SCH4U Organic Chemistry Test Format and Key Concepts Test Date: Tuesday, February 26, 2013 Format (This format may change) Section Question Type Number of Marks I Multiple Choice 15 II Matching (Definitions) 10 III Diagrams (Nomenclature, etc.) 20-30 IV Short Answer 25 Total 70-80 The test will incorporate aspects from each of the four categories from the achievement chart: • Knowledge and Understanding (mostly in Multiple Choice and Matching) • Thinking and Investigation (Short Answer) • Communication (will be found in both Diagrams and Short Answer) • Application (One or two questions in the Short Answer section) Key Concepts 1. Organic Compounds and Isomers a. What is an organic compound? b. Why is carbon such an important building block in organic chemistry? c. What is the difference between a constitutional isomer and a stereoisomer? d. Briefly explain the difference between a diastereomer and an enantiomer. Provide examples of each type. e. Can you explain cis and trans isomerism? 2. Hydrocarbons a. What is a hydrocarbon? b. What is the difference between an aliphatic and an aromatic hydrocarbon? c. What is the difference between an alkane, alkene, and alkyne? d. What are functional groups? 3. Naming a. You should be able to identify and properly name the following types of organic compounds: i. Alkanes, Alkenes, and Alkynes ii. Cycloalkanes and Cycloalkenes iii. Aromatic hydrocarbons (benzene rings) iv. Alkyl Halides (Haloalkanes) v. Alcohols vi. Ethers vii. Amines viii. Aldehydes ix. Ketones x. Carboxylic Acids xi. Esters xii. Amides 4. Physical Properties and Forces Between Molecules a. What is hydrogen bonding? How can you predict if hydrogen bonding will occur? b. What are dipole-dipole interactions? c. What are dispersion forces? d. How can you determine the properties of various organic compounds simply by knowing their structure? How does hydrogen bonding influence a compound’s behaviour? What about dispersion forces? e. Using your knowledge of intermolecular forces, can you determine which types of organic compounds are more likely to have higher boiling points than others? 5. Functional Groups a. What are the characteristics of the various functional groups that we discussed in class? (i.e. What is the polarity of the functional group? What kind of hydrogen bonding is occurring? What is the solubility in water? What are their relative melting and boiling points? b. How do the various physical properties of various organic compounds compare with one another? 6. Reactions of Functional Groups a. What are the differences between addition, elimination, and substitution reactions? b. What are the main reactions associated with alkenes and alkynes? c. What is Markovnikov’s rule? d. What are oxidation and reduction reactions? How can you identify them? e. How are condensation and hydrolysis reactions related? f. How is the oxidation of a primary alcohol different from the oxidation reactions of both secondary and tertiary alcohols? g. What are the reactions associated with aldehydes and ketones? h. What is an esterification reaction? 7. Polymers and Biomolecules a. What is a polymer? Can you name any examples? b. What is a monomer? Can you name any biological monomers that are extremely important to humans? c. What is a plastic? d. Briefly explain the process involved in an addition polymerization. What types of monomers are typically involved? e. What happens in a condensation polymerization? What are the products called if the condensation polymers contain amide bonds? What are the products called if the condensation polymers contain ester bonds? Textbook Review It is probably a good idea to look at the many practice problems in chapters 1 and 2. Chapter 1 review questions – pages 87-93 Chapter 2 review questions – pages 137-143 Unit 1 review questions – 147-155