Nomenclature Review (1.6

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SCH 4UI - Organic Nomenclature Review Assignment II
Aldehydes, Ketones, Carboxylic Acids, Esters, Amines, and Amides
A.
1
Name the following organic molecules and the family to which they belong.
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
B.
Draw the structure of each organic compound and state which family they belong to:
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
butanal
3-heptanone
4-methyl-3-pentenal
ethyl propanoate
1-aminopropane
N-methyl propanamide
4-aminohexanoic acid
ethyl-2-butenoate
4-hexenoic acid
(glycerol) 1,2,3-propanetriol
methoxypropane
N-isopropyl-1aminobutane
C.
Complete the following reactions by:
a)
drawing the structures for the reactants and products
b)
indicating the conditions required for each reaction to proceed
c)
stating the chemical family of the product
1.
3.
5.
7.
1-butanol + (O) →
5-ethyl-3,4-dimethyl-1-octene
2-propanol + (O) →
propanoic acid + N-ethyl-1-aminomethane
D.
State how you would synthesize each of the following compounds. (no structures are required)
a)
Indicate the reactants
b)
State the conditions required for the reaction to proceed
1.
3.
5.
ethyl propanoate
3-pentanone
N-methyl butanamide
E.
In which family do the following common compounds belong:
1.
4.
cortisone
formaldehyde
F.
State why the following names are incorrect:
1.
4.
1-butanone
2.
propoxyetane
N-methyl-N-ethyl-2-aminopropane
5.
G.
You are an organic chemist and are being asked to synthesize organic compounds. Your lab is
equipped with heat sources and any oxidizing agent or catalyst you might need. Draw the reaction
pathways needed to synthesize each compound. Number each step and be sure to include catalysts
or oxidizing agents used. You do not need to draw structures.
1.
2.
synthesize ethoxypropane starting from alkenes
synthesize an amide starting from an alcohol and/or alkenes.
13.
14.
15.
16.
17.
18.
19.
20.
21.
22.
23.
24.
5-ethyl-2-methyl-4-hydroxy-3-heptanone
butyl ethanoate
propylamine
formic acid
N-ethyl-N-methyl butanamide
1,3-diaminobenzene
ethyl benzoate
3-ethyl-1,4-diaminobenzene
N,N-diethyl-1-aminobutane
N-ethyl-N,3-dimethylbutanamide
2-methyl-3,4-dimethyl-1-aminohexane
propyl methanoate
2.
4.
6.
8.
2.
4.
6.
2.
5.
lactic acid
epinephrine
hexanoic acid + ethanol →
ethanal + (O) →
butanone + H2 →
acetic acid + butanol →
butanoic acid
hexanal
aminoethane
3.
6.
acetylsalicylic acid (ASA)
caffeine
3.
1,3-dibutanol
3-methyl-1-pentenoic acid
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