SCH 4UI - Organic Nomenclature Review Assignment II Aldehydes, Ketones, Carboxylic Acids, Esters, Amines, and Amides A. 1 Name the following organic molecules and the family to which they belong. 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 B. Draw the structure of each organic compound and state which family they belong to: 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. butanal 3-heptanone 4-methyl-3-pentenal ethyl propanoate 1-aminopropane N-methyl propanamide 4-aminohexanoic acid ethyl-2-butenoate 4-hexenoic acid (glycerol) 1,2,3-propanetriol methoxypropane N-isopropyl-1aminobutane C. Complete the following reactions by: a) drawing the structures for the reactants and products b) indicating the conditions required for each reaction to proceed c) stating the chemical family of the product 1. 3. 5. 7. 1-butanol + (O) → 5-ethyl-3,4-dimethyl-1-octene 2-propanol + (O) → propanoic acid + N-ethyl-1-aminomethane D. State how you would synthesize each of the following compounds. (no structures are required) a) Indicate the reactants b) State the conditions required for the reaction to proceed 1. 3. 5. ethyl propanoate 3-pentanone N-methyl butanamide E. In which family do the following common compounds belong: 1. 4. cortisone formaldehyde F. State why the following names are incorrect: 1. 4. 1-butanone 2. propoxyetane N-methyl-N-ethyl-2-aminopropane 5. G. You are an organic chemist and are being asked to synthesize organic compounds. Your lab is equipped with heat sources and any oxidizing agent or catalyst you might need. Draw the reaction pathways needed to synthesize each compound. Number each step and be sure to include catalysts or oxidizing agents used. You do not need to draw structures. 1. 2. synthesize ethoxypropane starting from alkenes synthesize an amide starting from an alcohol and/or alkenes. 13. 14. 15. 16. 17. 18. 19. 20. 21. 22. 23. 24. 5-ethyl-2-methyl-4-hydroxy-3-heptanone butyl ethanoate propylamine formic acid N-ethyl-N-methyl butanamide 1,3-diaminobenzene ethyl benzoate 3-ethyl-1,4-diaminobenzene N,N-diethyl-1-aminobutane N-ethyl-N,3-dimethylbutanamide 2-methyl-3,4-dimethyl-1-aminohexane propyl methanoate 2. 4. 6. 8. 2. 4. 6. 2. 5. lactic acid epinephrine hexanoic acid + ethanol → ethanal + (O) → butanone + H2 → acetic acid + butanol → butanoic acid hexanal aminoethane 3. 6. acetylsalicylic acid (ASA) caffeine 3. 1,3-dibutanol 3-methyl-1-pentenoic acid