Practice Test H.1 (pg 1 of 6) 1. 2. 3. 4. 6. (Ch 6, 7, and 21) • This is practice - Do NOT cheat yourself of finding out what you are capable of doing. Be sure you follow the testing conditions outlined below. • DO NOT USE A CALCULATOR. You may use ONLY the blue periodic table. • Try to work at a pace of 1.2 min per question. Time yourself. It is important that you practice working for speed. • Then when time is up, continue working and finish as necessary. Of the following transitions in the Bohr hydrogen atom, the _________ transition results in the emission of the shortest wavelength photon. a. n = 1 to n =6 b. n = 6 to n = 1 c. n = 6 to n = 3 d. n = 2 to n = 1 e. n = 1 to n = 4 There are __________ possible values for the magnetic quantum number (mL, 3rd quantum #) of an electron in 5f subshell. a. 1 b. 5 c. 7 d. 10 e. 14 In a px orbital, the subscript x denotes the _______ of the electron. a. energy b. spin of the electrons c. probability of the shell d. size of the orbital e. axis along which the orbital is aligned Which sketch represents an orbital with the quantum numbers n = 3, l = 0, and mL = 0 ? a 5. Electrons, Periodicity, and Nuclear b c d e How many electrons in an atom can possess the a principal quantum number of n = 3 a. 3 b. 6 c. 8 d. 10 e. 18 An electron can NOT have which set of the following quantum numbers n = __, l = __, mL = ___ . a. 6, 1, 0 b. 3, 2, 3 c. 3, 2, -2 d. 1, 0, 0 e. 3, 2, 1 7. How many p-orbitals are filled in a Kr atom? a. 3 b. 6 c. 9 d. 18 e. 27 8. How many unpaired electrons are in the iron atom a. 0 b. 2 c. 3 d. 4 e. 8 9. Which of the following is not a valid set of four quantum numbers? (n, l ,ml, ms) a. 2, 0, 0, +½ b. 2, 1, 0, −½ c. 3, 1, −1, −½ d. 1, 0, 0, +½ e. 1, 1, 0, +½ 10. [Ar]4s23d104p3 is the electron configuration of a(n) ______ atom. a. As b. V c. P d. Sb e. Sn 11. How many unpaired electrons are in the Ni2+ ion? a. 0 b. 2 c. 3 d. 4 e. 6 12. List the following species in order from smaller to larger size (radii). a. Se2− < Kr < Rb+ b. Kr < Se2− < Rb+ c. Rb+ < Kr < Se2− d. Rb+ < Se-2 < Kr e. They are all the same size. 13. All of the ________ have a valence shell electron configuration of ns2 a. noble gases b. halogens c. chalcogens d. alkali metals e. alkaline earth metals Unit H.1 Practice Test (pg 2 of 6) Electrons, Periodicity, and Nuclear (Ch 6, 7, & 21) 14. The elements in the ______ period of the periodic table have a core-electron configuration that is the same as the electron configuration of neon. a. first b. second c. third d. fourth e. fifth 15. Pick the graph below that best represents the relationship between energy and wavelength of light. E E E λ λ a b E λ E λ c λ d e 21. The ground state electron configuration of a highly reactive metal is a. a b. b c. c d. d e. e 22. The largest principal quantum number in the ground state electron configuration of iodine is _______ a. 1 b. 4 c. 5 d. 6 e. 7 Use the choices below to answer the next 6 questions a. 1s22s22p63s23p64s23d104p65s1 b. 1s22s22p63s23p5 c. 1s22s22p63s23p64s23d8 d. 1s22s22p63s23p64s23d104p6 e. 1s22s22p33s1 23. Identify the element whose 3+ ion has the following electron configuration: [Xe] 4f14 5d3 a. W b. Lu c. Ta d. Nb e. Y 16. The ground state electron configuration of a transition metal is a. a b. b c. c d. d e. e 24. In a multi-electron atom, how many electrons can have the quantum numbers: n = 4, l = 1, mL = −1 a. 1 b. 2 c. 6 d. 10 e. 0, this is not a valid set of 3 numbers 17. An electron configuration of an excited atom is a. a b. b c. c d. d e. e 25. In copper, which of the following electrons, characterized by the four quantum numbers, has the lowest energy? a. n = 4, l = 0, mL = 0, ms = −½ b. n = 3, l = 2, mL = 0, ms = +½ c. n = 3, l = 1, mL = −1, ms = +½ d. n = 3, l = 1, mL = 0, ms = −½ e. electrons c and d are degenerate and are of the same energy. 18. The ground state electron configuration of an element with the smallest number of valence electrons is a. a b. b c. c d. d e. e 19. The ground state electron configuration of a chemically un-reactive element is a. a b. b c. c d. d e. e 20. The ground state electron configuration of an element that forms a -1 ion is a. a b. b c. c d. d e. e 26. To remove which electron from gallium would you expect an extraordinarily high increase in successive ionization energy? a. 2nd b. 3rd c. 4th d. 5th e. none, all successive ionization energies increase steadily 27. To remove the second electron from which would you expect an extraordinarily high increase in the second successive ionization energy? a. Ca b. K c. Ga d. Ge e. Se Unit H.1 Practice Test (pg 3 of 6) Electrons, Periodicity, and Nuclear (Ch 6, 7, & 21) 28. Which of the following correctly represents the second ionization of phosphorus? a. P + e- → P− b. P + P−1 → e− c. P + P+ → e− d. P+ → P+2 + e− e. P+ + e− → P 35. Which of the following sets contains species that are isoelectronic? a. Br, Kr, Rb b. O2−, S2−, Se2− c. Al3−, S2−, Ar d. Cl+, Ar, K− e. F−, Ne, Na+ 29. The electron configuration of the ground state for the Ag atom is an exception to the electron-filling rules. Which configuration below is most likely to represent Ag. a. [Ar] 4s24d9 b. [Kr] 5s14d10 c. [Kr] 5s23d9 d. [Ar] 4s14d10 e. [Kr] 5s24d10 36. In general, as you go across a period in the periodic table from left to right: the atomic radius ______, the electron affinity becomes ______ negative, and the first ionization energy ______. a. decreases, decreasingly, increases b. increases, increasingly, decreases c. increases, increasingly, increases d. decreases, increasingly, increases e. decreases, decreasingly, decreases 30. Which equation correctly represents the electron affinity of sulfur? a. S + e− → S− + EA b. S + EA→ S+1 + e− c. S → S− + e− + EA d. S− + EA → S + e− e. S+ + e− → S + EA 37. Use the choices below to answer 4 questions a. [Kr] 5s1 b. [Ne] 3s23p1 c. [Ar] 4s23d104p4 d. [Ne] 3s23p6 e. [Ar] 4s1 31. The atom with the largest atomic radius is ________ a. a b. b c. c d. d e. e 32. The electron configuration of the two atoms that will form isoelectronic ions are a. a + c b. b + c c. c + d d. b + e e. a + e 33. The electron configuration of the atom that is expected to have the highest first ionization energy is _______ a. a b. b c. c d. d e. e 34. The electron configuration of the atom that is expected to form a stable 2− ion is ______ a. a b. b c. c d. d e. e 131I has a half-life of 3.5 days. Assuming you start with an 8.0 g sample, what mass will remain after two weeks? a. 4.0 g b. 2.4 g c. 2.0 g d. 1.0 g e. 0.5 g 38. Which reaction below best represents the transmutation that occurs inside the nucleus during beta decay? a. 11p → 10n + 0−1e b. 11p → 10n + 0+1e c. 10n → 11p + 0+1e d. 10n → 11p + 0−1e e. 10n → 11n + 0−1e 39. A sample of radioactive cadmium has a half life of 15 days. If you have a sample that originally weighed 40 g and later weighs 2.5 g. How much time elapsed between the initial and final masses? a. 600 days b. 100 days c. 60 days d. 45 days e. 37.5 days 40. Which one of the following processes results in an increase in the atomic number? a. gamma emission b. positron emission c. beta emission d. alpha emission e. electron capture 41. Fill in the blank in the following nuclear equation 252 Cf + 10 B → 259 Lr + _____ 98 5 103 a. 5 0-1e b. 3 10n c. 3 11p d. 3 0+1e e. 5 10n Unit H.1 Practice Test (pg 4 of 6) Electrons, Periodicity, and Nuclear (Ch 6, 7, & 21) 42. An element that participates in electron capture could accomplish the same transmutation by a. positron emission b. alpha emission c. beta emission d. alpha and beta occurring together e. neutron emission 43. Make the selection that correctly fills in the three blanks in the equation below. 27 ____Si → 27 13 _____ + _____ a. 14, Al, 0+1e b. 28, P, 0+1e c. 13, Al, 0-1e d. 14, Al, 0-1e e. there is not enough information to identify all of the three blank 44. What is the mass number of a neutron? a. 0 b. 1 c. 2 d. 3 e. 4 45. In balancing the nuclear reaction 238 U → X + 4 He 92 2 What is the identity of element X?. a. Pu b. Np c. Th d. U e. Pa 49. Tritium decays by a first-order process that has half-life of 12.5 years. How many years will it take to reduce the radioactivity of a tritium sample to 15% of it original value? a. 64 yrs b. 54 yrs c. 34 yrs d. 24 yrs e. 14 yrs 50. For a first order reaction that has a half-life of 69 s at 80°C, the value of the rate constant, k, is closest to? a. 0.01 s−1 b. 0.1 s−1 c. 1 s−1 d. 10 s−1 e. 100 s−1 51. If the half-life of a reaction is independent of concentration, what is the order of the reaction? a. zero b. first c. second d. half-life is unrelated to the order of the reaction e. unable to be determined without knowing starting concentrations 52. Which species contains the most neutrons? a. 5926Fe3+ b. 5626Fe c. 6029Cu d. 6130Zn e. 6030Zn+2 46. Identify the type of decay that the radioactive nuclide, 88Rb is likely to participate in? a. alpha b. positron c. beta d. electron capture e. either c or d 53. Which type of radiation changes both the atomic number and mass number of the emitting atom? a. alpha b. beta c. gamma d. positron e. electron capture 47. The reaction below is an example of 38 Ca → 3819K + _______ 20 a. alpha decay b. beta decay c. electron capture d. positron decay e. nuclear transmutation 54. Which represents the 235U atom? 48. Radium undergoes alpha decay. The product of this reaction also undergoes alpha decay. What is the product of this second decay reaction ? a. Rn b. U c. Th d. Hg e. Po Protons Electrons Neutrons (A) 46 46 143 (B) 46 46 92 (C) 92 92 143 (D) 92 92 146 (E) 92 92 235 55. A particular nuclear decay has a rate constant of 0.00346 min−1 What is the half-life? a. 3.3 hours b. 1.6 hours c. 0.0012 min d. 0.0024 min e. 0.0050 min Unit H.1 Practice Test (pg 5 of 6) Electrons, Periodicity, and Nuclear (Ch 6, 7, & 21) 56. The half-life of 14C is 5570 years. How many years will it take for 90% of a sample to decompose? a. 5,013 years b. 11,000 years c. 18,600 years d. 23,000 years e. 50,130 years 57. The half-life of 99Tc is 6.00 hours. If it takes exactly 12.00 hours for the manufacturer to deliver a 99Tc sample to a hospital, how much must be shipped in order for the hospital to receive 10.0 mg? a. 40.0 mg b. 30.0 mg c. 20.0 mg d. 15.0 mg e. 4.0 mg 58. An atom of phosphorus-28, 29P, contains a. 15 electrons, 15 protons, 16 neutrons. b. 15 electrons, 15 protons, 15 neutrons. c. 15 electrons, 15 protons, 14 neutrons. d. 15 electrons, 15 protons, 29 neutrons. e. 15 electrons, 15 protons, 29 neutrons. Practice Test H.1 (pg 6 of 6) 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. 14. 15. 16. 17. 18. 19. 20. 21. 22. 23. 24. 25. 26. 27. 28. 29. 30. 31. 32. 33. 34. 35. 36. 37. 38. 39. 40. 41. 42. 43. 44. 45. 46. 47. 48. 49. 50. 51. 52. 53. 54. 55. 56. 57. 58. b c e a e b c d e a b c e c b c e a d b a c a b e c b d b a a a d c e d e d c c b a a b c c d e c a b a a c a c a c Electrons, Periodicity, and Nuclear (Ch 6, 7, and 21) ANSWERS