MATERIAL SAFETY DATA SHEET 1. Product and Company Identification - Product Name: - Manufacturing Number: - Producer: N-LARGE Not available Stoller Enterprises P.O. Box 2374 Parklands 2121 South Africa - Telephone Number: +27 (0)82 921 8428 - Fax No: +27 (0) 865 476 711 - Email: jonathan@mbfi.co.za - Supplier: MBF International cc 2. Information on the Composition of Ingredients - Product Description: Plant growth regulator and alcohols. Contains Gibberellic acid, Gibberellin A3; Isopropyl alcohol, Isopropanol, 2- . - Dangerous Ingredients: None 3. Hazardous Identification - Possible Hazards: Flammable. Keep away from heat and open flame. Product will cause serious health hazards as a result of overexposure. Harmful if ingested. May cause irritation to skin and eyes if contact occurs. May cause discomfort to respiratory tract if inhaled or with prolonged exposure. 4. First Aid Measures - Inhalation: Remove from exposure area from mists or in the event of massive inhalation. Seek medical attention if any reaction or adverse effects are noticed. - Skin Contact: Rinse thoroughly with soap and water. Seek medical attention if irritation occurs or if an allergic reaction is noticed. - Eye Contact: Rinse slowly and gently with water for 1520minutes. Seek medical attention if irritation occurs or if an allergic reaction is noticed. - Ingestion: Victim should drink milk, egg whites or large quantities of water. Never give anything by mouth to someone who is unconscious, having convulsions or unable to swallow. Do not induce vomiting unless advised by medical personal. Seek medical attention if any reaction or adverse effects are noticed. 5. Fire Fighting Measures - Type of Material: Flammable liquid. - Extinguishing Media: Use water mist, foam, Carbon dioxide or dry chemicals. - Hazardous Decomposition Products: Toxic fumes (CO, CO2, etc.) under fire conditions. 6. Accidental Release Measures - Environmental Precautions: All work practices must be aimed at preventing environmental contamination. Do not apply directly to water, and avoid application where runoff may occur. Because of its nutritional nature, this product may cause eutrophication if discharged into water bodies. - Personal Precautions: Personal Protective Equipment (PPE) in the form of gloves, safety goggles and overalls are recommended. - Destruction and Clean Up: In case of a large spill, protect people by clearing and isolating the affected area. It is necessary to contain spill into the smallest area possible; recovering liquid in an appropriate container (labelling it accordingly if necessary). If the product is clean, use as intended following the original label directions; if contaminated, salvage for proper disposal as waste. Absorb residual product with absorbent substance (i.e. dirt, sand, sawdust) and then scrape up and dispose of appropriately. 7. Handling and Storage - Handling: Avoid breathing vapours or mists; use in a well – ventilated location and wash thoroughly after handling. - Storage: Store in original labelled container only. Keep lid tightly sealed and store under cool, dry conditions away from direct sunlight, sources of intense heat or where freezing is possible. Store away from food, feed, clothing materials and living quarters. Inspect all containers before storage, to ensure they are properly labled and not damaged. Keep away from children and domestic animals. - Incompatible Materials: May react with string oxidizers. 8. Exposure Control/Personal Protective Equipment Gibberellic acid – Not established. - TLV: Isopropyl alcohol – 400ppm. - Technical Measures/precautions: General ventilation is usually adequate. Local exhaust should be used if needed for safe, comfortable working conditions. - Personal Protection: Respiratory Protection: Prolonged exposure may cause temporary discomfort of respiratory tract and headache. Respiratory protection (face mask) is recommended. Hand Protection: As this product could cause irritation to the skin, it is recommended that gloves be worn as a precaution during handling. Eye Protection: This product may cause substantial but temporary eye irritation if contact/exposure occurs. Therefore the use of safety goggles/glasses is highly recommended. Skin Protection: This product may cause skin irritation/allergic reactions in some individuals. Overalls are recommended to avoid any such reactions. 9. Physical and Chemical Properties - Physical State: Liquid. - Colour: Clear to light-yellow. - Odour: Pleasant alcohol odour. - pH: N/A - Moisture (%): N/A - Density (Specific Gravity): 0.79 to 0.80 g/cm3 - Solubility/Miscibility in Water: >99% solubility - Partition Coefficient: N/A - Vapour Pressure (mm/Hg): 32mm @ 20°C. - Boiling Point: 85°C - Melting Point: 88.5°C - Flash Point: 12.5°C - Oxidizing Properties: Avoid strong oxidizers - Explosive Properties: Vapours are flammable and heavier than air. Drifting vapours may reach distant ignition sources and flash back. Use water mist to dissipate vapours. - Auto-ignition Temperature: N/A 10. Stability and Reactivity - Hazardous Decomposition Products: Toxic fumes (CO, CO2, etc.) under fire conditions. - Materials to Avoid: May react with strong oxidizers - Conditions to Avoid: Keep away from sources of ignition. 11. Toxological Information - Oral LD50 (rat): GA3 = 6300mg/kg Isopropanol = 5045 mg/kg - Inhalation LD50 (rat): Isopropanol = 19000 ppm/8hours - Skin Irritant (Rabbit): GA3 = 2000mg/kg Isopropanol = 1280mg/kg - Chronic Toxicity: Non-carcinogenic, non-teratogenic, non-mutagenic and does not produce reproductive toxicity. 12. Ecological Information The available data on this plant nutrient material does not indicate any undue hazard to the environment, if used correctly and according to the instructions on this MSDS and product label. Any waste due to spillage or leakage should be dealt with appropriately (see Accidental Release Measures). Due to the nutrient value, the product may contribute to eutrophication in water bodies. 13. Disposal Considerations Wastes disposal must be done according to hazardous waste regulations at an approved waste disposal site. NOTE: Empty containers may have residues (liquid and/or fumes) thus, handle them with care. Do not cut, drill, grind, weld or perform similar operations on or near containers, nor expose them to intense heat, flames, sparks, static electricity or other sources of ignition; they may explode and cause bodily injury or even death. Dispose of appropriately and according to regulations or make available to a container reconditioning facility for recycling. 14. Transportation Data - Shipping Name: Flammable Liquid - Hazard Class: 3 - UN No.: UN1219 (ISOPROPANOL Solution) - Packaging Group: II 15. Regulations - EEC Classification: Flammable Liquid - Hazardous Symbols: R10 – Flammable R20/21/22 – Harmful by inhalation, in contact with skin and if swallowed. R36/37/38 – Irritating to eyes, respiratory system and skin. - S-phases: S1/2 – Keep locked up and out of children’s reach. S20/21 – When using do not eat, drink or smoke. S24/25 – Avoid contact with skin and eyes. S36/37/39 – Wear suitable protective clothing, gloves and eye/face protection. - National Regulations: National Road Traffic Act (Act 93 of 1996); Fire Brigade Service Act (Act 99 of 1987); Occupational Health and Safety Act (Act 85 of 1993). - Other Regulations: None 16. Other Information The purpose of the above information is to describe the product only in terms of health and safety requirements. The information given should not therefore be construed as guaranteeing specific properties or as a specification. Customers should satisfy themselves as to the suitability and completeness of such information for their own particular use. Contact Person: Mr. Jonathan Etherington Contact Number: +27 82 924 8428