SIGMA CHEMICAL COMPANY -- AMMONIUM CHLORIDE -- 6810-00281-2033 ===================== ===================== Product Identification Product ID:AMMONIUM CHLORIDE MSDS Date:01/31/1995 FSC:6810 NIIN:00-281-2033 MSDS Number: CCBZR === Responsible Party === Company Name:SIGMA CHEMICAL COMPANY Address:3050 SPRUCE ST Box:14508 City:ST. LOUIS State:MO ZIP:63178 Country:US Info Phone Num:800-325-3010/FAX 800-325-5052 Emergency Phone Num:314-771-5765 CAGE:21076 === Contractor Identification === Company Name:ABBOTT LABORATORIES PHARMACEUTICAL PRODUCTS DIV Address:200 ABBOTT PARK RD Box:City:NORTH CHICAGO State:IL ZIP:60064-3500 Country:US Phone:847-935-7155 CAGE:70048 Company Name:SIGMA CHEMICAL COMPANY Address:3050 SPRUCE ST Box:14508 City:ST LOUIS State:MO ZIP:63178 Country:US Phone:314-771-5765 CAGE:21076 ============= ============= Composition/Information on Ingredients Ingred Name:AMMONIUM CHLORIDE (CERCLA) CAS:12125-02-9 RTECS #:BP4550000 Fraction by Wt: 100% % Other REC Limits:NONE RECOMMENDED OSHA PEL:10 MG/M3 ACGIH TLV:10 MG/M3 FUME; 9596 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== ===================== Hazards Identification LD50 LC50 Mixture:ORAL LD50 (RAT): 1650 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:HARMFUL IF SWALLOWED. MAY BE HARMFUL IF INHALED. MAY BE HARMFUL IF ABSORBED THROUGH THE SKIN. CAUSES SEVERE EYE IRRITATION. CAUSES SKIN IRRITATAION. MATERIAL IS IRRITATING TO MUCOUS MEMBRANES AND UPPE R RESPIRATORY TRACT. Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT CARCINOGENS. Effects of Overexposure:EYE IRRITATION, SKIN IRRITATION, IRRITATION OF THE MUCOUS MEMBRANES, UPPER RESPIRATORY TRACT IRRITATION. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= ======================= First Aid Measures First Aid:EYES: FLUSH WITH WATER FOR 15 MINUTES WHILE HOLDING EYELIDS OPEN. GET MEDICAL ATTENTION. SKIN: REMOVE CONTAMINATED CLOTHING. WASH WITH SOAP AND WATER. IF IRRITATION PERSIST, GET MEDICAL ATTENTION. INH ALATION: REMOVE TO FRESH AIR. RESTORE BREATHING. GET MEDICAL ATTENTION. INGESTION: WASH OUT MOUTH WITH WATER PROVIDED PERSON IS CONCSIOUS. CALL A PHYSICIAN. ===================== ===================== Fire Fighting Measures Flash Point:NONFLAMMABLE Lower Limits:NOT GIVEN Upper Limits:NOT GIVEN Extinguishing Media:NONFLAMMABLE. USE EXTINGUISHING MEDIA SUITABLE FOR SURROUNDING FIRE. Fire Fighting Procedures:FIRE FIGHTERS SHOULD WEAR SELF CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE GEAR. Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS. ================== ================== Accidental Release Measures Spill Release Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS, RUBBER BOOTS AND HEAVY RUBBER GLOVES. SWEEP UP, PLACE IN A BAG AND HOLD FOR WASTE DISPOSAL. AVOID RAISING DUST. VENTILATED AREA AND WASH SPILL SITE AFTER MATER IAL PICKUP IS COMPLETE. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:INCOMPATIBLE WITH LEAD AND SILVER SALTS. FORMS EXPLOSIVE MIXTURES WITH POTASSIUM CHLORATE. KEEP TIGHTLY CLOSED. STORE IN A COOL, DRY PLACE. Other Precautions:REACTS VIGOROUSLY WITH BROMINE TRIFLUORIDE AND BROMINE PENTAFLUORIDE. DO NOT BREATHE DUST. AVOID CONTACT WITH EYES, SKIN AND CLOTHING. AVOID PROLONGED CONTACT OR REPEATED EXPOSURE. WASH THOROUGHLY AFT ER HANDLING. ============= ============= Exposure Controls/Personal Protection Respiratory Protection:WEAR APPROPRIATE NIOSH/MSHAAPPROVED RESPIRATOR. Ventilation:LOCAL EXHAUST AND MECHANICAL (GENERAL) VENTILATION AS REQUIRED TO MAINTAIN EXPOSURE LEVELS. Protective Gloves:CHEMICAL-RESISTANT GLOVES Eye Protection:SAFETY GOGGLES Other Protective Equipment:CHEMICAL RESISTANT CLOTHING AS NECESSARY TO PREVENT SKIN CONTACT. AN EMERGENCY EYEWASH AND SHOWER SHOULD BE AVAILABLE. Work Hygienic Practices:WASH HANDS THOROUGHLY WITH SOAP AND WATER BEFORE EATING, DRINKING, SMOKING OR USING TOILET FACILITIES. Supplemental Safety and Health MFR RECOMMENDS FOR DISPOSAL OF SMALL QUANTITIES: CAUTIOUSLY ADD TO A LARGE STIRRED EXCESS OF WATER. ADJUST THE PH TO NEUTRAL, SEPARATE ANY INSOLUBLE SOLIDS OR LIQUIDS AND PACKAGE THEM FOR HAZARDOUS WA STE DISPOSAL. FLUSH THE AQUEOUS SOLUTION DOWN THE DRAIN WITH PLENTY OF WATER. CHECK WITH LOCAL AUTHORITIES FIRST. ================== ================== Physical/Chemical Properties HCC:N1 Boiling Pt:B.P. Text:NOT GIVEN Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN Vapor Pres:1 Vapor Density:1.9 Spec Gravity:1.530 Evaporation Rate & Reference:NOT GIVEN Solubility in Water:NOT GIVEN Appearance and Odor:WHITE CRYSTALLINE POWDER, ODOR NOT SPECIFIED ================= ================= Stability and Reactivity Data Stability Indicator/Materials to Avoid:YES STRONG ACIDS, STRONG BASES. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:HYDROGEN CHLORIDE GAS, AMMONIA. ==================== ==================== Disposal Considerations Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING SURROUNDING ENVIRONMENT. DISCARD ANY PRODUCT, RESIDUE, DISPOSAL CONTAINER OR LINER IN ACCORDANCE WITH ALL FEDERAL, STATE AND LOCAL REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.