Name ____________________________________________ Date ____________________ Class ___________________ 4 The Structure of the Atom Reviewing Vocabulary Match the definition in Column A with the term in Column B. Column A Column B ______ 1. Radiation deflected toward the positively charged plate a. atom ______ 2. Atoms with the same number of protons but different numbers of neutrons b. nucleus ______ 3. High-energy radiation that has no charge and no mass c. atomic mass ______ 4. The smallest particle of an element that retains the properties of that element ______ 5. The weighted average mass of an element’s isotopes ______ 6. The center-most part of an atom where the protons and neutrons are contained ______ 7. Radiation deflected toward the negatively charged plate d. isotopes e. gamma ray f. alpha radiation g. beta radiation ______ 8. The rays and particles emitted by radioactive material h. atomic mass unit ______ 9. Equal to 1/12 the mass of a carbon-12 atom i. radiation _____ 10. Ray of radiation traveling from the cathode to the anode j. Dalton’s atomic theory _____ 11. Process (not requiring energy) by which unstable nuclei lose energy _____ 12. States that all matter is composed of atoms k. cathode ray l. _____ 13. Process whereby some substances spontaneously emit radiation radioactivity m. radioactive decay Compare and contrast each pair of related terms. 14. mass number, atomic number ______________________________________________________________________________________________ ______________________________________________________________________________________________ ______________________________________________________________________________________________ 15. nuclear reaction, nuclear equation ______________________________________________________________________________________________ ______________________________________________________________________________________________ ______________________________________________________________________________________________ Chemistry: Matter and Change 1 Chapter Assessment Name ____________________________________________ Date ____________________ Class ___________________ 4 Understanding Main Ideas (Part A) Use the periodic table to identify each element described below. 1. atomic number 65 __________________ 2. 78 protons __________________ 3. 44 protons and 44 electrons __________________ 4. atomic number 24 __________________ 5. 21 protons __________________ 6. atomic number 55 __________________ In the space at the left, write true if the statement is true; if the statement is false, change the italicized term to make it true. _________________ 7. An atom’s nucleus contains its protons and electrons. _________________ 8. Neutrons have no electrical charge. _________________ 9. Beta particles have a charge of 2. ________________ 10. An alpha particle consists of two protons and two electrons. Complete the table below. Isotope Symbolic Notation Number of Protons Number of Electrons Number of Neutrons 11. Hydrogen-1 1 12. 3 1 1 H 8 13. 10 14. Copper-65 15. 0 36 235 92 Chemistry: Matter and Change U 2 Chapter Assessment Name ____________________________________________ Date ____________________ Class ___________________ 4 Understanding Main Ideas (Part B) For each description in Column A, write the letter of the matching symbol in Column B. Column A Column B a. 17 8 b. 63 29 Cu c. 12 6 6C ______ 4. Isotope that has one neutron more than its number of protons d. 50 24 Cr ______ 5. Carbon with equal numbers of neutrons, protons, and electrons e. 14 6 C ______ 6. Carbon with two more neutrons than its number of protons f. 65 29 Cu ______ 7. Chromium with two more neutrons than its number of protons g. 52 24 Cr ______ 8. Isotope in which the difference between the neutrons and number of protons is 4 h. 54 24 Cr ______ 1. Isotope in which the number of neutrons is six more than the isotope’s atomic number ______ 2. Copper-63 ______ 3. Copper with seven neutrons more than its atomic number O Answer the following questions. 9. Calculate the atomic mass of gallium (Ga). Gallium has two isotopes: 69Ga and 71Ga. 69Ga has a relative abundance of 60.12% and an atomic mass of 68.9257 amu. 71Ga has a relative abundance of 39.88% and an atomic mass of 70.9249 amu. Show all your work. 10. Calculate the atomic mass of the element X. Then use the periodic table to identify the element. Show all your work. Isotope Mass (amu) Percent Abundance 27 27.977 92.23 28 28.976 4.67 29 29.974 3.10 X X X Chemistry: Matter and Change 3 Chapter Assessment Name ____________________________________________ Date ____________________ Class ___________________ 4 Thinking Critically Antimony (Sb) has two stable isotopes. 121Sb has a mass of 120.90 amu. 123Sb has a mass of 122.90 amu. 1. What is antimony’s atomic mass? Use the periodic table. ______________________________________________________________________________________________ 2. Write an equation to describe the relationship between the percent abundance of 121Sb and the percent abundance of 123Sb. Assume that no other isotopes exist. ______________________________________________________________________________________________ 3. Write an equation that you can use to calculate the percent abundance of each isotope. ______________________________________________________________________________________________ ______________________________________________________________________________________________ 4. Calculate the percent abundance for each isotope of antimony. Show all your work. Chemistry: Matter and Change 4 Chapter Assessment Name ____________________________________________ Date ____________________ Class ___________________ 4 Applying Scientific Methods Data Table I is a chemist’s record of data about six isotopes. Data Table I Isotope Number of Protons Number of Electrons Number of Neutrons Mass (amu) Isotope 1 24 24 26 49.946 Isotope 2 24 24 28 51.941 Isotope 3 26 26 30 55.999 Isotope 4 24 24 29 52.941 Isotope 5 24 24 30 53.939 Isotope 6 26 26 31 56.969 1. Which of the isotopes listed are the same element? Explain your reasoning. ______________________________________________________________________________________________ ______________________________________________________________________________________________ ______________________________________________________________________________________________ ______________________________________________________________________________________________ 2. Explain why the mass of each isotope is not a whole number. ______________________________________________________________________________________________ ______________________________________________________________________________________________ ______________________________________________________________________________________________ ______________________________________________________________________________________________ ______________________________________________________________________________________________ Upon further research, the chemist determined the percent abundance of each isotope. These are listed in Data Table II below. Data Table II Isotope Isotope 1 Isotope 2 Isotope 3 Isotope 4 Isotope 5 Isotope 6 Chemistry: Matter and Change Percent Abundance 4.35 83.80 81.32 9.50 2.35 18.68 5 Chapter Assessment Name ____________________________________________ Date ____________________ Class ___________________ 4 Applying Scientific Methods, continued 3. Assume that Isotope 1 is an isotope of element X and that all the isotopes of X are listed in Data Table II. Determine the atomic mass of X. Show all your work. 4. Which isotope of X is most abundant? Least abundant? ______________________________________________________________________________________________ ______________________________________________________________________________________________ 5. Which isotope of X has the greatest effect on the atomic mass of X? Explain why. ______________________________________________________________________________________________ ______________________________________________________________________________________________ ______________________________________________________________________________________________ ______________________________________________________________________________________________ ______________________________________________________________________________________________ 6. If the chemist later discovered the following isotope, what could you conclude? Isotope Number of Protons Number of electrons Number of Neutrons Mass (amu) Isotope 7 24 24 31 54.939 ______________________________________________________________________________________________ ______________________________________________________________________________________________ ______________________________________________________________________________________________ ______________________________________________________________________________________________ ______________________________________________________________________________________________ ______________________________________________________________________________________________ ______________________________________________________________________________________________ ______________________________________________________________________________________________ ______________________________________________________________________________________________ ______________________________________________________________________________________________ Chemistry: Matter and Change 6 Chapter Assessment TEACHER GUIDE AND ANSWERS Chapter Assessment - Chapter 4 — The Structure of the Atom Understanding Main Ideas (Part B) 1. h 2. b 3. f 4. a 5. c 6. e 7. d 8. g 9. Mass contribution (mass)(percent abundance) 69 Ga: (68.9257 amu)(60.12%) 41.44 amu 71 Ga: (70.9249 amu)(39.88%) 28.28 amu Atomic mass of Ga 41.44 amu 28.28 amu 69.72 amu 10. Mass contribution (mass)(percent abundance) For 27X: (27.977 amu)(92.23%) 25.80 amu For 28X: (28.976 amu)(4.67%) 1.35 amu For 29X: (29.974 amu)(3.10%) 0.929 amu Atomic mass of X 25.80 amu 1.35 amu 0.929 amu 28.08 amu The element is silicon. Reviewing Vocabulary 1. g 2. d 3. e 4. a 5. c 6. b 7. f 8. i 9. h 10. k 11. m 12. j 13. l 14. Both pertain to atoms. The mass number is the sum of the protons and neutrons in the nucleus of a given atom. The atomic number is the number of protons in an atom. 15. Both concern changes in atoms. A nuclear reaction involves a change in an atom’s nucleus. A nuclear equation shows the atomic number and mass number of the particles involved in a reaction. Thinking Critically 1. 121.760 amu 2. Percent abundance of 121Sb Percent abundance of 123 Sb 100%, or 1 3. Atomic mass of Sb (mass of 121Sb)(percent abundance of 121Sb) (mass of 123Sb)(percent abundance of 123Sb) 4. Assume: Percent abundance of 121Sb x Percent abundance of 123Sb 1 – x Then solve: Atomic mass of Sb 121.760 amu (120.90 amu)x (122.90 amu)(1 x) 120.90x amu 122.90 amu 122.90x amu 1.140 amu 2x amu x 0.570 Percent abundance of 121Sb 57.0% Percent abundance of 123Sb 1 x 1 0.570 43.0% Understanding Main Ideas (Part A) 1. terbium 2. platinum 3. ruthenium 4. chromium 5. scandium 6. cesium 7. neutrons 8. true 9. Alpha 10. neutrons 1 1 H 12. Hydrogen-3, 1, 1, 2 13. Oxygen-18, 188 O, 8 11. 65 29 Cu, 29, 29 15. Uranium-235, 92, 92, 143 14. Chemistry: Matter and Change 7 Teacher Guide and Answers TEACHER GUIDE AND ANSWERS Applying Scientific Methods 1. Isotopes 1, 2, 4, and 5 are the same element; they all have 24 protons. Isotopes 3 and 6 are another element; they both have 26 protons. 2. Answers may vary. Although the masses of protons and neutrons, which make up most of the mass of an atom, are very close to 1 amu, they are not exactly 1 amu. Thus, the mass of each isotope is very close to a whole number, but is not exactly a whole number. 3. Mass contribution (mass)(percent abundance) Isotope 1: (49.946 amu)(4.35%) 2.17 amu Isotope 2: (51.941 amu)(83.80%) 43.53 amu Isotope 4: (52.941 amu)(9.50%) 5.03 amu Isotope 5: (53.939 amu) (2.35%) 1.27 amu Atomic mass of X 2.17 amu 43.53 amu 5.03 amu 1.27 amu 52.00 amu 4. Isotope 2; Isotope 5 5. Isotope 2; because the atomic mass of an element is a weighted average, the isotope that is the most abundant generally has the greatest effect on the atomic mass of the element. 6. Answers will vary. Students should include in their conclusions that Isotope 7, because it has 24 protons, is an isotope of element X. They may also conclude that the percent abundance of each isotope of X in Data Table II and the atomic mass of X calculated in question 3 may be inaccurate if Isotope 7 occurs in more than a trace amount. Students may suggest that the atomic mass of X should be greater than the calculation in question 3 suggests. Accept all other reasonable conclusions based on the data provided. Chemistry: Matter and Change 8 Teacher Guide and Answers