4(aq) + H2O(l) 17. Magnesium metal reacts with hydrochloric acid to form aqueous magnesium chloride and hydrogen gas. When 3.65 g of magnesium is added to 50.0 mL of 3.00 M hydrochloric acid, what mass of hydrogen is produced assuming a complete reaction? a. 0.123 g b. 0.151 g c. 0.246 g d. 0.302 g 23. A 6.32-g sample of potassium chlorate was decomposed according to the following equation: 2 KClO3 2KCl + 3O2 How many moles of oxygen are formed? a. 1.65 g b. 0.051 moles c. 0.0344 moles d. 0.0774 moles 24. How many grams of H2O will be formed when 32.0 g H2 is mixed with 32.0 g O2 and allowed to react to form water? a. 36.0 g b. 288 g c. 18.0 g d. 64.0 g 25. To calculate the concentration in moles per liter of a salt solution, you need to know a. the mass of the salt added to the solution and the volume of water added to the solution. b the mass of the salt added to the solution and the total volume of the solution. c. the mass of the salt added, the molar mass of the salt, and the total volume of the solution. d. the molar mass of the salt and the total volume of the solution. CLEARLY SHOW THE METHOD USED AN STEPS INVOLVED IN ARRIVING AT YOUR ANSWERS. It is to your advantage to do this, because you may earn partial credit if you do and you will receive little or no credit if you do not. Attention should be paid to significant figures. 1) A sample of aluminum chloride is made by reacting scrap 3.5 g aluminum with 5.6 g chlorine gas. i) Write the balanced chemical equation for the reaction. ii) Determine how many grams of the product are produced? 2) In a titration experiment, 12.55 mL of 0.520 M KOH is used to titrate 25.00 mL of H2SO4. i) Write a balanced equation for this reaction ii) Determine the molarity of the sulfuric acid. ANSWERS 1d 2b 3c 4c 5b 6c 7c 8a 9d 10d 11d 12b 13a 15c 16c 17b 18d 23d 24c 25c 1) A sample of aluminum chloride is made by reacting scrap 3.5 g aluminum with 5.6 g chlorine gas. i) Write the balanced chemical equation for the reaction. ii) Determine how many grams of the product are produced? 2) In a titration experiment, 12.55 mL of 0.520 M KOH is used to titrate 25.00 mL of H2SO4. i) Write a balanced equation for this reaction ii) Determine the molarity of the sulfuric acid.