Reaction Summary for Carboxylic Acids and Derivatives
H2NNHC6H4(NO2)2
C2H5CH=NNHC6H4(NO2)2
Ethanal 2, 4 - dinitrophenylhydrazone
C2H5CHO
C2H5CO2Na+
**NaOH(aq)
reflux
C2H5COOCH3
Methyl ethanoate
CH3OH
+ H+
LiAlH4 in
ether
Na2Cr2O7/H+
NaOH or Na2CO3
aqueous
LiAlH4 in
ether
Na2Cr2O7/H+
C2H5CH2 OH
C2H5CO2H
LiAlH4 in
ether
*CH3OH
*H2O(l)
*NH3(g)
C2H5COCl
C2H5CONH2
propanamide
NH4OH(aq)
*NH4OH(aq)
C2H5CO2NH4+
(CH3)2NH
C2H5CONHCH3
N – methylpropanamide
CH3NH2
C2H5CON(CH3)2
N, N – dimethylpropanamide
* HCl is produced as well whenever CH3COCl is involved in a reaction. CH3COCl reacts by NUCLEOPHILIC ADDITION ELIMINATION.
** The ALCOHOL, CH3OH is also produced. HCl is added to the end product to displace the CARBOXYLIC ACID.
Reaction Summary for Carboxylic Acids and Derivatives
C2H5CH=NNHC6H4(NO2)2
Ethanal 2, 4 - dinitrophenylhydrazone
C2H5CHO
C2H5CO2Na+
C2H5COOCH3
Methyl ethanoate
C2H5CH2 OH
C2H5CO2H
*
*
*
*
C2H5COCl
C2H5CONH2
C2H5CO2NH4+
propanamide
C2H5CONHCH3
N – methylpropanamide
C2H5CON(CH3)2
N, N – dimethylpropanamide
* HCl is produced as well whenever CH3COCl is involved in a reaction. CH3COCl reacts by NUCLEOPHILIC ADDITION ELIMINATION.
** The ALCOHOL, CH3OH is also produced. HCl is added to the end product to displace the CARBOXYLIC ACID.
Reaction Summary for Carboxylic Acids and Derivatives
H2NNHC6H4(NO2)2
**NaOH(aq)
reflux
CH3OH
+ H+
LiAlH4 in
ether
Na2Cr2O7/H+
NaOH or Na2CO3
aqueous
Na2Cr2O7/H+
C2H5CO2H
LiAlH4 in
ether
*CH3OH
*H2O(l)
NH4OH(aq)
*NH4OH(aq)
*NH3(g)
(CH3)2NH
propanamide
CH3NH2
N – methylpropanamide
N, N – dimethylpropanamide
* HCl is produced as well whenever CH3COCl is involved in a reaction. CH3COCl reacts by NUCLEOPHILIC ADDITION ELIMINATION.
** The ALCOHOL, CH3OH is also produced. HCl is added to the end product to displace the CARBOXYLIC ACID.
LiAlH4 in
ether