Page 1 of 2 Clements Chemicals SAFETY DATA SHEET GLASSWASH RINSE AID Revision Date: 06 Aug. 03 Date of Printing: 07 Mar. 16 MSDS Revision: 01 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY/UNDERTAKING Glasswash Rinseaid Product Name: Product NO: Supplier: A892, A893 William Clements (Chemicals) Ltd The Old Transport Museum Witham Street BELFAST BT4 1HP (028) 9073 8395 Telephone: 2. COMPOSITION/INFORMATION ON INGREDIENTS Ingredient Name Citric Acid Anhydrous Isopropanol 3. CAS No. 77-92-9 67-63-0 Contents (%) <2 <10 Health (class) Xi F Risk (R No.) 36 11, 36, 67 HAZARDS IDENTIFICATION Provided that this product is handled correctly, it is not classified as hazardous to humans. 4. FIRST AID MEASURES Inhalation: Ingestion: Skin Contact: Eye Contact: Remove from exposure, rest and keep warm. In severe cases, or if recovery is not rapid or complete, seek medical attention. Wash out mouth with water. Do not induce vomiting. If patient is conscious, give water to drink. If patient feels unwell seek medical attention. Drench the skin with plenty of water. Remove contaminated clothing and wash before reuse. If large areas of the skin are damaged, or if irritation persists seek medical attention. Irrigate thoroughly with water for at least 10 minutes. Obtain medical attention if irritation persists. FIRE-FIGHTING MEASURES Suitable Extinguishing Media: Special Fire-Fighting Procedures: Unusual Fire & Explosion Hazards: 6. Carbon Dioxide, dry chemical, sand. Wear full protective clothing and a self-contained breathing apparatus. In combustion may emit toxic fumes of carbon dioxide and carbon monoxide. ACCIDENTAL RELEASE MEASURES Do not discharge into drains or river. Contain the spillage using bunding. Bund or absorb the material with sand or earth. If possible transfer liquid to a salvage tank, otherwise absorb material and transfer to suitable containers for waste disposal. Spill Cleanup Procedures: 7. HANDLING AND STORAGE Usage Precautions: Storage Precautions: Avoid Ensure there is sufficient ventilation of the area. Avoid direct contact with the substance. Avoid sources of ignition. Do not breathe vapours. Temperature Range: Cool Humidity Range: Dry Keep container tightly closed. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure limits: Isopropanol: 400ppm (980 mg/m3), 8hr TWA; 500ppm (1225 mg/m3), STEL Monitoring Method: as Propan-2-ol Protective measures: N/A Nitrile or butyl rubber gloves. Safety goggles Overalls and boots Always wash thoroughly after handling chemicals. Respirators: Protective Gloves: Eye Protection: Other Protection: Type: OES Page 2 of 2 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Blue liquid 10. STABILITY AND REACTIVITY Stability: Materials to Avoid: Hazardous Decomposition Products: Stable under normal conditions Strong oxidising agents None when used and handled as intended. 11. TOXICOLOGICAL INFORMATION Health Warnings: Isopropranol- LD50: 5840 mg/kg oral-rat >12800 mg/kg skin-rabbit Causes eye irritation. Prolonged or repeated skin contact may cause defatting resulting in dermatitis and secondary infections. Inhalation and ingestion may produce general narcotic effects similar to drunkenness-central nervous system depression, drowsiness, dizziness, disorientation, behavioural changes and hypotension. 12. ECOLOGICAL INFORMATION Soluble in water Isopropanol: LC50, Fathead minnow = 9600 mg/l; LC50, 24h, Daphnia > 10000 mg/l. Not expected to bioaccumulate. Mobility: Aquatic Toxicity: Bioaccumulative potential: 13. DISPOSAL CONSIDERATIONS Disposal Methods: Via an authorised waste disposal contractor to an approved waste disposal site, observing all local and national regulations 14. TRANSPORT INFORMATION NOT REGULATED FOR TRANSPORT 15. REGULATORY INFORMATION NOT CLASSIFIED AS HAZARDOUS 16. OTHER INFORMATION Text of the R-phrases that are allocated to the ingredients listed in section 2 of this safety data sheet: R36 R11 R67 Irritating to eyes Highly Flammable Vapours may cause drowsiness and dizziness The information given in this safety data sheet is based on knowledge available at the time of completion and is intended to describe the product only in terms of the health and safety requirements. It does not signify any warranty with regard to specific properties or specifications.