Metals, Nonmetals or Metalloids? Rebecca Pittman, Educator, Mathematics & Science Center Developed with funding from the Mathematics & Science Center as part of the course, Chemistry for Middle School Teachers, Summer 2004. Curriculum Physical Science, Chemistry Elements in the periodic table can be divided into three categories: metals, nonmetals, and metalloids (semimetals). Metals make up approximately 75% of the elements on the periodic table and have the following physical properties: metallic shine or luster; usually solid at room temperature; can be hammered, pounded, or pressed into different shapes without breaking; can be drawn into thin sheets or wires without breaking; conduct heat and electricity; and usually show a reaction with acids. The 17 nonmetal elements have the opposite physical properties: seldom have a luster; often gases at room temperature; those present as solids at room temperature can not be hammered or drawn without breaking; poor conductors of heat and electricity. The 6 metalloids have properties that lie between these extremes: often look like metals but are brittle; neither conductors nor insulators but make excellent semiconductors. Key Concepts Overview Materials Elements are classified as either metals or nonmetals based on measurements of chemical and physical properties. conductivity apparatus*1 element samples*2 2.0M hydrochloric acid*3 microscale plates*4 Safety Follow normal classroom safety rules. Safety goggles must be worn while working with the acid solution. Time 50 minutes Grouping Groups of 2 or 3 work well for this activity. Procedure 1. Record the sample identity and observations for the first two columns “Metals, Nonmetals or Metalloids” 1 http://mathinscience.info in the data table for each sample to be tested. 2. Use the nail and rubber hammer provided to test each sample’s malleability. Place the nail in contact with the sample and hit the head of the nail several times with the hammer. If a sample is malleable it can be hammered, pounded, or pressed into different shapes without breaking. Record “yes” or “no” in the “Malleability” column. 3. Place a small sample of each element in a different well in the microscale plate. Test each sample’s ability to conduct an electric current by placing both wires of the conductivity meter in contact with the sample’s surface. If the meter’s light comes on, it is an indication that the sample is a conductor of electricity. 4. Cover each element sample with 2.0M HCl by filling the well with this solution. Observe for at least 2 minutes. Note any changes that occur. Compare the rate of formation of any gases by observation of bubble formation. 5. Fill in the table below based on your observations and the background information given under “Key Concepts”. Sample Identity “Metals, Nonmetals or Metalloids” Color Metallic Luster? (Y or N) 2 Malleable (Y or N) Conducts Electricity? (Y or N) Reacts with HCl? (Y or N) Explain Metal Nonmetal or Metalloid? http://mathinscience.info Assessment 1. Which bulb below (a or b) represents a positive test for a metal? Explain your answer. 2. Which material below is most likely to be a nonmetal? Explain your answer. 3. Which test tube represents a positive HCl test for a metal? Explain your answer. 4. What is a disadvantage of using a test such as the reaction with HCl? 5. How does this lab relate to the arrangement of elements on the periodic table? Resources A Periodic Table of the Elements http://periodic.lanl.gov/default.htm A periodic table resource for elementary, middle and high school students provided by the chemistry division at Los Alamos National Laboratory that includes an “ask a chemist” option. Metallic Structures http://www.chemguide.co.uk/atoms/structures/metals.html This page describes the structure of metals, and relates that structure to the physical properties of the metal. Nonmetals http://library.thinkquest.org/3659/pertable/nonmetal.html A general discussion of the nonmetals that includes the option to learn more detail about each one of them. Physical and Chemical Properties http://www.iun.edu/~cpanhd/C101webnotes/matter-and-energy/properties.html This site provides definitions of physical and chemical properties with examples. “Metals, Nonmetals or Metalloids” 3 http://mathinscience.info Physical or Chemical Change http://www.edinformatics.com/math_science/p_chem_change.htm This site offers definitions, examples, and an assessment to test your understanding. Proton Don http://www.funbrain.com/periodic/ Learn element names and symbols using this online interactive resource. Teacher Notes/ Advance Preparation *1The conductivity apparatus can be assembled using the instructions below or purchased through a scientific education vendor. Materials needed for each conductivity meter: Two 1.5 volt, AAA batteries; One LED (Light Emitting Diode may be purchased at a local electronics store); One 0.5-inch inside diameter, 4.5-inch long PVC pipe; one approximately 6-inch length of 18 gauge solid insulated copper wire Assembly: Connect the two batteries in series (positive to negative) by placing the two batteries side by side facing in opposite directions and soldering a small length of the copper wire from the positive end of one battery to the negative end of the other. Once the solder has solidified, bend the wire so that the two batteries form a straight line. Clip the positive lead of the LED (the longer lead) to a 0.75-inch length of the copper wire. Solder the free end of the wire to the exposed positive terminal of the battery. Solder a 4-inch length of the copper wire to the negative lead of the LED and route it past the two batteries connected in series. Solder a 1.5-inch length of the copper wire to the exposed negative end of the battery. Slide the battery assembly into the plastic pipe so that the LED protrudes slightly from one end and the free ends of the two copper wires protrude from the other end. Fill the ends of the pipe with silicone or with a hot glue gun. Strip a 0.25-inch section on the exposed ends of the copper wire of insulation. When the two exposed wires are placed in contact with a conductor the LED will glow. The intensity of the light will depend on the strength of the conductor. *2 Samples may be placed in capped vials for student distribution. Sample suggestions: carbon, sulfur rolls, aluminum foil, mossy zinc, “Metals, Nonmetals or Metalloids” 4 http://mathinscience.info calcium, copper, lead, magnesium, iron filings, and mossy tin. *3Concentrated HCl is 12M. 250 mL of 2.0M HCl may be prepared by diluting 41.6 mL of concentrated HCl to a total volume of 250 mL with distilled water. Remember to control the exothermic reaction by adding acid to water. Measure approximately 150mL of distilled water into a 250 mL volumetric flask ( or a graduated cylinder will work fine for this solution). Gradually add the measured amount of concentrated acid to the water with swirling. After all the acid has been added, fill to the 250 mL mark with distilled water. Dispense the acid in dropper bottles. *4Small test tubes may be substituted for the microscale plates. The data sheet for this activity can be used as part of the evaluation. Assign answers in each of the first three categories a value of one point. Answers for conductivity and “metal, nonmetal or metalloid” may be assigned a value of 3 points. The column for reaction with HCl is usually not graded because the bubbles of gas are sometimes very difficult to observe. Advise students that a change in the appearance of the metal can also indicate a reaction is occurring. Answers in the last column should be based on actual experimental data which may or may not be correct. Emphasize the importance of repeated trials and the need to change variables before drawing final conclusions. “Metals, Nonmetals or Metalloids” 5 http://mathinscience.info